GB1197847A - Hydroformylation Process - Google Patents

Hydroformylation Process

Info

Publication number
GB1197847A
GB1197847A GB33934/68A GB3393468A GB1197847A GB 1197847 A GB1197847 A GB 1197847A GB 33934/68 A GB33934/68 A GB 33934/68A GB 3393468 A GB3393468 A GB 3393468A GB 1197847 A GB1197847 A GB 1197847A
Authority
GB
United Kingdom
Prior art keywords
ene
atom
ligand
olefinic compound
hex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33934/68A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1197847A publication Critical patent/GB1197847A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
GB33934/68A 1967-08-03 1968-07-17 Hydroformylation Process Expired GB1197847A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US65805567A 1967-08-03 1967-08-03

Publications (1)

Publication Number Publication Date
GB1197847A true GB1197847A (en) 1970-07-08

Family

ID=24639724

Family Applications (1)

Application Number Title Priority Date Filing Date
GB33934/68A Expired GB1197847A (en) 1967-08-03 1968-07-17 Hydroformylation Process

Country Status (8)

Country Link
US (1) US3527809A (enExample)
BE (1) BE718781A (enExample)
DE (1) DE1793069B2 (enExample)
ES (1) ES356671A1 (enExample)
FR (1) FR1576072A (enExample)
GB (1) GB1197847A (enExample)
NL (1) NL160799C (enExample)
SE (1) SE370389B (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2064471A1 (de) * 1969-12-31 1971-07-08 Johnson, Matthey & Co Ltd , London Katalytisches Verfahren
EP0031590A1 (en) * 1979-12-28 1981-07-08 Union Carbide Corporation Rhodium catalyzed hydroformylation process
US4533757A (en) * 1983-01-19 1985-08-06 Basf Aktiengesellschaft Continuous hydroformylation of olefinically unsaturated compounds

