JP2005307082A - 難接着材質用光硬化性樹脂組成物 - Google Patents
難接着材質用光硬化性樹脂組成物 Download PDFInfo
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- JP2005307082A JP2005307082A JP2004128496A JP2004128496A JP2005307082A JP 2005307082 A JP2005307082 A JP 2005307082A JP 2004128496 A JP2004128496 A JP 2004128496A JP 2004128496 A JP2004128496 A JP 2004128496A JP 2005307082 A JP2005307082 A JP 2005307082A
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- 239000000463 material Substances 0.000 title claims abstract description 26
- 239000011342 resin composition Substances 0.000 title claims abstract description 11
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 26
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 21
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 3
- 229920005989 resin Polymers 0.000 claims abstract 2
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- 239000000203 mixture Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 2
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- 229920013716 polyethylene resin Polymers 0.000 abstract description 3
- 238000004381 surface treatment Methods 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 8
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- 239000004743 Polypropylene Substances 0.000 description 6
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- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 description 4
- GUUVPOWQJOLRAS-UHFFFAOYSA-N Diphenyl disulfide Chemical class C=1C=CC=CC=1SSC1=CC=CC=C1 GUUVPOWQJOLRAS-UHFFFAOYSA-N 0.000 description 3
- 244000028419 Styrax benzoin Species 0.000 description 3
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- 239000004642 Polyimide Substances 0.000 description 2
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- 239000003085 diluting agent Substances 0.000 description 2
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- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- SDXHBDVTZNMBEW-UHFFFAOYSA-N 1-ethoxy-2-(2-hydroxyethoxy)ethanol Chemical compound CCOC(O)COCCO SDXHBDVTZNMBEW-UHFFFAOYSA-N 0.000 description 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 description 1
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 1
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- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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- 239000004831 Hot glue Substances 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- NQSMEZJWJJVYOI-UHFFFAOYSA-N Methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 NQSMEZJWJJVYOI-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- QWYSJTTWCUXHQO-UHFFFAOYSA-N [F].OC(=O)C=C Chemical compound [F].OC(=O)C=C QWYSJTTWCUXHQO-UHFFFAOYSA-N 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N desyl alcohol Natural products C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- BXCOOPLIKAAONJ-UHFFFAOYSA-N di(propan-2-yl)diazene Chemical compound CC(C)N=NC(C)C BXCOOPLIKAAONJ-UHFFFAOYSA-N 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
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- 239000011256 inorganic filler Substances 0.000 description 1
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- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
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Landscapes
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
【課題】
表面処理などの煩雑な別工程を必要とせず、ポリエチレンテレフタレート樹脂、シリコーン樹脂やポリエチレン樹脂などの難接着材質に対し、優れた接着性、密着性を示す光硬化性樹脂組成物を提供することを目的とするものである。
