JP2000502594A - 強酸性カチオン交換体の製造方法 - Google Patents
強酸性カチオン交換体の製造方法Info
- Publication number
- JP2000502594A JP2000502594A JP9523323A JP52332397A JP2000502594A JP 2000502594 A JP2000502594 A JP 2000502594A JP 9523323 A JP9523323 A JP 9523323A JP 52332397 A JP52332397 A JP 52332397A JP 2000502594 A JP2000502594 A JP 2000502594A
- Authority
- JP
- Japan
- Prior art keywords
- cation exchanger
- strongly acidic
- acidic cation
- divinylbenzene
- sulfonation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
- C08F8/36—Sulfonation; Sulfation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. スチレンとジビニルベンゼンとの、硫酸を用いる、沸騰範囲が120〜2 20℃である不活性組成物を45%まで添加して又は添加しないでの共重合によ って得られる、架橋剤含量がジビニルベンゼン1〜65重量%であるゲル様の又 は多孔性のスチレン/ジビニルベンゼン共重合体(ビード重合体)のスルホン化 による、粒子サイズが≧0.1mmである強酸性カチオン交換体の製造方法であ って、ビード重合体が、不活性な塩素含有膨潤剤を添加しないで、含量が80〜 96%である濃硫酸を用いて、125〜180℃の温度で20時間までの時間ス ルホン化され、そして水和されそして公知の方法のよって十分に洗浄されること を特徴とする方法。 2. ビード重合体が、一般的には80〜96%強度の、好ましくは86〜94 %強度の硫酸を用いてスルホン化されることを特徴とする請求項1に記載の強酸 性カチオン交換体の製造方法。 3. ビード重合体が、一般的には20時間までの時間、好ましくは8〜12時 間スルホン化されることを特徴とする請求項1及び2のいずれかに記載の強酸性 カチオン交換体の製造方法。 4. 多孔性のビード重合体が、一般的には125〜180℃の温度で、好まし くは130〜140℃の温度でスルホン化されることを特徴とする請求項1〜3 のいずれかに記載の強酸性カチオン交換体の製造方法。 5. ゲル様のビード重合体が、一般的には125〜180℃の温度で、好まし くは160〜170℃の温度でスルホン化されることを特徴とする請求項1〜3 のいずれかに記載の強酸性カチオン交換体の製造方法。 6. 請求項1〜5のいずれかに従って製造された生成物が水和されそ して公知の方法のよって十分に洗浄されることを特徴とする請求項1〜5のいず れかに記載の強酸性カチオン交換体の製造方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19548012 | 1995-12-21 | ||
DE19548012.0 | 1995-12-21 | ||
DE19644217.6 | 1996-10-24 | ||
DE19644217A DE19644217A1 (de) | 1995-12-21 | 1996-10-24 | Verfahren zur Herstellung von stark sauren Kationenaustauschern |
PCT/EP1996/005784 WO1997023517A1 (de) | 1995-12-21 | 1996-12-20 | Verfahren zur herstellung stark saurer kationenaustauscher |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2000502594A true JP2000502594A (ja) | 2000-03-07 |
JP2000502594A5 JP2000502594A5 (ja) | 2004-09-16 |
JP4024300B2 JP4024300B2 (ja) | 2007-12-19 |
Family
ID=26021539
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52332397A Expired - Fee Related JP4024300B2 (ja) | 1995-12-21 | 1996-12-20 | 強酸性カチオン交換体の製造方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US6228896B1 (ja) |
EP (1) | EP0868444B1 (ja) |
JP (1) | JP4024300B2 (ja) |
CN (1) | CN1140544C (ja) |
AU (1) | AU1304497A (ja) |
DE (1) | DE59603190D1 (ja) |
WO (1) | WO1997023517A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013529546A (ja) * | 2010-07-09 | 2013-07-22 | リ−エヌ テクノロジー アンパルトセルスカブ | 液状厩肥を含む有機廃水からアンモニア性窒素を除去するための方法 |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1104286C (zh) † | 1995-12-21 | 2003-04-02 | Iab离子交换器股份有限公司 | 制备自由流动的强酸性阳离子交换剂的方法 |
AU752379B2 (en) * | 1998-01-12 | 2002-09-19 | Dexerials Corporation | Method of manufacturing polyelectrolyte |
DE10033585A1 (de) * | 2000-07-11 | 2002-01-24 | Bayer Ag | Sulfonierungsverfahren |
US6784213B2 (en) * | 2001-06-22 | 2004-08-31 | Rohm And Haas Company | Method for preparation of strong acid cation exchange resins |
US6750259B2 (en) | 2002-07-08 | 2004-06-15 | Bayer Aktiengesellschaft | Process for preparing gel-type cation exchangers |
DE10326666A1 (de) * | 2003-02-24 | 2004-09-02 | Bayer Ag | Stoffgemische |
JP2007505209A (ja) * | 2003-07-07 | 2007-03-08 | ダウ グローバル テクノロジーズ インコーポレーテッド | 交換樹脂の改良された無溶媒スルホン化 |
CN100336597C (zh) * | 2003-07-18 | 2007-09-12 | 中山大学 | 一种纳米离子交换材料及其制备方法 |
DE102004052720A1 (de) * | 2004-10-30 | 2006-05-04 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von silberhaltigen Perlpolymerisaten |
CN101209428B (zh) * | 2006-12-28 | 2010-05-19 | 江苏索普(集团)有限公司 | 一种用于除去有机介质中碘化物的吸附剂及制法和应用 |
