JP2005170947A - アルコキシ純粋なアルカリ土類金属アルコキシドの製造方法 - Google Patents
アルコキシ純粋なアルカリ土類金属アルコキシドの製造方法 Download PDFInfo
- Publication number
- JP2005170947A JP2005170947A JP2004360132A JP2004360132A JP2005170947A JP 2005170947 A JP2005170947 A JP 2005170947A JP 2004360132 A JP2004360132 A JP 2004360132A JP 2004360132 A JP2004360132 A JP 2004360132A JP 2005170947 A JP2005170947 A JP 2005170947A
- Authority
- JP
- Japan
- Prior art keywords
- alkaline earth
- alcohol
- general formula
- reaction
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 150000004703 alkoxides Chemical class 0.000 title abstract description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 73
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 87
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 45
- -1 alkaline earth metal alkoxide Chemical class 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 35
- CRGZYKWWYNQGEC-UHFFFAOYSA-N magnesium;methanolate Chemical compound [Mg+2].[O-]C.[O-]C CRGZYKWWYNQGEC-UHFFFAOYSA-N 0.000 claims description 25
- 238000004821 distillation Methods 0.000 claims description 19
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 19
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 16
- 239000011575 calcium Substances 0.000 claims description 16
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 14
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 11
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 7
- 230000000737 periodic effect Effects 0.000 claims description 7
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
- 125000006165 cyclic alkyl group Chemical group 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 238000006136 alcoholysis reaction Methods 0.000 abstract description 20
- 239000002904 solvent Substances 0.000 abstract description 2
- 239000011777 magnesium Substances 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 17
- 229910052749 magnesium Inorganic materials 0.000 description 16
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 15
- 150000001298 alcohols Chemical class 0.000 description 12
- 150000001342 alkaline earth metals Chemical class 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 230000035484 reaction time Effects 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- 238000001514 detection method Methods 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 238000012856 packing Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 230000001788 irregular Effects 0.000 description 5
- XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 description 5
- ORPJQHHQRCLVIC-UHFFFAOYSA-N magnesium;propan-2-olate Chemical compound CC(C)O[Mg]OC(C)C ORPJQHHQRCLVIC-UHFFFAOYSA-N 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000012456 homogeneous solution Substances 0.000 description 3
- HFTSQAKJLBPKBD-UHFFFAOYSA-N magnesium;butan-1-olate Chemical compound [Mg+2].CCCC[O-].CCCC[O-] HFTSQAKJLBPKBD-UHFFFAOYSA-N 0.000 description 3
- BIRXHGQICXXWGB-UHFFFAOYSA-N magnesium;decan-1-olate Chemical compound [Mg+2].CCCCCCCCCC[O-].CCCCCCCCCC[O-] BIRXHGQICXXWGB-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005684 Liebig rearrangement reaction Methods 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- OLXKLALYKVKDMV-UHFFFAOYSA-N calcium;hexan-1-olate Chemical compound [Ca+2].CCCCCC[O-].CCCCCC[O-] OLXKLALYKVKDMV-UHFFFAOYSA-N 0.000 description 2
- YBGHFLPNIGPGHX-UHFFFAOYSA-N calcium;octan-1-olate Chemical compound [Ca+2].CCCCCCCC[O-].CCCCCCCC[O-] YBGHFLPNIGPGHX-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- XLQMOUZWUAUZJX-UHFFFAOYSA-N magnesium;butan-2-olate Chemical compound [Mg+2].CCC(C)[O-].CCC(C)[O-] XLQMOUZWUAUZJX-UHFFFAOYSA-N 0.000 description 2
- GOMJHGKTFLDIRI-UHFFFAOYSA-N magnesium;hexan-1-olate Chemical compound [Mg+2].CCCCCC[O-].CCCCCC[O-] GOMJHGKTFLDIRI-UHFFFAOYSA-N 0.000 description 2
- WNJYXPXGUGOGBO-UHFFFAOYSA-N magnesium;propan-1-olate Chemical compound CCCO[Mg]OCCC WNJYXPXGUGOGBO-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- WDYVUKGVKRZQNM-UHFFFAOYSA-N 6-phosphonohexylphosphonic acid Chemical compound OP(O)(=O)CCCCCCP(O)(O)=O WDYVUKGVKRZQNM-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- MZNDIOURMFYZLE-UHFFFAOYSA-N butan-1-ol Chemical compound CCCCO.CCCCO MZNDIOURMFYZLE-UHFFFAOYSA-N 0.000 description 1