Families Citing this family (263)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3965192A (en) * 1967-05-29 1976-06-22 Union Oil Company Of California Hydrocarbonylation process
US4482748A (en) * 1967-05-29 1984-11-13 Celanese Corporation Hydrocarbonylation
GB1243189A (en) * 1967-12-05 1971-08-18 British Petroleum Co Oxo process
US4183871A (en) * 1968-05-09 1980-01-15 Badische Anilin-& Soda-Fabrik Aktiengesellschaft Production of aldehydes and alcohols by the oxo method
DE1939322B2 (de) * 1968-08-02 1981-02-26 Johnson, Matthey & Co., Ltd., London Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen
BE754724A (fr) * 1969-08-12 1971-01-18 Progil Procede d'hydroformylation des olefines et catalyseurs utilisesa cet effet
CA918673A (en) * 1969-12-22 1973-01-09 L. Pruett Roy Hydroformylation process
US4108905A (en) * 1969-12-31 1978-08-22 Johnson, Matthey & Co., Limited Catalytic reactions
US3859359A (en) * 1970-04-27 1975-01-07 Ethyl Corp Compound and method
US3974227A (en) * 1971-12-17 1976-08-10 Rhone-Progil Acid extracted-alkalized/carbon catalyst support with coordination complex catalyst and method of manufacture
US4268688A (en) * 1973-02-16 1981-05-19 Monsanto Company Asymmetric hydroformylation process
JPS535879B2 (enExample) * 1973-08-14 1978-03-02
JPS5638576B2 (enExample) * 1974-07-25 1981-09-08
US4052461A (en) * 1975-02-03 1977-10-04 Monsanto Company Hydroformylation process
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4072709A (en) * 1975-05-27 1978-02-07 Monsanto Company Production of lactic acid
DE2649900A1 (de) * 1975-11-05 1977-05-12 Firestone Tire & Rubber Co Verfahren zur herstellung von gamma- hydroxytetrahydrofuran oder tetrahydrofuran
US4137240A (en) * 1976-01-31 1979-01-30 E. I. Du Pont De Nemours And Company Hydroformylation process for preparation of predominantly linear aldehydes
CA1090823A (en) * 1976-04-08 1980-12-02 Everard A.V. Brewester Cyclic hydroformylation process
US4221743A (en) * 1976-07-07 1980-09-09 Union Carbide Corporation Hydroformylation process
US4143075A (en) * 1976-08-12 1979-03-06 Union Carbide Corporation Control of condensation products in hydroformylation process
US4277627A (en) * 1977-01-25 1981-07-07 Union Carbide Corporation Hydroformylation process
ZA78146B (en) * 1977-01-25 1978-12-27 Union Carbide Corp Improved hydroformylation process
ZA78147B (en) * 1977-01-25 1978-11-29 Union Carbide Corp Improved hydroformylation process
US4139565A (en) * 1977-03-31 1979-02-13 Celanese Corporation Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands
US4169861A (en) * 1977-08-19 1979-10-02 Celanese Corporation Hydroformylation process
US4201728A (en) * 1977-08-19 1980-05-06 Celanese Corporation Hydroformylation catalyst and process
US4183872A (en) * 1978-02-13 1980-01-15 Conoco, Inc. Polymer bound (pentahaptocyclopentadienyl)biscarbonyl rhodium hydroformylation catalyst
US4288634A (en) * 1978-04-10 1981-09-08 Toa Nenryo Kogyo Kabushiki Kaisha Novel rhodium compounds and process for producing the same
US4198353A (en) * 1978-07-14 1980-04-15 Conoco, Inc. Iridium or rhodium trihalide polymer bound hydrogenation and hydroformylation catalyst
EP0007768A3 (en) * 1978-07-27 1980-02-20 DAVY McKEE (LONDON) LIMITED Hydroformylation of alpha-olefinic compounds
DE2833538C2 (de) * 1978-07-31 1984-09-20 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung von α-methylverzweigten Aldehyden
EP0014796B2 (en) * 1978-10-04 1988-11-09 Toa Nenryo Kogyo Kabushiki Kaisha Process for the production of aldehydes by hydroformylation in presence of rhodium compound
JPS5849534B2 (ja) * 1979-04-06 1983-11-05 東亜燃料工業株式会社 アルデヒドの製造方法
US4198352A (en) * 1978-11-29 1980-04-15 Shell Oil Company Internal olefin hydroformylation process
US4221744A (en) * 1978-12-01 1980-09-09 Celanese Corporation Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents
US4593141A (en) * 1979-02-12 1986-06-03 Exxon Research And Engineering Co. Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes
US4344896A (en) * 1979-02-12 1982-08-17 Chevron Research Company Preparation of 2-cyanoaldehydes by rhodium-catalyzed hydroformylation
WO1980001690A1 (en) * 1979-02-12 1980-08-21 Exxon Research Engineering Co Carbonylation process and novel transition metal catalysts
US4450299A (en) * 1980-10-01 1984-05-22 Exxon Research And Engineering Co. Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes
