GB1335531A - Process for producing aldehydes by vapour phase hydroformylation of an olefinically unsaturated organic compound - Google Patents

Process for producing aldehydes by vapour phase hydroformylation of an olefinically unsaturated organic compound

Info

Publication number
GB1335531A
GB1335531A GB5588369A GB1335531DA GB1335531A GB 1335531 A GB1335531 A GB 1335531A GB 5588369 A GB5588369 A GB 5588369A GB 1335531D A GB1335531D A GB 1335531DA GB 1335531 A GB1335531 A GB 1335531A
Authority
GB
United Kingdom
Prior art keywords
olefinically unsaturated
organic compound
vapour phase
unsaturated organic
hydroformylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5588369A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of GB1335531A publication Critical patent/GB1335531A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1335531 Hydroformylation JOHNSON MATTHEY & CO Ltd 4 Nov 1970 [14 Nov 1969] 55883/69 Addition to 1298331 Heading C2C [Also in Division B1] Aldehydes are produced by hydroformylation of olefinically unsaturated compounds in the presence of a catalyst comprising a hydridocarbonylbis(trisubstituted phosphine, arsine or stibine) rhodium compound or a hydrocarbonyltris(trisubstituted phosphine, arsine or stibine) rhodium compound, the catalyst being supported on a carrier. An example describes the preparation of butyraldehyde from propylen in the presence of hydridocarbonylbis(triphenylphosphine) rhodium (I) on alumina.
GB5588369A 1969-11-14 1969-11-14 Process for producing aldehydes by vapour phase hydroformylation of an olefinically unsaturated organic compound Expired GB1335531A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5588369 1969-11-14

Publications (1)

Publication Number Publication Date
GB1335531A true GB1335531A (en) 1973-10-31

Family

ID=10475113

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5588369A Expired GB1335531A (en) 1969-11-14 1969-11-14 Process for producing aldehydes by vapour phase hydroformylation of an olefinically unsaturated organic compound

Country Status (5)

Country Link
BE (1) BE758802A (en)
DE (1) DE2055539B2 (en)
FR (1) FR2069322A5 (en)
GB (1) GB1335531A (en)
NL (1) NL7016532A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002908A1 (en) * 1977-12-16 1979-07-11 Monsanto Company Hydroformylation of formaldehyde with rhodium catalyst
EP3632888A1 (en) * 2018-10-05 2020-04-08 Evonik Operations GmbH Process for the in-situ production of a hydroformylation catalyst system which is heterogenized on a vessel
EP3632887A1 (en) * 2018-10-05 2020-04-08 Evonik Operations GmbH Process for starting a hydroformylation reactor

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
AT356639B (en) * 1977-01-20 1980-05-12 Stamicarbon METHOD FOR CATALYTICALLY IMPLEMENTING OLEFINICALLY UNSATURATED COMPOUNDS WITH HYDROGEN AND CARBON MONOXIDE
DE2833538C2 (en) * 1978-07-31 1984-09-20 Ruhrchemie Ag, 4200 Oberhausen Process for the preparation of α-methyl branched aldehydes
US4694109A (en) * 1986-06-13 1987-09-15 Eastman Kodak Company Chelate ligands for low pressure hydroformylation catalyst and process employing same
EP3632889B1 (en) * 2018-10-05 2022-11-02 Evonik Operations GmbH Process for hydroformylation of c2- to c5-olefins without intermediate partial separation
ES2969859T3 (en) * 2018-10-05 2024-05-23 Evonik Oxeno Gmbh & Co Kg Procedure for hydroformylation of short chain olefins in alkane-rich off-gas streams
EP3744707B1 (en) * 2018-10-05 2024-01-10 Evonik Oxeno GmbH & Co. KG Process for hydroformylation of short-chain olefins in the recycle stream of a liquid phase hydroformylation
US10647650B2 (en) * 2018-10-05 2020-05-12 Evonik Operations Gmbh Process for hydroformylating short-chain olefins using a heterogenized catalyst system without ionic liquid

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002908A1 (en) * 1977-12-16 1979-07-11 Monsanto Company Hydroformylation of formaldehyde with rhodium catalyst
EP3632888A1 (en) * 2018-10-05 2020-04-08 Evonik Operations GmbH Process for the in-situ production of a hydroformylation catalyst system which is heterogenized on a vessel
EP3632887A1 (en) * 2018-10-05 2020-04-08 Evonik Operations GmbH Process for starting a hydroformylation reactor
WO2020070052A1 (en) * 2018-10-05 2020-04-09 Evonik Operations Gmbh Process for preparing short-chain olefins in the gas phase
CN112888671A (en) * 2018-10-05 2021-06-01 赢创运营有限公司 Process for preparing short-chain olefins in the gas phase
US11384042B2 (en) 2018-10-05 2022-07-12 Evonik Operations Gmbh Process for hydroformylation of short-chain olefins in the gas phase
CN112888671B (en) * 2018-10-05 2023-12-12 赢创奥克森诺有限责任两合公司 Process for preparing short-chain olefins in the gas phase

Also Published As

Publication number Publication date
FR2069322A5 (en) 1971-09-03
BE758802A (en) 1971-04-16
DE2055539A1 (en) 1971-05-27
NL7016532A (en) 1971-05-18
DE2055539B2 (en) 1981-02-26

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Legal Events

Date Code Title Description
694A Case decided by the comptroller (rule 94(3)/1968)
PS Patent sealed
48R Reference inserted (sect. 8/1949)
PCNP Patent ceased through non-payment of renewal fee