JP2003518146A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2003518146A5 JP2003518146A5 JP2001531892A JP2001531892A JP2003518146A5 JP 2003518146 A5 JP2003518146 A5 JP 2003518146A5 JP 2001531892 A JP2001531892 A JP 2001531892A JP 2001531892 A JP2001531892 A JP 2001531892A JP 2003518146 A5 JP2003518146 A5 JP 2003518146A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst system
- metallocene
- phenyl
- contacting
- fluorenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 description 9
- 239000012968 metallocene catalyst Substances 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- -1 silylene group Chemical group 0.000 description 4
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N C1CCCCC1 Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- JYOWZBJHFGPDIK-ULUSZKPHSA-N C[C@](C1)(CC2)C12[I](C)N Chemical compound C[C@](C1)(CC2)C12[I](C)N JYOWZBJHFGPDIK-ULUSZKPHSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000005103 alkyl silyl group Chemical group 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- SINKOGOPEQSHQD-UHFFFAOYSA-N cyclopentadienide Chemical class C=1C=C[CH-]C=1 SINKOGOPEQSHQD-UHFFFAOYSA-N 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/422,533 US6300433B1 (en) | 1998-10-23 | 1999-10-21 | Olefin copolymerization process with bridged hafnocenes |
| US09/422,533 | 1999-10-21 | ||
| PCT/US2000/029197 WO2001029096A1 (en) | 1999-10-21 | 2000-10-23 | High activity carbenium-activated polymerization catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003518146A JP2003518146A (ja) | 2003-06-03 |
| JP2003518146A5 true JP2003518146A5 (enExample) | 2007-12-13 |
Family
ID=23675314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001531892A Withdrawn JP2003518146A (ja) | 1999-10-21 | 2000-10-23 | 高活性のカルベニウム活性化重合触媒 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6300433B1 (enExample) |
| EP (1) | EP1259553B1 (enExample) |
| JP (1) | JP2003518146A (enExample) |
| KR (1) | KR20020040905A (enExample) |
| CN (1) | CN1376168A (enExample) |
| AT (1) | ATE286921T1 (enExample) |
| BR (1) | BR0014119A (enExample) |
| CA (1) | CA2397818A1 (enExample) |
| DE (1) | DE60017467T2 (enExample) |
| ES (1) | ES2233471T3 (enExample) |
| MX (1) | MXPA02003940A (enExample) |
| WO (1) | WO2001029096A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7232871B2 (en) * | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| BR9914717A (pt) * | 1998-10-23 | 2001-07-10 | Exxonmobil Chem Patents Inc | Matalocenos em ponte para copolimerização de olefinas |
| US6825295B2 (en) * | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| KR100884294B1 (ko) * | 2001-02-08 | 2009-02-18 | 미쓰이 가가쿠 가부시키가이샤 | 에틸렌과 탄소수 3 ~ 20의 α-올레핀의 랜덤 공중합체와 그것을 사용한 성형품 |
| ATE485319T1 (de) | 2001-04-12 | 2010-11-15 | Exxonmobil Chem Patents Inc | Verfahren zur polymerisation von propylen und ethylen in lösung |
| WO2003000740A2 (en) | 2001-06-20 | 2003-01-03 | Exxonmobil Chemical Patents Inc. | Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them |
| KR100785840B1 (ko) * | 2002-09-27 | 2007-12-13 | 미쓰이 가가쿠 가부시키가이샤 | 가교 메탈로센 화합물, 올레핀 중합 촉매 및 올레핀의 중합방법 |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US8263722B2 (en) * | 2004-03-24 | 2012-09-11 | Exxonmobil Chemical Patents Inc. | Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers |
| KR101141359B1 (ko) * | 2005-09-09 | 2012-05-03 | 에스케이이노베이션 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계 |
| EP1934266B1 (en) * | 2005-09-09 | 2015-11-18 | SABIC SK Nexlene Company Pte. Ltd. | Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins |
| SG169377A1 (en) | 2006-03-02 | 2011-03-30 | Exxonmobil Chem Patents Inc | Process for producing propylene copolymers |
| JP4714088B2 (ja) * | 2006-06-16 | 2011-06-29 | 株式会社小糸製作所 | 車両用前照灯 |
| US7872086B2 (en) | 2008-01-17 | 2011-01-18 | Tonen Chemical Corporation | Polymeric material and its manufacture and use |
| EP2287145A1 (en) | 2009-08-12 | 2011-02-23 | BP p.l.c. | Process for purifying ethylene |
| JP6492018B2 (ja) | 2014-02-13 | 2019-03-27 | 三井化学株式会社 | エチレン／α−オレフィン共重合体の製造方法 |
| US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
| US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
| US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
| KR102872215B1 (ko) | 2022-07-05 | 2025-10-16 | 한화토탈에너지스 주식회사 | 신규한 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물 및 이를 이용한 에틸렌 및 α-올레핀의 공중합체의 제조방법 |