US4298541A (en) * 1979-02-12 1981-11-03 Exxon Research & Engineering Co. Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts
EP0016285B2 (en) * 1979-03-21 1986-03-05 DAVY McKEE (LONDON) LIMITED Process for the production of valeraldehydes by hydroformylation of butene-1
DE16286T1 (de) * 1979-03-21 1983-05-11 Davy Mckee (London) Ltd., London Hydroformylierungsverfahren.
US4297239A (en) * 1979-07-16 1981-10-27 Union Carbide Corporation Hydroformylation catalyst reactivation
US4219684A (en) * 1979-04-02 1980-08-26 Uop Inc. Synthesis of alcohols by hydroformylation with nitrile promoter
ATE3537T1 (de) * 1979-04-11 1983-06-15 Davy Mckee (London) Limited Aldehyd-aether und verfahren zu ihrer herstellung.
US4267383A (en) * 1979-05-04 1981-05-12 Celanese Corporation Hydrocarbonylation
US4283304A (en) * 1979-05-21 1981-08-11 Union Carbide Corporation Process for removing triorganophosphine from a liquid composition
US4246177A (en) * 1979-06-21 1981-01-20 Phillips Petroleum Company Preparation of dihydropyrans
US4258215A (en) * 1979-08-29 1981-03-24 Eastman Kodak Company Hydroformylation process
US4283562A (en) * 1979-10-26 1981-08-11 Union Carbide Corporation Hydroformylation process using stable rhodium catalyst
US4288380A (en) * 1979-11-01 1981-09-08 Union Carbide Corporation Heteronuclear-bridged rhodium clusters
US4348539A (en) * 1979-11-01 1982-09-07 Union Carbide Corporation Heteronuclear-bridged rhodium clusters
US4687866A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Ligand exchange process for producing alkyl diaryl phosphine rhodium carbonyl hydrides
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
US4374278A (en) * 1980-02-28 1983-02-15 Union Carbide Corporation Hydroformylation catalyst reactivation
US4710587A (en) * 1980-04-16 1987-12-01 Union Carbide Corp. Process for removing triorganophosphine from an organic liquid
US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process
US4291179A (en) * 1980-04-21 1981-09-22 National Distillers And Chemical Corp. Rhodium catalyzed process for acetaldehyde and ethanol
US4343950A (en) * 1980-06-16 1982-08-10 Union Carbide Corporation Rhodium-catalyzed oxidation process for producing carboxylic acids
US4605780A (en) * 1980-09-24 1986-08-12 Union Carbide Corporation Reactivation of rhodium complex hydroformylation catalysts
EP0054986A1 (en) * 1980-12-22 1982-06-30 Shell Internationale Researchmaatschappij B.V. A process for the hydroformylation of olefins
DE3107007C1 (de) * 1981-02-25 1982-10-28 Degussa Ag, 6000 Frankfurt 4-Methylmercapto-2-acetoxy-butyraldehyd und Verfahren zu dessen Herstellung
US4400547A (en) * 1981-04-10 1983-08-23 Eastman Kodak Company Hydroformylation process utilizing an unmodified rhodium catalyst and the stabilization and regeneration thereof
GB2097795B (en) * 1981-05-01 1984-08-01 Johnson Matthey Plc Recovering triaryl phosphine from poisoned thodium catalyst systems
US4388476A (en) * 1981-05-01 1983-06-14 Eastman Kodak Company Hydroformylation process with rhodium catalyst and oxygen stabilization thereof
US4388477A (en) * 1981-06-02 1983-06-14 Eastman Kodak Company Hydroformylation process employing unmodified rhodium-cobalt catalyst
US4409149A (en) * 1981-06-29 1983-10-11 Union Carbide Corporation Process for producing catalyst precursors
US4405821A (en) * 1981-08-11 1983-09-20 National Distillers And Chemical Corporation Process for preparing glycolaldehyde and/or ethylene glycol
US4593011A (en) * 1981-08-17 1986-06-03 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4522933A (en) * 1981-08-17 1985-06-11 Union Carbide Corporation Hydroformylation catalyst containing bisphosphine monooxide ligands
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
US4491675A (en) * 1981-08-17 1985-01-01 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4446074A (en) * 1981-12-24 1984-05-01 Union Carbide Corporation Preparation of rhodium complex compounds
US4424392A (en) 1982-03-24 1984-01-03 Union Carbide Corporation Aldehyde containing hydrolyzable silanes
EP0096986B1 (en) * 1982-06-11 1987-04-22 DAVY McKEE (LONDON) LIMITED Hydroformylation process
ATE16475T1 (de) * 1982-06-11 1985-11-15 Davy Mckee London Hydroformylierungsverfahren.
ATE28183T1 (de) * 1982-06-11 1987-07-15 Davy Mckee London Hydroformylierungsverfahren.
US4480138A (en) * 1982-10-12 1984-10-30 Celanese Corporation Hydroformylation process
US4451679A (en) * 1982-10-21 1984-05-29 Texaco Inc. Alcohols and aldehydes prepared from olefins and synthesis gas