【解決手段】
(a)下記構造式(1)で表される、イソステアリル(メタ)アクリレート、(b)熱可塑性エラストマー、および(c)光開始剤からなることを特徴とする難接着材質用光硬化性樹脂組成物。(ただし、式中Rは水素またはメチル基である。)
【化1】
Description
下記化学式(1)に示され、Rが水素である化合物(新中村化学社製、NKエステルS−1800A)を75重量部、無水マレイン酸SEBS共重合体(クレイトンポリマー社製、FG1901X)を16重量部、SEBS共重合体(クレイトンポリマー社製、G1726)を9重量部、光開始剤として2−ヒドロキシ−2−メチル−1−フェニル−プロパン−1−オンを1.1重量部を混合して組成物を調製した。本組成物を実施例1とした。同様に実施例2〜5、比較例1〜9を表の通り調製した。表中、化合物Bは下記化学式(2)、化合物Cは下記化学式(3)である。ただし、比較例9は固形分が組成物中に残存したため、組成物を得ることはできなかった。
Claims (2)
- (a)下記構造式(1)で表される、イソステアリル(メタ)アクリレート、(b)熱可塑性エラストマー、および(c)光開始剤からなることを特徴とする難接着材質用光硬化性樹脂組成物。(ただし、式中Rは水素またはメチル基である。)
- 前記(a)イソステアリル(メタ)アクリレートと前記(b)熱可塑性エラストマーの配合比率が重量比で(a):(b)=40:60〜95:5である請求項2に記載の難接着材質用光硬化性樹脂組成物。
Priority Applications (1)
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JP2004128496A JP4645797B2 (ja) | 2004-04-23 | 2004-04-23 | 難接着材質用光硬化性樹脂組成物 |
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JP2004128496A JP4645797B2 (ja) | 2004-04-23 | 2004-04-23 | 難接着材質用光硬化性樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
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JP2005307082A true JP2005307082A (ja) | 2005-11-04 |
JP4645797B2 JP4645797B2 (ja) | 2011-03-09 |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007056087A (ja) * | 2005-08-23 | 2007-03-08 | Three Bond Co Ltd | 光硬化性防湿コート剤組成物 |
JP2010138290A (ja) * | 2008-12-11 | 2010-06-24 | Nichiban Co Ltd | 光硬化性組成物、その色素増感型太陽電池用シーリング材としての使用、及び色素増感型太陽電池 |
US8137807B2 (en) | 2010-03-26 | 2012-03-20 | 3M Innovative Properties Company | Pressure-sensitive adhesives derived from 2-alkyl alkanols |
JPWO2012005169A1 (ja) * | 2010-07-08 | 2013-09-02 | 電気化学工業株式会社 | 硬化性樹脂組成物 |
US20140248489A1 (en) * | 2011-09-30 | 2014-09-04 | Nitto Denko Corporation | Adhesive, adhesive layer, and adhesive sheet |
KR20150118903A (ko) | 2014-04-15 | 2015-10-23 | 쓰리본드 화인 케미칼 가부시키가이샤 | 광경화성 조성물 |
WO2015190552A1 (ja) * | 2014-06-11 | 2015-12-17 | 日本化薬株式会社 | タッチパネル用紫外線硬化型樹脂組成物、それを用いた貼り合せ方法及び物品 |
WO2015190571A1 (ja) * | 2014-06-11 | 2015-12-17 | 日本化薬株式会社 | タッチパネル用紫外線硬化型樹脂組成物、それを用いた貼り合せ方法及び物品 |
US9399724B2 (en) | 2011-09-26 | 2016-07-26 | 3M Innovative Properties Company | Pressure-sensitive adhesives with (meth)acrylic-based elastomeric materials prepared using (2-isopropyl-5-methyl)hexyl (meth)acrylate |
CN106459726A (zh) * | 2014-06-11 | 2017-02-22 | 日本化药株式会社 | 触控面板用紫外线固化型树脂组合物、使用了该组合物的贴合方法和物品 |
Citations (3)
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JPH06207146A (ja) * | 1993-01-11 | 1994-07-26 | Three Bond Co Ltd | 光硬化性接着剤組成物 |
JPH0790228A (ja) * | 1993-04-28 | 1995-04-04 | Nippon Zeon Co Ltd | 紫外線硬化性組成物、それを用いた接着方法、及び接着物 |
JP2003096114A (ja) * | 2001-09-19 | 2003-04-03 | Sekisui Chem Co Ltd | 光重合性組成物及び粘着テープ |
-
2004
- 2004-04-23 JP JP2004128496A patent/JP4645797B2/ja not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06207146A (ja) * | 1993-01-11 | 1994-07-26 | Three Bond Co Ltd | 光硬化性接着剤組成物 |
JPH0790228A (ja) * | 1993-04-28 | 1995-04-04 | Nippon Zeon Co Ltd | 紫外線硬化性組成物、それを用いた接着方法、及び接着物 |
JP2003096114A (ja) * | 2001-09-19 | 2003-04-03 | Sekisui Chem Co Ltd | 光重合性組成物及び粘着テープ |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007056087A (ja) * | 2005-08-23 | 2007-03-08 | Three Bond Co Ltd | 光硬化性防湿コート剤組成物 |
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CN106459675B (zh) * | 2014-06-11 | 2020-04-10 | 日本化药株式会社 | 触控面板用紫外线固化型树脂组合物、使用了该组合物的贴合方法和物品 |
CN106459726B (zh) * | 2014-06-11 | 2020-12-22 | 日本化药株式会社 | 触控面板用紫外线固化型树脂组合物、使用了该组合物的贴合方法和物品 |
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