- GKMQWTVAAMITHR-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O.CCC(C)O GKMQWTVAAMITHR-UHFFFAOYSA-N 0.000 description 1
- JHLCADGWXYCDQA-UHFFFAOYSA-N calcium;ethanolate Chemical compound [Ca+2].CC[O-].CC[O-] JHLCADGWXYCDQA-UHFFFAOYSA-N 0.000 description 1
- AMJQWGIYCROUQF-UHFFFAOYSA-N calcium;methanolate Chemical compound [Ca+2].[O-]C.[O-]C AMJQWGIYCROUQF-UHFFFAOYSA-N 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- SYJRVVFAAIUVDH-UHFFFAOYSA-N ipa isopropanol Chemical compound CC(C)O.CC(C)O SYJRVVFAAIUVDH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/70—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups
- C07C29/705—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups by transalcoholysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10358412A DE10358412A1 (de) | 2003-12-13 | 2003-12-13 | Verfahren zur Herstellung alkoxyreiner Erdalkalialkoxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2005170947A true JP2005170947A (ja) | 2005-06-30 |
Family
ID=34485362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004360132A Withdrawn JP2005170947A (ja) | 2003-12-13 | 2004-12-13 | アルコキシ純粋なアルカリ土類金属アルコキシドの製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US20050159630A1 (de) |
| EP (1) | EP1541540B1 (de) |
| JP (1) | JP2005170947A (de) |
| CN (1) | CN1651375A (de) |
| AT (1) | ATE391114T1 (de) |
| DE (2) | DE10358412A1 (de) |
| ES (1) | ES2303012T3 (de) |
| PL (1) | PL1541540T3 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012171957A (ja) * | 2011-02-18 | 2012-09-10 | Colcoat Kk | 混合マグネシウムジアルコキシド粒状物、その合成方法およびその利用方法 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101723803A (zh) * | 2008-10-24 | 2010-06-09 | 上海奥锐特国际贸易有限公司 | 高纯度叔丁醇镁的制备方法 |
| CN102351650B (zh) * | 2011-09-14 | 2013-11-20 | 上海逸安医药科技有限公司 | 一种叔丁醇镁的制备方法 |
| CN102633600A (zh) * | 2011-11-22 | 2012-08-15 | 荆门市帅邦化学科技有限公司 | 高纯度叔丁醇镁的制备方法 |
| CN102603476B (zh) * | 2012-02-06 | 2013-11-27 | 扬州三友合成化工有限公司 | 高纯度高级醇镁的一种合成方法 |
| CN103232323A (zh) * | 2013-04-24 | 2013-08-07 | 荆门市帅邦化学科技有限公司 | 高纯度异丙醇镁的制备方法 |
| CZ2013610A3 (cs) * | 2013-08-06 | 2015-03-11 | Fyzikální ústav AV ČR, v.v.i. | Způsob výroby methoxidu hořečnatého reakcí hořčíku a methanolu za použití zinku jako katalyzátoru |
| CN106748191A (zh) * | 2016-12-28 | 2017-05-31 | 滁州市施集赵洼茶厂 | 一种高钙富磷抗逆性山地茶树有机肥及其制备方法 |
| CN116547259A (zh) * | 2020-12-04 | 2023-08-04 | 巴斯夫欧洲公司 | 用于控制反应精馏塔的方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB667708A (en) * | 1949-03-15 | 1952-03-05 | Standard Oil Dev Co | Improvements in or relating to preparation of catalytic and adsorbent magnesia-containing materials |
| US2965663A (en) * | 1957-11-25 | 1960-12-20 | Anderson Chemical Company | Processes for preparing metal alkyls and alkoxides |
| JPS545904A (en) * | 1977-06-11 | 1979-01-17 | Dynamit Nobel Ag | Continuos process for preparing alkali alcholate and apparatus therefor |
| JPS5470227A (en) * | 1977-10-31 | 1979-06-05 | Stamicarbon | Method of manufacturing oxygen contained organic magnesium compound solution in hydrocarbon |
| JPS5656233A (en) * | 1979-09-27 | 1981-05-18 | Union Carbide Corp | Manufacture of catalyst for oxyalkylation of reactive hydrogen compound |
| JPS60181104A (ja) * | 1984-02-28 | 1985-09-14 | Toa Nenryo Kogyo Kk | オレフイン重合用触媒成分の製造方法 |
| JPS61500438A (ja) * | 1983-11-15 | 1986-03-13 | リチウム・コ−ポレ−ション・オブ・アメリカ | アルカリ土類金属有機金属化合物の製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB767601A (en) * | 1953-04-29 | 1957-02-06 | Hardman & Holden Ltd | Improvements relating to metal alcoholates |
| US3971833A (en) * | 1973-07-02 | 1976-07-27 | Dynamit Nobel Aktiengesellschaft | Method for the preparation of alcohol-free alkali and alkaline earth metal alcoholates |
| GB8521431D0 (en) * | 1985-08-28 | 1985-10-02 | Shell Int Research | Spherical magnesium alkoxide particles |
| US4876230A (en) * | 1988-09-06 | 1989-10-24 | Shell Oil Company | Magnesium alkoxide polymerization catalyst by boiling in organic solvents |
-
2003
- 2003-12-13 DE DE10358412A patent/DE10358412A1/de not_active Withdrawn
-
2004
- 2004-11-13 PL PL04027034T patent/PL1541540T3/pl unknown
- 2004-11-13 EP EP04027034A patent/EP1541540B1/de not_active Not-in-force
