JP2004537584A5 - - Google Patents
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- JP2004537584A5 JP2004537584A5 JP2003519002A JP2003519002A JP2004537584A5 JP 2004537584 A5 JP2004537584 A5 JP 2004537584A5 JP 2003519002 A JP2003519002 A JP 2003519002A JP 2003519002 A JP2003519002 A JP 2003519002A JP 2004537584 A5 JP2004537584 A5 JP 2004537584A5
- Authority
- JP
- Japan
- Prior art keywords
- iii
- hydrocarbyl
- substituted
- heterohydrocarbyl
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims 23
- 238000000034 method Methods 0.000 claims 21
- 239000003054 catalyst Substances 0.000 claims 13
- -1 Alkyl zinc compound Chemical class 0.000 claims 11
- 229910052736 halogen Inorganic materials 0.000 claims 11
- 150000002367 halogens Chemical class 0.000 claims 11
- 229910052739 hydrogen Inorganic materials 0.000 claims 11
- 239000001257 hydrogen Substances 0.000 claims 11
- 229910052723 transition metal Inorganic materials 0.000 claims 11
- 150000003624 transition metals Chemical class 0.000 claims 11
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 10
- 239000011701 zinc Substances 0.000 claims 10
- 239000010936 titanium Substances 0.000 claims 9
- 125000000524 functional group Chemical group 0.000 claims 8
- 125000004432 carbon atom Chemical group C* 0.000 claims 7
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 239000004711 α-olefin Substances 0.000 claims 6
- 125000004429 atom Chemical group 0.000 claims 5
- 229910052725 zinc Inorganic materials 0.000 claims 5
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 4
- 229910052768 actinide Inorganic materials 0.000 claims 4
- 150000001255 actinides Chemical class 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 4
- 229910052747 lanthanoid Inorganic materials 0.000 claims 4
- 150000002602 lanthanoids Chemical class 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 3
- 239000012190 activator Substances 0.000 claims 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 3
- 239000012968 metallocene catalyst Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 230000003647 oxidation Effects 0.000 claims 3
- 238000007254 oxidation reaction Methods 0.000 claims 3
- 229910052698 phosphorus Inorganic materials 0.000 claims 3
- BEZVGIHGZPLGBL-UHFFFAOYSA-N 2,6-diacetylpyridine Chemical group CC(=O)C1=CC=CC(C(C)=O)=N1 BEZVGIHGZPLGBL-UHFFFAOYSA-N 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 150000004703 alkoxides Chemical class 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 150000004696 coordination complex Chemical class 0.000 claims 2
- 125000004122 cyclic group Chemical group 0.000 claims 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 2
- 239000003446 ligand Substances 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- FOKGVHRHBBEPPI-UHFFFAOYSA-K 1,2,3,4,5-pentamethylcyclopentane;trichlorozirconium Chemical compound Cl[Zr](Cl)Cl.C[C]1[C](C)[C](C)[C](C)[C]1C FOKGVHRHBBEPPI-UHFFFAOYSA-K 0.000 claims 1
- WCGXJPFHTHQNJL-UHFFFAOYSA-N 1-[5-ethyl-2-hydroxy-4-[6-methyl-6-(2H-tetrazol-5-yl)heptoxy]phenyl]ethanone Chemical compound CCC1=CC(C(C)=O)=C(O)C=C1OCCCCCC(C)(C)C1=NNN=N1 WCGXJPFHTHQNJL-UHFFFAOYSA-N 0.000 claims 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims 1
- AJKVQEKCUACUMD-UHFFFAOYSA-N 2-Acetylpyridine Chemical compound CC(=O)C1=CC=CC=N1 AJKVQEKCUACUMD-UHFFFAOYSA-N 0.000 claims 1
- VVNYDCGZZSTUBC-UHFFFAOYSA-N 5-amino-2-[(2-methylpropan-2-yl)oxycarbonylamino]-5-oxopentanoic acid Chemical compound CC(C)(C)OC(=O)NC(C(O)=O)CCC(N)=O VVNYDCGZZSTUBC-UHFFFAOYSA-N 0.000 claims 1
- MQNPENQYQXUCOX-UHFFFAOYSA-N C=1C=CC=CC=1C[Zn]CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1C[Zn]CC1=CC=CC=C1 MQNPENQYQXUCOX-UHFFFAOYSA-N 0.000 claims 1