US4469895A (en) * 1982-10-21 1984-09-04 Texaco Inc. Process for preparing alcohols from olefins and synthesis gas
US4451680A (en) * 1982-10-21 1984-05-29 Texaco Inc. Alcohols prepared from olefins and synthesis gas
JPS59109245A (ja) * 1982-12-15 1984-06-23 Daicel Chem Ind Ltd ヒドロホルミル化触媒の処理法
DE3317164A1 (de) * 1983-05-11 1984-11-15 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von (delta)-formylvaleriansaeureestern
US4590311A (en) * 1983-12-29 1986-05-20 Shell Oil Company Process for the preparation of 1,4-butanediol
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4663468A (en) 1984-03-14 1987-05-05 Kuraray Company, Ltd. Hydroformylation of 3-methyl-3-buten-1-ol and analogs thereof and use of such hydroformylation products
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4593127A (en) * 1985-01-11 1986-06-03 Union Carbide Corporation Hydroformylation process
DE3505654A1 (de) * 1985-02-19 1986-08-21 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von 2-alkyl-1,4-butandial
US4625068A (en) * 1985-03-20 1986-11-25 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of internal olefins
US4556722A (en) * 1985-03-28 1985-12-03 Union Carbide Corporation Process for the preparation of aminopropylalkoxysilanes
US4642388A (en) * 1985-08-30 1987-02-10 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of alpha-substituted alpha-olefins
US4605781A (en) * 1985-09-03 1986-08-12 Celanese Corporation Production of 2-methylbutanal
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4885401A (en) * 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4613701A (en) * 1985-09-19 1986-09-23 Celanese Corporation Recovery of rhodium from hydroformylation reaction product
US4673753A (en) * 1986-02-03 1987-06-16 Minnesota Mining And Manufacturing Company Rhodium oxymetallate catalysts
US4788308A (en) * 1986-02-03 1988-11-29 Minnesota Mining And Manufacturing Company Rhodium oxymetallate catalysts
US5053551A (en) * 1986-07-01 1991-10-01 Davy Mckee (London) Limited Process for the production of aldehydes by hydroformylation
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands
DE3625261A1 (de) * 1986-07-25 1988-02-04 Basf Ag Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
JP2535028B2 (ja) * 1987-07-31 1996-09-18 東燃株式会社 アミノプロピルアルコキシシラン類の製造方法
US4871878A (en) * 1987-08-10 1989-10-03 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
US4879008A (en) * 1987-11-09 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
US4879416A (en) * 1987-11-23 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
US5026886A (en) * 1988-01-25 1991-06-25 Eastman Kodak Company Preparation of bidentate ligands
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
US4929767A (en) * 1988-08-12 1990-05-29 Union Carbide Chemicals And Plastics Company Inc. Treatment of rhodium catalysts
US4873213A (en) * 1988-08-12 1989-10-10 Puckette Thomas A Low pressure rhodium catalyzed hydroformylation of olefins
US4960949A (en) * 1988-12-22 1990-10-02 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
DE3920423A1 (de) * 1989-06-22 1991-01-03 Basf Ag Verfahren zur herstellung von 2,3-dialkoxypropanalen
US5001274A (en) * 1989-06-23 1991-03-19 Union Carbide Chemicals And Plastics Company Inc. Hydroformylation process
DE3924720A1 (de) * 1989-07-26 1991-01-31 Basf Ag Hydroformylierungsverfahren
DE3938092A1 (de) * 1989-11-16 1991-05-23 Basf Ag Verfahren zur herstellung von 2-formyl-2-methyl-bernsteinsaeureestern
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
TW213465B (enExample) * 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
US5312996A (en) * 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5410091A (en) * 1994-06-02 1995-04-25 Quimica Oxal C.A. Rhodium catalyzed oxo process in tubular reactor
US5756855A (en) 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
ZA96178B (en) 1995-01-18 1997-06-30 Exxon Chemical Patents Inc Organic compounds and processes for their manufacture
US6756411B2 (en) * 1995-06-29 2004-06-29 Sasol Technology (Proprietary) Limited Process for producing oxygenated products
US5744650A (en) * 1995-12-06 1998-04-28 Union Carbide Chemicals & Plastics Technology Corporation Metal-Ligand complex catalyzed processes
US5654455A (en) * 1995-12-21 1997-08-05 Ciba-Geigy Corporation Tris-phosphite ligands and their use in transitioin metal catalyzed processes
