JP2003511524A5 - - Google Patents
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- Publication number
- JP2003511524A5 JP2003511524A5 JP2001530385A JP2001530385A JP2003511524A5 JP 2003511524 A5 JP2003511524 A5 JP 2003511524A5 JP 2001530385 A JP2001530385 A JP 2001530385A JP 2001530385 A JP2001530385 A JP 2001530385A JP 2003511524 A5 JP2003511524 A5 JP 2003511524A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst composition
- composition according
- compound
- magnesium
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 claims 29
- 239000003054 catalyst Substances 0.000 claims 25
- 150000001336 alkenes Chemical class 0.000 claims 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 8
- 229910052782 aluminium Inorganic materials 0.000 claims 6
- 239000002245 particle Substances 0.000 claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 239000000126 substance Substances 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 150000002681 magnesium compounds Chemical class 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims 4
- 239000004800 polyvinyl chloride Substances 0.000 claims 4
- 239000002243 precursor Substances 0.000 claims 4
- 239000011949 solid catalyst Substances 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 150000003623 transition metal compounds Chemical class 0.000 claims 3
- -1 aluminum compound Chemical class 0.000 claims 2
- 238000007334 copolymerization reaction Methods 0.000 claims 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical group 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 239000002861 polymer material Substances 0.000 claims 2
- 239000011148 porous material Substances 0.000 claims 2
- 150000003377 silicon compounds Chemical class 0.000 claims 2
- 150000003755 zirconium compounds Chemical class 0.000 claims 2
- 239000004711 α-olefin Substances 0.000 claims 2
- YVSMQHYREUQGRX-UHFFFAOYSA-N 2-ethyloxaluminane Chemical compound CC[Al]1CCCCO1 YVSMQHYREUQGRX-UHFFFAOYSA-N 0.000 claims 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims 1
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 239000012018 catalyst precursor Substances 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 125000006165 cyclic alkyl group Chemical group 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 claims 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 claims 1
- YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 claims 1
- KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 claims 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 claims 1
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 claims 1
- RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 claims 1
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 229910052755 nonmetal Inorganic materials 0.000 claims 1
- 238000006772 olefination reaction Methods 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000005049 silicon tetrachloride Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/416,282 US6288182B1 (en) | 1999-10-12 | 1999-10-12 | Supported metallocene catalyst system for olefin polymerization |
| US09/416,282 | 1999-10-12 | ||
| PCT/EP2000/010026 WO2001027168A1 (en) | 1999-10-12 | 2000-10-11 | Supported metallocene catalyst system for olefin polymerization |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003511524A JP2003511524A (ja) | 2003-03-25 |
| JP2003511524A5 true JP2003511524A5 (enExample) | 2005-04-28 |
| JP3990153B2 JP3990153B2 (ja) | 2007-10-10 |
Family
ID=23649335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001530385A Expired - Fee Related JP3990153B2 (ja) | 1999-10-12 | 2000-10-11 | オレフィン重合用の支持されたメタロセン触媒系 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US6288182B1 (enExample) |
| EP (1) | EP1222215B1 (enExample) |
| JP (1) | JP3990153B2 (enExample) |
| DE (1) | DE60025017T2 (enExample) |
| SA (1) | SA00201065B1 (enExample) |
| WO (1) | WO2001027168A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GC0000293A (en) * | 2000-10-10 | 2006-11-01 | Saudi Basic Ind Corp | Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems |
| DE60104809T2 (de) * | 2001-02-07 | 2005-01-05 | Saudi Basic Industries Corp. | Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung |
| DE60101207T2 (de) * | 2001-02-15 | 2004-08-26 | Saudi Basic Industries Corp. | Geträgerte Katalysatorzusammensetzung für die Olefinpolymerisation; Verfahren zu deren Herstellung und Polymerisationsverfahren unter deren Verwendung |
| DE60104857T2 (de) * | 2001-10-15 | 2005-09-01 | Saudi Basic Industries Corp. (Sabic) | Geträter Polymerisationskatalysator enthaltend Magnesium und einen Metallocen |
| US6861487B2 (en) * | 2003-04-15 | 2005-03-01 | Saudi Basic Industries Corporation | Catalyst precursor for the polymerization of olefins and polymerization process using the same |
| JP4732087B2 (ja) * | 2005-09-13 | 2011-07-27 | 三井化学株式会社 | オレフィン重合触媒用担体、オレフィン重合触媒およびオレフィン系重合体粒子 |
| KR100735220B1 (ko) * | 2005-11-21 | 2007-07-03 | 삼성전자주식회사 | 양방향 광 교차 결합기 |
| US7662894B2 (en) * | 2006-12-19 | 2010-02-16 | Saudi Bosic Industries Corporation | Polymer supported metallocene catalyst composition for polymerizing olefins |
| JP2012526895A (ja) * | 2009-05-15 | 2012-11-01 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 汚れを減少させたオレフィン重合方法 |
| CA2985611C (en) * | 2015-05-11 | 2021-06-01 | W.R. Grace & Co.-Conn. | Process to produce modified clay, supported metallocene polymerization catalyst, catalyst produced and use thereof |
| US10940460B2 (en) | 2015-05-11 | 2021-03-09 | W. R. Grace & Co.-Conn. | Process to produce modified clay, modified clay produced and use thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH072798B2 (ja) * | 1987-10-28 | 1995-01-18 | 住友化学工業株式会社 | オレフィン重合用固体触媒成分 |
| FR2656315B1 (fr) * | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
| US5145818A (en) * | 1989-12-29 | 1992-09-08 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
| US5614456A (en) * | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
| US6111040A (en) * | 1996-05-30 | 2000-08-29 | Nippon Mitsubishi Oil Corporation | Process for the production of olefinic polymers |
| US6228792B1 (en) * | 1998-02-27 | 2001-05-08 | W. R. Grace & Co.-Conn. | Donor-modified olefin polymerization catalysts |
-
1999
- 1999-10-12 US US09/416,282 patent/US6288182B1/en not_active Expired - Lifetime
-
2000
- 2000-04-01 SA SA00201065A patent/SA00201065B1/ar unknown
- 2000-10-11 EP EP00972738A patent/EP1222215B1/en not_active Expired - Lifetime
- 2000-10-11 JP JP2001530385A patent/JP3990153B2/ja not_active Expired - Fee Related
- 2000-10-11 WO PCT/EP2000/010026 patent/WO2001027168A1/en not_active Ceased
- 2000-10-11 DE DE60025017T patent/DE60025017T2/de not_active Expired - Lifetime
-
2001
- 2001-09-10 US US09/950,014 patent/US6617277B2/en not_active Expired - Fee Related
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