JP2004529254A5 - - Google Patents
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- JP2004529254A5 JP2004529254A5 JP2003503675A JP2003503675A JP2004529254A5 JP 2004529254 A5 JP2004529254 A5 JP 2004529254A5 JP 2003503675 A JP2003503675 A JP 2003503675A JP 2003503675 A JP2003503675 A JP 2003503675A JP 2004529254 A5 JP2004529254 A5 JP 2004529254A5
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- JP
- Japan
- Prior art keywords
- group
- alkyl
- formula
- saturated
- periodic table
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 10
- 230000000737 periodic effect Effects 0.000 claims 9
- 229920006395 saturated elastomer Polymers 0.000 claims 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims 8
- 125000005842 heteroatom Chemical group 0.000 claims 8
- 125000002877 alkyl aryl group Chemical group 0.000 claims 7
- 125000003710 aryl alkyl group Chemical group 0.000 claims 7
- 125000003118 aryl group Chemical group 0.000 claims 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- 125000003968 arylidene group Chemical group [H]C(c)=* 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 125000001118 alkylidene group Chemical group 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- -1 ethylene, propylene Chemical group 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 125000004434 sulfur atom Chemical group 0.000 claims 1
- 150000003624 transition metals Chemical group 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 15
- OSCBARYHPZZEIS-UHFFFAOYSA-N phenoxyboronic acid Chemical compound OB(O)OC1=CC=CC=C1 OSCBARYHPZZEIS-UHFFFAOYSA-N 0.000 description 9
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 7
- IMFACGCPASFAPR-UHFFFAOYSA-O tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-O 0.000 description 6
- 150000004645 aluminates Chemical class 0.000 description 5
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 4
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 4
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 description 3
- HTGQCLJTWPSFNL-UHFFFAOYSA-N (2-methylphenoxy)boronic acid Chemical compound CC1=CC=CC=C1OB(O)O HTGQCLJTWPSFNL-UHFFFAOYSA-N 0.000 description 2
- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical compound [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 description 2
- LKWLQPNRJQQVEB-UHFFFAOYSA-N (2,3-dimethylphenoxy)boronic acid Chemical compound CC1=CC=CC(OB(O)O)=C1C LKWLQPNRJQQVEB-UHFFFAOYSA-N 0.000 description 1
- PHBVXHIVWULVNF-UHFFFAOYSA-N (4-fluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC=C(F)C=C1 PHBVXHIVWULVNF-UHFFFAOYSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- UVSSPWOKVSKHCU-UHFFFAOYSA-N [2-(trifluoromethyl)phenoxy]boronic acid Chemical compound OB(O)OC1=CC=CC=C1C(F)(F)F UVSSPWOKVSKHCU-UHFFFAOYSA-N 0.000 description 1
- GGSUCNLOZRCGPQ-UHFFFAOYSA-O diethyl(phenyl)azanium Chemical compound CC[NH+](CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-O 0.000 description 1
- GPAYUJZHTULNBE-UHFFFAOYSA-O diphenylphosphanium Chemical compound C=1C=CC=CC=1[PH2+]C1=CC=CC=C1 GPAYUJZHTULNBE-UHFFFAOYSA-O 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- RXJKFRMDXUJTEX-UHFFFAOYSA-O triethylphosphanium Chemical compound CC[PH+](CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-O 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- GIIXTFIYICRGMZ-UHFFFAOYSA-N tris(2,3-dimethylphenyl)phosphane Chemical compound CC1=CC=CC(P(C=2C(=C(C)C=CC=2)C)C=2C(=C(C)C=CC=2)C)=C1C GIIXTFIYICRGMZ-UHFFFAOYSA-N 0.000 description 1
- COIOYMYWGDAQPM-UHFFFAOYSA-N tris(2-methylphenyl)phosphane Chemical compound CC1=CC=CC=C1P(C=1C(=CC=CC=1)C)C1=CC=CC=C1C COIOYMYWGDAQPM-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01202263 | 2001-06-12 | ||
| PCT/EP2002/006575 WO2002100909A1 (en) | 2001-06-12 | 2002-06-11 | Process for the polymerization of 1-butene |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004529254A JP2004529254A (ja) | 2004-09-24 |
| JP2004529254A5 true JP2004529254A5 (https=) | 2006-01-05 |
| JP4332029B2 JP4332029B2 (ja) | 2009-09-16 |
Family
ID=8180466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003503675A Expired - Fee Related JP4332029B2 (ja) | 2001-06-12 | 2002-06-11 | １−ブテンの重合方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US7074864B2 (https=) |
| EP (1) | EP1446429B1 (https=) |
| JP (1) | JP4332029B2 (https=) |
| AT (1) | ATE444975T1 (https=) |
| DE (1) | DE60233961D1 (https=) |