US6265619B1 (en) 1996-01-17 2001-07-24 Exxon Chemical Patents Inc. Oxygenates and processes for their manufacture
DE19625167C1 (de) * 1996-06-24 1997-12-11 Hoechst Ag Neue einen 2,2'-Biarylrest enthaltende Bisether und ein Verfahren zu ihrer Herstellung
US5840647A (en) * 1997-09-15 1998-11-24 Eastman Chemical Company Hydroformylation process using novel phosphite-metal catalyst system
US6130358A (en) 1998-10-16 2000-10-10 Eastman Chemical Company Hydroformylation process using novel phosphite-metal catalyst system
US6252121B1 (en) 1999-07-27 2001-06-26 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
WO2001051441A1 (en) * 2000-01-12 2001-07-19 Eastman Chemical Company Hydroformylation method for making aldehydes from sterically hindered olefins
EP1249441A1 (en) 2001-04-13 2002-10-16 Dsm N.V. Continuous hydroformylation process
GB0113080D0 (en) * 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
US6693219B2 (en) 2001-06-02 2004-02-17 Eastman Chemical Company Epoxide stabilization of fluorophosphite-metal catalyst system in a hydroformylation process
US6831035B2 (en) * 2002-01-22 2004-12-14 Eastman Kodak Company Stabilization of fluorophosphite-containing catalysts
CN1639177B (zh) * 2002-03-11 2010-05-05 陶氏技术投资有限责任公司 用于羰基化过程的双亚磷酸酯
US6846960B2 (en) * 2002-09-16 2005-01-25 Eastman Chemical Company Process for reducing fluoride impurities resulting from use of fluorophosphite catalysts
US6995292B2 (en) * 2002-09-16 2006-02-07 Eastman Chemical Company Process for reducing fluoride impurities resulting from use of fluorophosphite catalysts
AU2003270902A1 (en) * 2002-10-15 2004-05-04 Union Carbide Chemicals And Plastics Technology Corporation Bis-chelating ligand and use thereof in carbonylation processes
AU2003292815A1 (en) * 2003-01-16 2004-08-10 Teijin Fibers Limited Differential-shrinkage polyester combined filament yarn
CN1997616B (zh) * 2003-07-03 2011-01-19 陶氏技术投资有限责任公司 配体降解产物的最小化,或其向有用的膦配体的转化
ATE401292T1 (de) * 2003-10-21 2008-08-15 Basf Se Verfahren zur kontinuierlichen herstellung von aldehyden
DE10352261B4 (de) * 2003-11-08 2006-08-24 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von TCD-Dialdehyd
CA2575122C (en) 2004-08-02 2013-06-25 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of a hydroformylation process
JP4534732B2 (ja) * 2004-11-25 2010-09-01 三菱化学株式会社 ヒドロホルミル化方法
JP4548103B2 (ja) * 2004-11-30 2010-09-22 三菱化学株式会社 ヒドロホルミル化方法
MY146608A (en) * 2007-03-20 2012-09-14 Dow Technology Investments Llc Hydroformylation process with improved control over product isomers
TWI432411B (zh) * 2007-04-05 2014-04-01 Dow Global Technologies Llc 用於氫甲醯化方法之杯芳烴雙亞磷酸酯配體
EP2348015A3 (en) 2007-09-07 2012-05-23 Dow Global Technologies LLC Preparation of cyano-aliphatic aldehydes
US8394978B2 (en) * 2008-01-15 2013-03-12 Dow Global Technologies Llc Sulfonated organophosphine compounds and use thereof in hydroformylation processes
US8466306B2 (en) * 2008-01-15 2013-06-18 Dow Global Technologies Llc Sulfonated organophosphine compounds and use in hydroformylation processes
EP2231683B1 (en) * 2008-01-15 2016-03-23 Dow Global Technologies LLC Sulfonated organophosphine compounds and use thereof in hydroformylation processes
US7674937B2 (en) * 2008-05-28 2010-03-09 Eastman Chemical Company Hydroformylation catalysts
CN102143933B (zh) 2008-07-03 2014-09-17 陶氏技术投资有限公司 控制再循环催化剂料流中重物质的方法
WO2010021863A1 (en) * 2008-08-19 2010-02-25 Dow Technology Investments Llc Hydroformylation process using a symmetric bisphosphite ligand for improved control over product isomers
DE102009004655B4 (de) 2009-01-15 2013-02-14 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
EP2414314B1 (en) 2009-03-31 2017-09-13 Dow Technology Investments LLC Hydroformylation process with triphenylphosphine and a doubly open-ended bisphosphite ligand
DE102009016651B4 (de) 2009-04-07 2011-11-17 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
DE102009016652A1 (de) 2009-04-07 2010-10-14 Oxea Gmbh Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
CN102574878A (zh) 2009-10-16 2012-07-11 陶氏技术投资有限责任公司 气相加氢甲酰化方法
CN102741209B (zh) 2009-12-22 2014-12-03 陶氏技术投资有限责任公司 通过控制烯烃分压来控制混合配体加氢甲酰化工艺中的正构∶异构醛比率
EP2722325B2 (en) 2009-12-22 2019-01-16 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
EP2942343B1 (en) 2009-12-22 2019-09-04 Dow Technology Investments LLC Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process
CN103153462B (zh) 2010-10-05 2016-06-01 陶氏技术投资有限责任公司 加氢甲酰基化方法
