JP2004250690A5

JP2004250690A5 -

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Publication number: JP2004250690A5
Authority: JP; Japan
Prior art keywords: acid; extract; fullerene; skin; derivatives
Prior art date: 2004-01-27
Legal status : Granted

Application number

JP2004019081A

Other languages

English (en)

Japanese (ja)

Other versions

JP4360925B2 (ja

JP2004250690A (ja

Filing date

2004-01-27

Publication date

2007-02-01

2004-01-27 Application filed filed Critical

2004-01-27 Priority to JP2004019081A priority Critical patent/JP4360925B2/ja

2004-01-27 Priority claimed from JP2004019081A external-priority patent/JP4360925B2/ja

2004-09-09 Publication of JP2004250690A publication Critical patent/JP2004250690A/ja

2007-02-01 Publication of JP2004250690A5 publication Critical patent/JP2004250690A5/ja

2009-11-11 Application granted granted Critical

2009-11-11 Publication of JP4360925B2 publication Critical patent/JP4360925B2/ja

2024-01-27 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

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229910003472 fullerene Inorganic materials 0.000 description 128
239000000284 extract Substances 0.000 description 123
-1 Lipid peroxide Chemical class 0.000 description 121
OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 105
239000000203 mixture Substances 0.000 description 77
239000011780 sodium chloride Substances 0.000 description 60
235000002639 sodium chloride Nutrition 0.000 description 60
150000003839 salts Chemical class 0.000 description 56
MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 54
210000003491 Skin Anatomy 0.000 description 52
229920003171 Poly (ethylene oxide) Polymers 0.000 description 50
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
230000000694 effects Effects 0.000 description 46
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 42
235000014113 dietary fatty acids Nutrition 0.000 description 37
239000000194 fatty acid Substances 0.000 description 37
239000000843 powder Substances 0.000 description 33
229960005070 ascorbic acid Drugs 0.000 description 28
239000003921 oil Substances 0.000 description 28
235000019198 oils Nutrition 0.000 description 28
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Vitamin C Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 27
235000019441 ethanol Nutrition 0.000 description 25
LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
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239000011668 ascorbic acid Substances 0.000 description 18
239000003795 chemical substances by application Substances 0.000 description 18
239000006210 lotion Substances 0.000 description 17
238000002360 preparation method Methods 0.000 description 17
RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl radical Chemical class [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 16
229920000642 polymer Polymers 0.000 description 16
QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 15
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125000002887 hydroxy group Chemical group [H]O* 0.000 description 15
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BVDRUCCQKHGCRX-UHFFFAOYSA-N 2,3-dihydroxypropyl formate Chemical compound OCC(O)COC=O BVDRUCCQKHGCRX-UHFFFAOYSA-N 0.000 description 14
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239000002253 acid Substances 0.000 description 11
230000002000 scavenging Effects 0.000 description 11
OUUQCZGPVNCOIJ-UHFFFAOYSA-M superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 11
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235000000069 L-ascorbic acid Nutrition 0.000 description 10
150000001298 alcohols Chemical class 0.000 description 10
150000004665 fatty acids Chemical class 0.000 description 10
DFPAKSUCGFBDDF-UHFFFAOYSA-N nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 10
CIHOLLKRGTVIJN-UHFFFAOYSA-N tBuOOH Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 10
HVYWMOMLDIMFJA-DPAQBDIFSA-N (3β)-Cholest-5-en-3-ol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 9
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229940083542 Sodium Drugs 0.000 description 8
OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
150000007524 organic acids Chemical class 0.000 description 8
KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 8
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239000008117 stearic acid Substances 0.000 description 8
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
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VYGQUTWHTHXGQB-FFHKNEKCSA-N trans-Retinyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C VYGQUTWHTHXGQB-FFHKNEKCSA-N 0.000 description 8
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210000000170 Cell Membrane Anatomy 0.000 description 7
IPCSVZSSVZVIGE-UHFFFAOYSA-N Palmitic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 7
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MIJPAVRNWPDMOR-ZAFYKAAXSA-K [(2R)-2-[(1S)-1,2-dihydroxyethyl]-3-oxido-5-oxo-2H-furan-4-yl] phosphate Chemical compound OC[C@H](O)[C@H]1OC(=O)C(OP([O-])([O-])=O)=C1[O-] MIJPAVRNWPDMOR-ZAFYKAAXSA-K 0.000 description 7
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FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 7
239000007864 aqueous solution Substances 0.000 description 7
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XMWRBQBLMFGWIX-UHFFFAOYSA-N Buckminsterfullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 6
229920000858 Cyclodextrin Polymers 0.000 description 6
206010013786 Dry skin Diseases 0.000 description 6
210000002510 Keratinocytes Anatomy 0.000 description 6
POULHZVOKOAJMA-UHFFFAOYSA-N Lauric acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 6
AUNGANRZJHBGPY-OUCADQQQSA-N Riboflavin Natural products OC[C@@H](O)[C@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-OUCADQQQSA-N 0.000 description 6
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210000004927 Skin cells Anatomy 0.000 description 6
JNYAEWCLZODPBN-CTQIIAAMSA-N Sorbitan Chemical compound OCC(O)C1OCC(O)[C@@H]1O JNYAEWCLZODPBN-CTQIIAAMSA-N 0.000 description 6
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NWGKJDSIEKMTRX-HSACVWGTSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] (E)-octadec-9-enoate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-HSACVWGTSA-N 0.000 description 6
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FWKQNCXZGNBPFD-UHFFFAOYSA-N 1,4-dimethyl-7-(1-methylethyl)azulene Chemical compound CC(C)C1=CC=C(C)C2=CC=C(C)C2=C1 FWKQNCXZGNBPFD-UHFFFAOYSA-N 0.000 description 4
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JP2004019081A 2003-01-27 2004-01-27 外用組成物 Expired - Lifetime JP4360925B2 (ja)