| WO (1) | WO2002100909A1 (https=) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1446429B1 (en) | 2001-06-12 | 2009-10-07 | Basell Polyolefine GmbH | Process for the polymerization of 1-butene |
| US7459511B2 (en) | 2001-06-12 | 2008-12-02 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| WO2003008496A1 (en) * | 2001-07-17 | 2003-01-30 | Basell Polyolefine Gmbh | Multistep process for the (co)polymerization of olefins |
| US7019157B2 (en) * | 2001-08-06 | 2006-03-28 | Chisso Corporation | Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process |
| WO2003045964A1 (en) * | 2001-11-30 | 2003-06-05 | Basell Polyolefine Gmbh | Metallocene compounds and process for the preparation of propylene polymers |
| WO2004022613A1 (en) * | 2002-09-06 | 2004-03-18 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| JP2006502260A (ja) * | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| AU2003296585A1 (en) * | 2002-12-04 | 2004-06-23 | Basell Polyolefine Gmbh | 1-buten copolymers and process for preparing them |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| US7390862B2 (en) * | 2003-05-12 | 2008-06-24 | Basell Polyolefine Gmbh | Process for polymerizing 1-butene |
| JP2007528925A (ja) * | 2004-03-12 | 2007-10-18 | バセル ポリオレフィン ジーエムビーエイチ | １−ヘキセンまたは高級α−オレフィンの重合方法 |
| ATE445650T1 (de) * | 2004-05-04 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von ataktischen 1- butenpolymeren |
| WO2006005648A1 (en) | 2004-07-13 | 2006-01-19 | Basell Polyolefine Gmbh | Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom |
| JP2008506825A (ja) | 2004-07-22 | 2008-03-06 | バーゼル・ポリオレフィン・ゲーエムベーハー | フラクション化可能な１−ブテンポリマー類の製造法 |
| ATE388994T1 (de) | 2004-07-22 | 2008-03-15 | Basell Polyolefine Gmbh | 1-butenpolymerzusammensetzung |
| PL1805231T3 (pl) | 2004-10-18 | 2010-08-31 | Basell Poliolefine Italia Srl | (Ko)polimery butenu-1 o niskiej izotaktyczności |
| EP1802669B1 (en) | 2004-10-21 | 2011-03-09 | Basell Polyolefine GmbH | 1-butene polymer and process for the preparation thereof |
| US8051611B2 (en) * | 2005-06-24 | 2011-11-08 | Dryvit Systems, Inc. | Exterior insulation and finish system and method and tool for installing same |
| JP5580590B2 (ja) * | 2006-08-30 | 2014-08-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンプロピレンコポリマー組成物 |
| WO2008025710A1 (en) * | 2006-08-30 | 2008-03-06 | Basell Polyolefine Gmbh | 1-butene propylene copolymer compositions |
| DE102008005949A1 (de) * | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Polyolefine mit Isotaktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung |
| EP2254917A1 (en) * | 2008-03-20 | 2010-12-01 | Basell Poliolefine Italia S.R.L. | 1-butene copolymers |
| ATE543870T1 (de) * | 2008-03-20 | 2012-02-15 | Basell Poliolefine Srl | Zusammensetzungen aus polymeren auf 1-buten-basis |
| JP2011515517A (ja) * | 2008-03-20 | 2011-05-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | １−ブテンコポリマー |
| EP2254918A1 (en) * | 2008-03-20 | 2010-12-01 | Basell Poliolefine Italia S.R.L. | 1-butene terpolymers |
| ES2758928T3 (es) | 2012-09-14 | 2020-05-07 | Mitsui Chemicals Inc | Copolímero de 1-buteno/alfa-olefina y composición que lo contiene |
| CN115991804A (zh) * | 2021-10-20 | 2023-04-21 | 中国石油化工股份有限公司 | 聚1-丁烯及其制备方法 |
Family Cites Families (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US376409A (en) * | 1888-01-10 | Adolf kaysee | ||
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| JPS60262804A (ja) | 1984-06-11 | 1985-12-26 | Mitsui Petrochem Ind Ltd | ポリ１−ブテン樹脂 |
| DE3474673D1 (en) | 1984-08-30 | 1988-11-24 | Mitsui Petrochemical Ind | 1-butene polymer and its use |
| JPH0816133B2 (ja) * | 1987-03-14 | 1996-02-21 | 出光石油化学株式会社 | ブテン−１共重合体 |
| AU6158390A (en) | 1989-08-03 | 1991-03-11 | Exxon Chemical Patents Inc. | Very high molecular weight polyethylene |
| JPH03126704A (ja) * | 1989-10-11 | 1991-05-29 | Idemitsu Petrochem Co Ltd | パイプ用ポリブテン‐１および樹脂パイプ |
| RU2118203C1 (ru) | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов |
| ES2071888T3 (es) | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| DE59107926D1 (de) | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| TW294669B (https=) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| DE4333128A1 (de) | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