DE102007060790A1 (de) | 2007-12-18 | 2009-06-25 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Kationenaustauschern |
JP6170157B2 (ja) | 2012-08-31 | 2017-07-26 | ローム アンド ハース カンパニーRohm And Haas Company | アルコールを有機酸から作製する方法 |
CN103059190B (zh) * | 2013-01-16 | 2014-07-23 | 吉林大学 | 可溶胀吸附烃类混合物中芳烃组分树脂球及其制备方法 |
US20150353445A1 (en) | 2013-02-01 | 2015-12-10 | Rhom And Haas Company | Method for performing carbon-carbon coupling reactions with cationic exchange resin supported palladium catalyst |
WO2015017972A1 (en) | 2013-08-06 | 2015-02-12 | Dow Global Technologies Llc | Method for treating oil-containing aqueous mixtures with cation exchange resin |
DE112015001834T5 (de) | 2014-04-15 | 2017-01-05 | Rohm And Haas Company | Sulfonierung von Aromatischen Polymeren unter Verwendung einer fluorierten Benzolverbindung als Quellmittel |
WO2016137787A1 (en) | 2015-02-27 | 2016-09-01 | Rohm And Haas Company | Chromatographic separation of saccharides using cation exchange resin beads with rough outer surface |
CN108102032B (zh) * | 2018-01-05 | 2020-11-27 | 江苏国创新材料研究中心有限公司 | 一种无溶剂的绿色苯乙烯系阳离子交换树脂的制备方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2809959A (en) | 1957-10-15 | Preparation of high-viscosity sulfona- | ||
US2399007A (en) | 1943-10-20 | 1946-04-23 | Davis & Furber | Tape condenser |
US2500149A (en) | 1947-02-21 | 1950-03-14 | Dow Chemical Co | Sulfonation of copolymers of monovinyl-and polyvinyl-aromatic compounds |
US2597438A (en) * | 1951-05-12 | 1952-05-20 | Rohm & Haas | Cation-exchange polymers of the sulfonic type |
GB784028A (en) | 1954-11-24 | 1957-10-02 | Dow Chemical Co | Preparation of high-viscosity sulphonation products having a viscosity stability |
US4382124B1 (en) | 1958-07-18 | 1994-10-04 | Rohm & Haas | Process for preparing macroreticular resins, copolymers and products of said process |
NL125475C (ja) | 1961-03-01 | |||
US4157432A (en) * | 1977-11-29 | 1979-06-05 | Exxon Research & Engineering Co. | Bulk sulfonation process |
US4380590A (en) * | 1978-09-19 | 1983-04-19 | Rohm And Haas Company | Emulsion copolymer cation exchange resins |
US5248435A (en) | 1991-12-17 | 1993-09-28 | Mitsubishi Kasei Corporation | Ion exchange resin, process for producing the same, and method for removing impurities from condensate |
US5244926A (en) * | 1992-06-16 | 1993-09-14 | The Dow Chemical Company | Preparation of ion exchange and adsorbent copolymers |
-
1996
- 1996-12-20 AU AU13044/97A patent/AU1304497A/en not_active Abandoned
- 1996-12-20 EP EP96944623A patent/EP0868444B1/de not_active Expired - Lifetime
- 1996-12-20 JP JP52332397A patent/JP4024300B2/ja not_active Expired - Fee Related
- 1996-12-20 WO PCT/EP1996/005784 patent/WO1997023517A1/de active IP Right Grant
- 1996-12-20 DE DE59603190T patent/DE59603190D1/de not_active Expired - Lifetime
- 1996-12-20 US US09/091,367 patent/US6228896B1/en not_active Expired - Fee Related
- 1996-12-20 CN CNB961992123A patent/CN1140544C/zh not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013529546A (ja) * | 2010-07-09 | 2013-07-22 | リ−エヌ テクノロジー アンパルトセルスカブ | 液状厩肥を含む有機廃水からアンモニア性窒素を除去するための方法 |
Also Published As
Publication number | Publication date |
---|---|
JP4024300B2 (ja) | 2007-12-19 |
WO1997023517A1 (de) | 1997-07-03 |
CN1140544C (zh) | 2004-03-03 |
AU1304497A (en) | 1997-07-17 |
EP0868444B1 (de) | 1999-09-22 |
EP0868444A1 (de) | 1998-10-07 |
DE59603190D1 (de) | 1999-10-28 |
CN1205709A (zh) | 1999-01-20 |
US6228896B1 (en) | 2001-05-08 |
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