HRP20110499T1 - Smjese veziva i srodni postupci - Google Patents

Smjese veziva i srodni postupci Download PDF

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HRP20110499T1
HRP20110499T1 HR20110499T HRP20110499T HRP20110499T1 HR P20110499 T1 HRP20110499 T1 HR P20110499T1 HR 20110499 T HR20110499 T HR 20110499T HR P20110499 T HRP20110499 T HR P20110499T HR P20110499 T1 HRP20110499 T1 HR P20110499T1
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binder mixture
mixture according
acid
thermally
fibers
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HR20110499T
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H. Helbing Clarence
Hession Mary
Helbing James
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Knauf Insulation Gmbh
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Publication of HRP20110499T1 publication Critical patent/HRP20110499T1/hr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00—Thermal insulation in general
    • F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
    • F16L59/028—Composition or method of fixing a thermally insulating material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/092—Polycarboxylic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/249942—Fibers are aligned substantially parallel
    • Y10T428/249944—Fiber is precoated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/249942—Fibers are aligned substantially parallel
    • Y10T428/249946—Glass fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/249948—Fiber is precoated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Materials For Medical Uses (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Nonwoven Fabrics (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Paper (AREA)

Abstract

Vodena smjesa veziva za vlakna koja se može termički stvrdnuti i sadrži: (a) polikiselu komponentu s kiselinskim skupinama, ili njihovim anhidridnim ili solnim derivatima; i (b) polihidroksilnu komponentu s hidroksilnim skupinama; i (c) spoj koji sadrži silicij; gdje je pH smjese veziva veća od oko 7. Patent sadrži još 31 patentni zahtjev.

Claims (32)

1. Vodena smjesa veziva za vlakna koja se može termički stvrdnuti i sadrži: (a) polikiselu komponentu s kiselinskim skupinama, ili njihovim anhidridnim ili solnim derivatima; i (b) polihidroksilnu komponentu s hidroksilnim skupinama; i (c) spoj koji sadrži silicij; gdje je pH smjese veziva veća od oko 7.
2. Smjesa veziva prema zahtjevu 1, gdje je pH smjese veziva u rasponu od oko 7 do oko 10.
3. Smjesa veziva prema zahtjevu 1, gdje je omjer broja molarnih ekvivalenata kiselinskih skupina, ili njihovih anhidridnih ili solnih derivata, prema broju molarnih ekvivalenata hidroksilnih skupina u rasponu od oko 0.6:1 do oko 1.2:1.
4. Smjesa veziva prema zahtjevu 1, gdje su vlakna uključena u izolacijski proizvod od fiberglasa (staklena vuna).
5. Smjesa veziva prema zahtjevu 1, gdje vlakna sadrže staklena vlakna.
6. Smjesa veziva prema zahtjevu 1, gdje se termički ukrutiva, vodena smjesa veziva može termički učvrstiti za poliestersku smolu koja je u netopljiva u vodi i očvrsnuta toplinskom obradom.
7. Smjesa veziva prema zahtjevu 1, gdje se polikisela komponenta izabire između nezasićenih alifatskih polikarboksilnih kiselina, zasićenih alifatskih polikarboksilnih kiselina, aromatskih polikarboksilnih kiselina, nezasićenih cikličkih polikarboksilnih kiselina, zasićenih cikličkih polikarboksilnih kiselina, njihovih hidroksi-supstituiranih derivata, i njihovih soli i anhidrida, i njihovih kombinacija.
8. Smjesa veziva prema zahtjevu 1 koja dalje sadrži amonijak ili njegovu sol.
9. Smjesa veziva prema zahtjevu 1, gdje je polikisela komponenta amonijeva sol nezasićene alifatske polikarboksilne kiseline.
10. Smjesa veziva prema zahtjevu 1, gdje je polihidroksilna komponenta polimerni poliol.
11. Smjesa veziva prema zahtjevu 10, gdje je polimerni poliol polialkilensi poliol ili polialkenilenski poliol.
12. Smjesa veziva prema zahtjevu 10 gdje se polimerni poliol izabire između djelomično hidroliziranog polivinil acetata, polivinil alkohola i njihovih smjesa.
13. Smjesa veziva prema zahtjevu 12, gdje je djelomično hidrolizirani polivinil acetat 87-89% hidrolizirani polivinil acetat.
14. Smjesa veziva prema zahtjevu 13, gdje je omjer broja molarnih ekvivalenata kiselinskih skupina, ili njihovih anhidridnih ili solnih derivata, prema broju molarnih ekvivalenata hidroksilnih skupina u rasponu od oko 0.6:1 do oko 1.2:1.
15. Smjesa veziva prema zahtjevu 1 koja dalje sadrži katalizator koji može povećati stupanj stvaranja estera.
16. Smjesa veziva prema zahtjevu 15, gdje je katalizator sumporna kiselina ili sulfonska kiselina, ili njihova sol ili derivat.
17. Smjesa veziva prema zahtjevu 15, gdje se katalizator izabire između amonijevog para-toluen sulfonata, amonijevog naftalen disulfonata, amonijevog sulfata, amonijevog klorida, sumporne kiseline, olovo acetata, natrij acetata, kalcij acetata, cink acetata, organotin spojeva, estera titana, trioksida antimona, soli germanija, natrij hipofosfita, natrij fosfita, metan sulfonske kiseline i para toluen sulfonske kiseline, i njihovih smjesa.
18. Smjesa veziva prema zahtjevu 1, gdje je spoj koji sadrži silicij amino-supstitutirani spoj koji sadrži silicij.
19. Smjesa veziva prema zahtjevu 1, gdje je spoj koji sadrži silicij silileter.
20. Smjesa veziva prema zahtjevu 1, gdje se spoj koji sadrži silicij izabire između gama-aminopropiltrietoksisilana, gamaglicidoksipropiltrimetoksisilana, i njihovih smjesa.
21. Vodena smjesa veziva za vlakna koja se može termički stvrdnuti prema zahtjevu 1; gdje, polikisela komponenta koja ima kiselinske skupine, ili njihove anhidridne ili solne derivate, je amonijeva sol dikarboksilne kiseline
22. Smjesa prema zahtjevu 21, gdje je pH smjese veziva u rasponu od oko 7 do oko 10.
23. Smjesa prema zahtjevu 21, gdje dikarboksilna kiselina je maleinska kiselina.
24. Smjesa prema zahtjevu 21, gdje je polihidroksilna komponenta djelomično hidrolizirani polivinil acetat.
25. Smjesa prema zahtjevu 24, gdje je djelomično hidrolizirani polivinil acetat 87-89% djelomično hidrolizirani polivinil acetat.
26. Smjesa veziva prema zahtjevu 21, gdje je omjer broja molarnih ekvivalenata solnih skupina karboksilne kiseline na dikarboksilnoj kiselini, prema broju ekvivalenata hidroksilnih skupina na polihidroksilnoj komponenti u rasponu od oko 0.6:1 do oko1.2:1.
27. Postupak povezivanja vlakana koji obuhvaća: (a) dovođenje vlakana u doticaj s vodenom smjesom veziva koja se može termički stvrdnuti prema zahtjevu 1; i (b) zagrijavanje vodene smjese veziva koja se može termički stvrdnuti, na temperaturi koja je dovoljna da stvrdne vodenu smjesu veziva.
28. Postupak prema zahtjevu 27, gdje vlakna nisu tkana.
29. Postupak prema zahtjevu 27, gdje se vodena smjesa veziva koja se može termički stvrdnuti, termički učvršćuje za poliestersku smolu koja je termički očvrsnuta.
30. Proizvod od staklenih vlakana koji sadrži smjesu pripremljenu zagrijavanjem vlakana koja sadrže staklena vlakna, obložena vodenom smjesom veziva koja se može termički stvrdnuti, a koja sadrži polikiselu komponenta koja ima kiselinske skupine, ili njihove anhidridne ili solne derivate, polihidroksilnu komponentu s hidroksilnim skupinama te spoj koji sadrži silicij, gdje je pH smjese veziva veći od oko 7.
31. Proizvod od staklenih vlakana prema zahtjevu 30, gdje su vlakna uključena u podložak od netkanih vlakana i proizvod od staklenih vlakana je izolacijski proizvod od fibeglasa (staklene vune).
32. Proizvod od staklenih vlakana prema zahtjevu 30, gdje se vodena smjesa veziva koja se može termički stvrdnuti, termički učvršćuje za poliestersku smolu koja je termički očvrsnuta.
HR20110499T 2004-03-11 2011-07-05 Smjese veziva i srodni postupci HRP20110499T1 (hr)