- LHHAUUVITWQDQI-UHFFFAOYSA-L CC1=C(C)C(C)(C(C)=C1C)[Zr](Cl)(Cl)C1C=CC=C1 Chemical compound CC1=C(C)C(C)(C(C)=C1C)[Zr](Cl)(Cl)C1C=CC=C1 LHHAUUVITWQDQI-UHFFFAOYSA-L 0.000 claims 1
- AYEXPZYTCYCMPE-UHFFFAOYSA-N CCCCCCCCCCCC[Zn]CCCCCCCCCCCC Chemical compound CCCCCCCCCCCC[Zn]CCCCCCCCCCCC AYEXPZYTCYCMPE-UHFFFAOYSA-N 0.000 claims 1
- QGAXJIMCDCDTDX-UHFFFAOYSA-N CCCCCCCCCC[Zn]CCCCCCCCCC Chemical compound CCCCCCCCCC[Zn]CCCCCCCCCC QGAXJIMCDCDTDX-UHFFFAOYSA-N 0.000 claims 1
- JUOCTSZRGAFSKS-UHFFFAOYSA-N CCCCCC[Zn]CCCCCC Chemical compound CCCCCC[Zn]CCCCCC JUOCTSZRGAFSKS-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- MIILMDFFARLWKZ-UHFFFAOYSA-L dichlorozirconium;1,2,3,4,5-pentamethylcyclopentane Chemical group [Cl-].[Cl-].CC1=C(C)C(C)=C(C)C1(C)[Zr+2]C1(C)C(C)=C(C)C(C)=C1C MIILMDFFARLWKZ-UHFFFAOYSA-L 0.000 claims 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- AXAZMDOAUQTMOW-UHFFFAOYSA-N dimethylzinc Chemical compound C[Zn]C AXAZMDOAUQTMOW-UHFFFAOYSA-N 0.000 claims 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims 1
- 150000003138 primary alcohols Chemical class 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- HEPBQSXQJMTVFI-UHFFFAOYSA-N zinc;butane Chemical compound [Zn+2].CCC[CH2-].CCC[CH2-] HEPBQSXQJMTVFI-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/921,695 US7087686B2 (en) | 2001-08-06 | 2001-08-06 | Chain growth reaction process |
| PCT/GB2002/003096 WO2003014046A1 (en) | 2001-08-06 | 2002-07-05 | Chain growth reaction process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004537584A JP2004537584A (ja) | 2004-12-16 |
| JP2004537584A5 true JP2004537584A5 (enExample) | 2006-01-05 |
Family
ID=25445836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003519002A Pending JP2004537584A (ja) | 2001-08-06 | 2002-07-05 | 連鎖生長反応方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US7087686B2 (enExample) |
| EP (2) | EP1414772B1 (enExample) |
| JP (1) | JP2004537584A (enExample) |
| KR (1) | KR100895599B1 (enExample) |
| CN (2) | CN101070261B (enExample) |
| CA (1) | CA2456711C (enExample) |
| EA (2) | EA007922B1 (enExample) |
| ES (2) | ES2623164T3 (enExample) |
| MY (1) | MY143732A (enExample) |
| WO (1) | WO2003014046A1 (enExample) |
Families Citing this family (89)
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-
2001
- 2001-08-06 US US09/921,695 patent/US7087686B2/en not_active Expired - Lifetime
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2002
- 2002-07-05 ES ES02745584.9T patent/ES2623164T3/es not_active Expired - Lifetime
- 2002-07-05 EP EP02745584.9A patent/EP1414772B1/en not_active Expired - Lifetime
- 2002-07-05 CA CA2456711A patent/CA2456711C/en not_active Expired - Lifetime
- 2002-07-05 CN CN2007101264295A patent/CN101070261B/zh not_active Expired - Lifetime
- 2002-07-05 JP JP2003519002A patent/JP2004537584A/ja active Pending
- 2002-07-05 ES ES10179957T patent/ES2711251T3/es not_active Expired - Lifetime
- 2002-07-05 WO PCT/GB2002/003096 patent/WO2003014046A1/en not_active Ceased
- 2002-07-05 EP EP10179957.5A patent/EP2308815B1/en not_active Expired - Lifetime
- 2002-07-05 CN CNB028194128A patent/CN100457695C/zh not_active Expired - Lifetime
- 2002-07-05 KR KR1020047001907A patent/KR100895599B1/ko not_active Expired - Fee Related
- 2002-07-05 EA EA200400255A patent/EA007922B1/ru not_active IP Right Cessation
- 2002-07-05 EA EA200601455A patent/EA011711B1/ru not_active IP Right Cessation
- 2002-08-02 MY MYPI20022909A patent/MY143732A/en unknown
-
2006
- 2006-06-28 US US11/476,206 patent/US7767771B2/en not_active Expired - Fee Related
-
2007
- 2007-01-31 US US11/700,111 patent/US7964681B2/en not_active Expired - Fee Related
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