| KR20250026547A (ko) * | 2023-08-17 | 2025-02-25 | 한화솔루션 주식회사 | 전이금속 화합물을 이용한 에틸렌-α-올레핀 공중합체의 용액중합방법 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
| ATE137247T1 (de) * | 1989-10-30 | 1996-05-15 | Fina Technology | Addition von alkylaluminium zum verbessern eines metallocenkatalysators |
| US6313240B1 (en) * | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
| US6008307A (en) * | 1994-04-28 | 1999-12-28 | Exxon Chemical Patents Inc | Process for producing olefin polymers using cationic catalysts |
| DE69511352T2 (de) * | 1994-10-03 | 2000-03-30 | Sumitomo Chemical Co., Ltd. | Verfahren zur Herstellung eines Copolymerkautschuks |
| JPH08208736A (ja) * | 1994-11-28 | 1996-08-13 | Chisso Corp | 塩化ビニル系樹脂の製造方法 |
| ATE233790T1 (de) | 1995-03-10 | 2003-03-15 | Dow Global Technologies Inc | Geträgerter katalysatorbestandteil, trägerkatalysator, herstellungsverfahren, polymerisationsverfahren, komplexverbindungen und ihre herstellung |
| US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| US5767208A (en) | 1995-10-20 | 1998-06-16 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| WO1997022639A1 (en) * | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature solution polymerization process |
| EP0786466B1 (en) | 1996-01-25 | 2003-04-16 | Tosoh Corporation | Olefin polymerisation process which comprises a transition metal catalyst. |
| US5856256A (en) | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
| DE59703850D1 (de) | 1996-08-13 | 2001-07-26 | Basell Polyolefine Gmbh | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| ES2190197T3 (es) | 1998-03-03 | 2003-07-16 | Aquasol Ltd | Peliculas solubles en agua. |
| DE69924712T2 (de) * | 1998-03-04 | 2006-03-09 | Exxonmobil Chemical Patents Inc., Baytown | Nicht koordinierende anionen für die polymerisation von olefinen |
-
1999
- 1999-10-21 US US09/422,533 patent/US6300433B1/en not_active Expired - Lifetime
-
2000
- 2000-10-23 CA CA002397818A patent/CA2397818A1/en not_active Abandoned
- 2000-10-23 AT AT00973781T patent/ATE286921T1/de not_active IP Right Cessation
- 2000-10-23 KR KR1020027005129A patent/KR20020040905A/ko not_active Ceased
- 2000-10-23 CN CN00813183A patent/CN1376168A/zh active Pending
- 2000-10-23 ES ES00973781T patent/ES2233471T3/es not_active Expired - Lifetime
- 2000-10-23 WO PCT/US2000/029197 patent/WO2001029096A1/en not_active Ceased
- 2000-10-23 EP EP00973781A patent/EP1259553B1/en not_active Expired - Lifetime
- 2000-10-23 DE DE60017467T patent/DE60017467T2/de not_active Expired - Lifetime
- 2000-10-23 MX MXPA02003940A patent/MXPA02003940A/es active IP Right Grant
- 2000-10-23 JP JP2001531892A patent/JP2003518146A/ja not_active Withdrawn
- 2000-10-23 BR BR0014119-4A patent/BR0014119A/pt not_active IP Right Cessation
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2003518146A5 (enExample) | ||
| US5561093A (en) | Catalyst useful for the polymerization of olefins | |
| JP2904301B2 (ja) | エチレンポリマーの製造方法、それに用いる触媒および該触媒の構成成分である新規のメタロセン | |
| JP3244124B2 (ja) | オレフィン類重合用触媒成分、重合用触媒およびこれを用いたオレフィン類の重合方法 | |
| EP1401880B1 (en) | Metallocene catalysts containing an indenyl moiety substituted at the 4-, 5-, 6- or 7-position by a siloxy or germyloxy group | |
| JP4237494B2 (ja) | オレフィン重合用触媒 | |
| JPWO1999002571A1 (ja) | オレフィン類重合用触媒成分、重合用触媒およびこれを用いたオレフィン類の重合方法 | |
| JPH09183788A5 (enExample) | ||
| EP1572762B1 (en) | High molecular weight polypropylene process | |
| JPH08502094A (ja) | 改善された生産性の触媒系及びその重合プロセスにおける使用 | |
| JP2018178101A (ja) | オレフィン重合用触媒、及び、その製造方法、並びに、そのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 | |
| JP3340064B2 (ja) | α−オレフィンの重合及び共重合用の有機金属触媒 | |
| JPH1057815A (ja) | 担持触媒系、その合成方法及びオレフィン重合のためのその使用 | |
| KR102189654B1 (ko) | 신규한 리간드 화합물 및 전이금속 화합물의 제조 방법 | |
| JP4228135B2 (ja) | 遷移金属化合物、オレフィン重合用触媒、およびポリオレフィンの製造方法 | |
| JP3572325B2 (ja) | オレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法 | |
| JP2988244B2 (ja) | オレフィン重合用触媒およびオレフィンの重合方法 | |
| JP3061297B2 (ja) | オレフィン重合体の製造方法 | |
| JP2002053607A (ja) | オレフィン類重合用触媒成分、重合用触媒およびこれを用いたオレフィン類の重合方法 | |
| JP3458636B2 (ja) | 有機金属錯体を用いたオレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法 | |
| JP3070257B2 (ja) | オレフィン重合体の製造方法 | |
| JP3308062B2 (ja) | オレフィン重合用触媒及びポリオレフィンの製造方法 | |
| JP3302415B2 (ja) | 内部オレフィン重合用触媒及び内部オレフィン重合体の製造方法 | |
| JP4590164B2 (ja) | オレフィン重合用触媒およびポリオレフィンの製造方法 | |
| JP3201802B2 (ja) | オレフィンの重合方法 |