MX346922B (es) 2010-11-12 2017-04-05 Dow Technology Investments Llc Moderación de suciedad en procesos de hidroformilación mediante adición de agua.
US8513468B2 (en) 2010-12-30 2013-08-20 Eastman Chemical Company Process for removing degradation acids from hydroformylation reactions
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
CN102826976B (zh) * 2011-06-17 2015-04-15 中国石油化工股份有限公司 一种调节丙烯催化制备的丁醛正异比的方法
US8492593B2 (en) 2011-08-16 2013-07-23 Eastman Chemical Company Amido-fluorophosphite compounds and catalysts
CN103906755B (zh) * 2011-09-30 2018-02-27 陶氏技术投资有限责任公司 纯化方法
MX2014007651A (es) 2011-12-20 2014-09-26 Dow Technology Investments Llc Un proceso de hidroformilacion.
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
KR102104824B1 (ko) 2012-04-12 2020-04-28 바스프 에스이 연속적 히드로포르밀화에서 촉매를 보충하는 방법
CA2872823A1 (en) 2012-06-04 2013-12-12 Dow Technology Investments Llc Hydroformylation process
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
DE102012013969B4 (de) 2012-07-13 2017-09-14 Oxea Gmbh Verfahren zur Herstellung eines Gemisches stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
DE102012014396B4 (de) 2012-07-13 2018-01-11 Oxea Gmbh Verfahren zur Herstellung eines Vinylestergemisches aus einem Gemisch stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
DE102012014395B3 (de) 2012-07-13 2013-08-22 Oxea Gmbh Isononylamine ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE102012013968A1 (de) 2012-07-13 2014-04-03 Oxea Gmbh Carbonsäureester der Isononansäure ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
BR112015003762B1 (pt) 2012-08-29 2021-04-13 Dow Technology Investments Llc Processo para a formação de um catalisador de hidroformilação
IN2015DN02639A (enExample) 2012-09-25 2015-09-18 Dow Technology Investments Llc
EP2740535A1 (en) 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentate ligands for hydroformylation of ethylene
US9382180B2 (en) 2012-12-06 2016-07-05 Dow Technology Investments Llc Hydroformylation process
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
CN105189426B (zh) * 2013-05-03 2020-09-18 沙特基础工业公司 用于同时生产含氧醇和增塑剂的集成方法
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
CN104513143A (zh) 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 加氢甲酰化方法
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
CN106103399B (zh) 2013-12-19 2019-07-09 陶氏技术投资有限责任公司 氢甲酰化方法
CN106103400B (zh) 2014-03-31 2020-03-03 陶氏技术投资有限责任公司 氢甲酰化方法
US10501486B2 (en) 2014-05-14 2019-12-10 Dow Technology Investments Llc Stabilized organophosphorous compounds
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
US9856198B1 (en) 2014-12-10 2018-01-02 Dp&Pl Llc Processes for making C3 products from ethylene and syngas using hydroformylation strategies
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
PL3374340T3 (pl) * 2015-11-10 2022-04-11 Dow Technology Investments Llc Sposób wytwarzania aldehydów
RU2751511C9 (ru) 2016-02-11 2021-08-18 Дау Текнолоджи Инвестментс Ллк Способы превращения олефинов в спирты, простые эфиры или их комбинации
CN107141204B (zh) 2016-03-01 2022-03-15 陶氏技术投资有限责任公司 氢甲酰化工艺
MX2018010980A (es) 2016-03-18 2018-11-15 Dow Technology Investments Llc Proceso de hidroformilacion.
US9687837B1 (en) 2016-08-31 2017-06-27 Eastman Chemical Company Stable hydroformylation catalyst for preparation of high N/Iso ratio aldehyde product
US9975833B2 (en) 2016-08-31 2018-05-22 Eastman Chemical Company Efficient catalyst for the formation of polyaryl hydrocarbons suitable as precursors for polydentate organophosphorus catalyst ligands
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
US10981851B2 (en) 2017-10-25 2021-04-20 Dow Technology Investments Llc Hydroformylation process
WO2019094290A1 (en) 2017-11-13 2019-05-16 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
TWI793216B (zh) 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
MY207749A (en) 2018-05-30 2025-03-16 Dow Technology Investments Llc Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it
CN120271422A (zh) 2018-05-30 2025-07-08 陶氏技术投资有限责任公司 在加氢甲酰化过程中减缓催化剂失活和/或减缓四膦配位体使用的方法
BR112020022070B1 (pt) 2018-05-30 2023-09-26 Dow Technology Investments Llc Método para controlar um processo de hidroformilação para produzir aldeídos
MY203235A (en) 2018-11-29 2024-06-19 Dow Technology Investments Llc Hydroformylation process
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