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Application Number Priority Date Filing Date Title
US55236104P 2004-03-11 2004-03-11
US10/965,359 US7842382B2 (en) 2004-03-11 2004-10-13 Binder compositions and associated methods
PCT/US2005/008018 WO2005087837A1 (en) 2004-03-11 2005-03-10 Binder compositions and associated methods

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US (4) US7842382B2 (hr)
EP (2) EP1732968B2 (hr)
JP (1) JP2007528438A (hr)
AT (1) ATE512182T1 (hr)
CA (1) CA2558981C (hr)
DK (1) DK1732968T3 (hr)
EA (1) EA013372B1 (hr)
HR (1) HRP20110499T1 (hr)
MX (1) MXPA06010302A (hr)
NO (1) NO20063916L (hr)
PL (1) PL1732968T3 (hr)
PT (1) PT1732968E (hr)
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EA200601663A1 (ru) 2007-02-27
US7842382B2 (en) 2010-11-30
WO2005087837A1 (en) 2005-09-22
NO20063916L (no) 2006-10-24
CA2558981A1 (en) 2005-09-22
SI1732968T1 (sl) 2011-10-28
US20160297923A1 (en) 2016-10-13
EP1732968B1 (en) 2011-06-08
EA013372B1 (ru) 2010-04-30
US20110054143A1 (en) 2011-03-03
EP1732968B2 (en) 2016-01-06
US20050202224A1 (en) 2005-09-15
EP2392605A2 (en) 2011-12-07
ATE512182T1 (de) 2011-06-15
DK1732968T3 (da) 2011-08-01
PT1732968E (pt) 2011-07-25
US8691934B2 (en) 2014-04-08
PL1732968T3 (pl) 2011-11-30
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EP2392605A3 (en) 2014-02-19
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US20140197349A1 (en) 2014-07-17
JP2007528438A (ja) 2007-10-11

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