| DE4344689A1 (de) | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| IT1269837B (it) | 1994-05-26 | 1997-04-15 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| JP3338190B2 (ja) | 1994-08-17 | 2002-10-28 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
| JP3540431B2 (ja) * | 1994-12-20 | 2004-07-07 | 三井化学株式会社 | ポリ１−ブテンの製造方法 |
| US6399533B2 (en) | 1995-05-25 | 2002-06-04 | Basell Technology Company Bv | Compounds and catalysts for the polymerization of olefins |
| JP3281389B2 (ja) | 1995-06-08 | 2002-05-13 | 昭和電工株式会社 | イオン性化合物およびその化合物を用いたオレフィン重合用触媒 |
| TR199901635T2 (xx) | 1996-11-15 | 2000-02-21 | Montell Technology Company Bv | Heterosiklik metalosenler ve polimerizasyon kataliz�rleri. |
| EP0846696B1 (en) | 1996-12-09 | 2003-06-18 | Mitsubishi Chemical Corporation | Catalyst for polymerization of alpha-olefins |
| KR100624632B1 (ko) * | 1997-03-07 | 2006-09-15 | 타고르 게엠베하 | 메탈로센 및 그의 제조 방법 |
| US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
| CA2283880A1 (en) * | 1998-01-14 | 1999-07-22 | Montell Technology Company B.V. | Process for the preparation of metallocene compounds |
| DE19804970A1 (de) | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
| EP0980396B2 (en) | 1998-03-05 | 2009-08-19 | Basell Poliolefine Italia S.r.l. | Polybutene-1 (co)polymers and process for their preparation |
| CA2294239A1 (en) * | 1998-04-21 | 1999-10-28 | Montell Technology Company B.V. | Process for the preparation of copolymers of ethylene with alpha-olefins |
| DE19903306A1 (de) | 1999-01-28 | 2000-08-03 | Targor Gmbh | Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung |
| DE19917985A1 (de) | 1999-04-21 | 2000-10-26 | Targor Gmbh | Katalysatorsystem |
| EP1074557A3 (de) | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
| BR0014616A (pt) | 1999-09-22 | 2002-06-18 | Basell Technology Co Bv | Sistema catalìtico e processo para a polimerização de olefinas |
| US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| DE19962910A1 (de) | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| DE19962814A1 (de) | 1999-12-23 | 2001-06-28 | Targor Gmbh | Neues Katalysatorsystem und dessen Verwendung |
| BRPI0016723B1 (pt) | 1999-12-23 | 2018-02-27 | Basell Polyolefine Gmbh. | Metaloceno, sistema catalisador, e, processo para a copolimerização de propileno com etileno |
| WO2001062764A1 (en) | 2000-02-24 | 2001-08-30 | Basell Technology Company B.V. | Organometallic compound useful as cocatalyst for polymerizing olefins |
| KR100765398B1 (ko) * | 2000-07-03 | 2007-10-11 | 미쓰이 가가쿠 가부시키가이샤 | 부텐계 공중합체, 이 공중합체를 함유하는 수지 조성물,이 조성물의 성형체, 이 공중합체 제조용 고체상 티탄촉매 및 이 촉매의 제조 방법 |
| ATE394407T1 (de) | 2001-04-10 | 2008-05-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von mono oder bis halogensubstituierten metallozenverbindungen |
| DE60202524T2 (de) | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
| US7459511B2 (en) * | 2001-06-12 | 2008-12-02 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| EP1446429B1 (en) * | 2001-06-12 | 2009-10-07 | Basell Polyolefine GmbH | Process for the polymerization of 1-butene |
| ATE321061T1 (de) | 2001-06-22 | 2006-04-15 | Basell Polyolefine Gmbh | Metallocene, verwendung in katalysatoren für olefinpolymerisation |
| WO2003008496A1 (en) | 2001-07-17 | 2003-01-30 | Basell Polyolefine Gmbh | Multistep process for the (co)polymerization of olefins |
| JP2005501841A (ja) | 2001-08-01 | 2005-01-20 | バセル ポリオレフィン ジーエムビーエイチ | 複素環式ペンタレン誘導体の製造方法 |
| WO2003045964A1 (en) | 2001-11-30 | 2003-06-05 | Basell Polyolefine Gmbh | Metallocene compounds and process for the preparation of propylene polymers |
| JP2005517773A (ja) | 2002-02-25 | 2005-06-16 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| WO2004022613A1 (en) * | 2002-09-06 | 2004-03-18 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
-
2002
- 2002-06-11 EP EP02743196A patent/EP1446429B1/en not_active Expired - Lifetime
- 2002-06-11 AT AT02743196T patent/ATE444975T1/de not_active IP Right Cessation
- 2002-06-11 US US10/479,328 patent/US7074864B2/en not_active Expired - Lifetime
- 2002-06-11 JP JP2003503675A patent/JP4332029B2/ja not_active Expired - Fee Related
- 2002-06-11 DE DE60233961T patent/DE60233961D1/de not_active Expired - Lifetime
- 2002-06-11 WO PCT/EP2002/006575 patent/WO2002100909A1/en not_active Ceased
-
2006
- 2006-03-15 US US11/376,406 patent/US7476717B2/en not_active Expired - Lifetime
- 2006-03-15 US US11/376,409 patent/US7619051B2/en not_active Expired - Lifetime
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