US12031091B2 (en) 2019-05-24 2024-07-09 Eastman Chemical Company Recycle content cracked effluent
CN113993977B (zh) 2019-05-24 2024-09-13 伊士曼化工公司 进入气体裂化器中加工的液体流中混入少量热解油
KR20220024858A (ko) 2019-06-27 2022-03-03 다우 테크놀로지 인베스트먼츠 엘엘씨. 귀금속 회수를 위한 히드로포르밀화 공정으로부터 용액을 제조하는 공정
CN114206821B (zh) 2019-07-29 2024-12-31 伊士曼化工公司 回收成分(c4)烷酸
TW202112716A (zh) 2019-07-29 2021-04-01 美商伊士曼化學公司 回收物環丁烷二醇聚酯
CN114206820B (zh) 2019-07-29 2024-05-10 伊士曼化工公司 回收成分(c4)烷醛
KR20220041177A (ko) 2019-07-29 2022-03-31 이스트만 케미칼 컴파니 열분해 및 가메탄올분해로부터의 재활용된 단량체를 갖는 폴리에스테르의 제조 방법
EP4051762A4 (en) 2019-10-31 2023-12-27 Eastman Chemical Company PYROLYSIS PROCESS AND SYSTEM FOR RECYCLED WASTE
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自c6或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
WO2021092306A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content alpha olefins and fatty alcohols
WO2021092305A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content mixed esters and solvents
WO2021126421A1 (en) 2019-12-19 2021-06-24 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
MX2022008306A (es) 2020-02-10 2022-08-08 Eastman Chem Co Reciclaje quimico de corrientes procesadas de desecho de plastico mezclado.
EP3888790A1 (en) * 2020-04-01 2021-10-06 V. Mane Fils Hydroformylation catalyst system with syngas surrogate
WO2022132372A1 (en) 2020-12-14 2022-06-23 Dow Technology Investments Llc Processes to improve catalytic metal accountability in hydroformylation processes
US20230406802A1 (en) 2020-12-22 2023-12-21 Dow Technology Investments Llc Hydroformylation reaction processes
MX2023010493A (es) 2021-03-31 2023-09-18 Dow Technology Investments Llc Procesos de hidroformilacion.
US12195674B2 (en) 2021-09-21 2025-01-14 Eastman Chemical Company Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic
WO2023086718A1 (en) 2021-11-11 2023-05-19 Dow Technology Investments Llc Processes for recovering rhodium from hydroformylation processes
WO2023107322A1 (en) 2021-12-06 2023-06-15 Dow Global Technologies Llc Alcohol mixtures including linear tridecanols
EP4448170B1 (en) 2021-12-16 2025-08-20 Dow Technology Investments LLC Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
CN118338965A (zh) 2021-12-16 2024-07-12 陶氏技术投资有限责任公司 包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
KR20250099706A (ko) 2022-10-28 2025-07-02 바스프 에스이 재생가능한 기원의 에탄올로부터 프로필렌-유래된 관심 화학물질, 특히 아크릴산 에스테르를 제조하는 방법
WO2024089255A1 (en) 2022-10-28 2024-05-02 Basf Se Process for the manufacture of an ethylene-derived chemical of interest, in particular styrene, from renewably-sourced ethanol
WO2024107323A1 (en) 2022-11-18 2024-05-23 Dow Global Technologies Llc Heterogeneous catalysts
WO2024123510A1 (en) 2022-12-06 2024-06-13 Dow Technology Investments Llc Process of controlling heavies in a recycle catalyst stream
WO2024129290A1 (en) 2022-12-13 2024-06-20 Dow Technology Investments Llc Process to minimize polyphosphine usage by making use of degradation products
WO2024133082A1 (en) 2022-12-20 2024-06-27 Basf Se Manufacture of an ethylene-derived chemical of interest in combination with production of thermal energy
EP4428116A1 (de) 2023-03-07 2024-09-11 Röhm GmbH Neues verfahren zur herstellung von methylmethacrylat über acetalische zwischenstufen
CN121039090A (zh) 2023-05-04 2025-11-28 陶氏技术投资有限责任公司 加氢甲酰化方法
GB202307175D0 (en) 2023-05-15 2023-06-28 Johnson Matthey Davy Technologies Ltd Process for hydrogenating a substrate
WO2025006020A1 (en) 2023-06-26 2025-01-02 Dow Technology Investments Llc Methods of controlling hydroformylation processes
WO2025029349A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Hydroformylation process
WO2025029369A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity
WO2025078359A1 (en) 2023-10-09 2025-04-17 Basf Se Manufacture of ethylene-derived chemicals having a bio-based carbon content from bio-naphtha
WO2025078362A1 (en) 2023-10-09 2025-04-17 Basf Se Process for the manufacture of styrene acrylic copolymers having a renewably-sourced carbon content
WO2025078353A1 (en) 2023-10-09 2025-04-17 Basf Se Manufacture of ethylene-derived chemicals having a bio-based carbon content from pyrolysis oil
WO2025193446A1 (en) 2024-03-12 2025-09-18 Dow Technology Investments Llc Heterogeneous catalysts
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol
WO2025224042A1 (en) 2024-04-23 2025-10-30 Basf Se Process for the manufacture of renewably-sourced n-butanol or 2-ethylhexanol