- 2004-11-13 DE DE502004006713T patent/DE502004006713D1/de active Active
- 2004-11-13 AT AT04027034T patent/ATE391114T1/de active
- 2004-11-13 ES ES04027034T patent/ES2303012T3/es active Active
- 2004-12-10 US US11/008,574 patent/US20050159630A1/en not_active Abandoned
- 2004-12-13 CN CNA2004101021162A patent/CN1651375A/zh active Pending
- 2004-12-13 JP JP2004360132A patent/JP2005170947A/ja not_active Withdrawn
-
2007
- 2007-10-31 US US11/980,380 patent/US20080071119A1/en not_active Abandoned
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB667708A (en) * | 1949-03-15 | 1952-03-05 | Standard Oil Dev Co | Improvements in or relating to preparation of catalytic and adsorbent magnesia-containing materials |
| US2965663A (en) * | 1957-11-25 | 1960-12-20 | Anderson Chemical Company | Processes for preparing metal alkyls and alkoxides |
| JPS545904A (en) * | 1977-06-11 | 1979-01-17 | Dynamit Nobel Ag | Continuos process for preparing alkali alcholate and apparatus therefor |
| JPS5470227A (en) * | 1977-10-31 | 1979-06-05 | Stamicarbon | Method of manufacturing oxygen contained organic magnesium compound solution in hydrocarbon |
| JPS5656233A (en) * | 1979-09-27 | 1981-05-18 | Union Carbide Corp | Manufacture of catalyst for oxyalkylation of reactive hydrogen compound |
| JPS61500438A (ja) * | 1983-11-15 | 1986-03-13 | リチウム・コ−ポレ−ション・オブ・アメリカ | アルカリ土類金属有機金属化合物の製造方法 |
| JPS60181104A (ja) * | 1984-02-28 | 1985-09-14 | Toa Nenryo Kogyo Kk | オレフイン重合用触媒成分の製造方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012171957A (ja) * | 2011-02-18 | 2012-09-10 | Colcoat Kk | 混合マグネシウムジアルコキシド粒状物、その合成方法およびその利用方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE391114T1 (de) | 2008-04-15 |
| EP1541540B1 (de) | 2008-04-02 |
| EP1541540A1 (de) | 2005-06-15 |
| US20080071119A1 (en) | 2008-03-20 |
| PL1541540T3 (pl) | 2008-09-30 |
| US20050159630A1 (en) | 2005-07-21 |
| ES2303012T3 (es) | 2008-08-01 |
| DE10358412A1 (de) | 2005-07-07 |
| DE502004006713D1 (de) | 2008-05-15 |
| CN1651375A (zh) | 2005-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10745421B2 (en) | Method for producing alkyl-indium compounds and the use thereof | |
| TWI525039B (zh) | 氫矽烷類的製備方法 | |
| US20080071119A1 (en) | Process for preparing alkoxy-pure alkaline-earth alkoxides | |
| KR102109904B1 (ko) | 트리알킬갈륨 화합물의 제조 방법 | |
| JP2006347874A (ja) | ドデカヒドロドデカボレート塩の製造方法 | |
| EP3275886B1 (de) | Verfahren zur herstellung von dialkylaminosilan | |
| US9840523B2 (en) | Process of synthesizing diisopropylamino-disilanes | |
| KR102044434B1 (ko) | 불포화 결합 함유 실란 화합물의 정제 방법 및 제조 방법 | |
| JP2020037592A (ja) | トリアルキルガリウム化合物の調製及びその使用 | |
| JP2005170946A (ja) | アルコキシ純粋なアルカリ土類金属アルコキシドの製造方法 | |
| US20140364639A1 (en) | Method for preparing trialkoxysilane | |
| US8148286B2 (en) | Activated alkaline earth metal, in particular magnesium, for the preparation of organoalkaline earth metal compounds | |
| JP5529591B2 (ja) | 多座β−ケトイミネートの金属錯体の調製方法 | |
| CN104926848B (zh) | 一种制备甲基硼酸的方法 | |
| CA2935420C (en) | Method for producing aprotic solutions that contain zinc bromide and lithium bromide | |
| CN111655708B (zh) | 2,3－双膦基吡嗪衍生物、其制造方法、配位化合物和催化剂、有机硼化合物的制造方法 | |
| JP6107389B2 (ja) | トリス（ジアルキルアミド）アルミニウム化合物の製造方法 | |
| JPH085899B2 (ja) | アルコキシシランの製造法 | |
| CN117700326A (zh) | 一种催化氨基甲酸酯类化合物氢化裂解的方法及氮膦三齿配体钌催化剂的制备方法 | |
| CN116946989A (zh) | 一种磷烷/氘代磷烷及其衍生物的制备方法 | |
| US10059599B2 (en) | Synthesis of borane compounds | |
| KR20150059456A (ko) | 3-메틸-3-부텐-1-올의 제조 방법 | |
| CN102939156A (zh) | 在含氧供体的溶剂或溶剂混合物中的路易斯酸溶液 | |
| JPH05310764A (ja) | 高純度モノアルキルまたはモノアリ−ルアルシン化合物の製造方法 | |
| JPH05506641A (ja) | ラクトン由来の２，２―ジアルコキシサイクリックオルトエステルの製造 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070927 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100804 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101102 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101108 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101202 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101207 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101228 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20101228 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110106 |
|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20110203 |