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA727641A (en) * 1966-02-08 H. Slaugh Lynn Hydroformylation of olefins
DE953605C (de) * 1952-06-18 1956-12-06 Chemische Verwertungsgesellsch Verfahren zur Herstellung sauerstoffhaltiger Verbindungen
NL213649A (enExample) * 1956-01-11
US3150188A (en) * 1960-04-21 1964-09-22 Diamond Alkali Co Aromatic phosphite catalyst modifiers in the oxo process
NL146830C (enExample) * 1960-07-22
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
NL263403A (enExample) * 1961-02-08
US3290379A (en) * 1961-09-01 1966-12-06 Diamond Alkali Co Selective hydroformylation of olefinic compounds
US3310576A (en) * 1963-02-05 1967-03-21 Exxon Research Engineering Co Hydroformylation catalyst and process relating thereto
DE1518236A1 (de) * 1964-12-15 1972-06-08 Johnson Matthey Co Ltd Katalytische Verfahren
GB1138601A (en) * 1964-12-15 1969-01-01 Geoffrey Wilkinson Improvements in catalytic reactions

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2064471A1 (de) * 1969-12-31 1971-07-08 Johnson, Matthey & Co Ltd , London Katalytisches Verfahren
EP0031590A1 (en) * 1979-12-28 1981-07-08 Union Carbide Corporation Rhodium catalyzed hydroformylation process
US4533757A (en) * 1983-01-19 1985-08-06 Basf Aktiengesellschaft Continuous hydroformylation of olefinically unsaturated compounds

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DE1793069C3 (enExample) 1990-06-21
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BE718781A (enExample) 1969-01-30
ES356671A1 (es) 1970-02-01
DE1793069A1 (de) 1972-02-03
NL160799C (nl) 1984-01-16
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US3527809A (en) 1970-09-08

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