FR3047676B1 - Procede de traitement hydrophobe d'un substrat en carbone - Google Patents
Procede de traitement hydrophobe d'un substrat en carbone Download PDFInfo
- Publication number
- FR3047676B1 FR3047676B1 FR1651084A FR1651084A FR3047676B1 FR 3047676 B1 FR3047676 B1 FR 3047676B1 FR 1651084 A FR1651084 A FR 1651084A FR 1651084 A FR1651084 A FR 1651084A FR 3047676 B1 FR3047676 B1 FR 3047676B1
- Authority
- FR
- France
- Prior art keywords
- carbon substrate
- drying
- treating
- carbon
- fluorinated copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 64
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 50
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 24
- 230000002209 hydrophobic effect Effects 0.000 title description 12
- 229920001577 copolymer Polymers 0.000 claims abstract description 31
- 238000001035 drying Methods 0.000 claims abstract description 23
- 239000007864 aqueous solution Substances 0.000 claims abstract description 10
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005470 impregnation Methods 0.000 claims abstract description 8
- KRUVFKLWACQUEB-UHFFFAOYSA-N FC1(OC(=C(O1)F)F)OC(F)(F)F Chemical compound FC1(OC(=C(O1)F)F)OC(F)(F)F KRUVFKLWACQUEB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 8
- 239000004917 carbon fiber Substances 0.000 claims description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 abstract description 14
- 239000000446 fuel Substances 0.000 abstract description 8
- 150000001721 carbon Chemical class 0.000 abstract description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 18
- 239000004810 polytetrafluoroethylene Substances 0.000 description 18
- 238000005245 sintering Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- 229920002313 fluoropolymer Polymers 0.000 description 5
- 229920001600 hydrophobic polymer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- -1 polytetrafluoroethylene Polymers 0.000 description 4
- 238000001291 vacuum drying Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000004811 fluoropolymer Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- JSGITCLSCUKHFW-UHFFFAOYSA-N 2,2,4-trifluoro-5-(trifluoromethoxy)-1,3-dioxole Chemical compound FC1=C(OC(F)(F)F)OC(F)(F)O1 JSGITCLSCUKHFW-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8817—Treatment of supports before application of the catalytic active composition
- H01M4/8821—Wet proofing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0234—Carbonaceous material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0239—Organic resins; Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0241—Composites
- H01M8/0245—Composites in the form of layered or coated products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Carbon And Carbon Compounds (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1651084A FR3047676B1 (fr) | 2016-02-11 | 2016-02-11 | Procede de traitement hydrophobe d'un substrat en carbone |
| US15/414,217 US10170769B2 (en) | 2016-02-11 | 2017-01-24 | Method of hydrophobic treatment of a carbon substrate |
| EP17152949.8A EP3206247B1 (fr) | 2016-02-11 | 2017-01-25 | Procédé de traitement hydrophobe d'un substrat en carbone |
| JP2017011914A JP6967855B2 (ja) | 2016-02-11 | 2017-01-26 | 炭素基材の疎水性処理方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1651084A FR3047676B1 (fr) | 2016-02-11 | 2016-02-11 | Procede de traitement hydrophobe d'un substrat en carbone |
| FR1651084 | 2016-02-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR3047676A1 FR3047676A1 (fr) | 2017-08-18 |
| FR3047676B1 true FR3047676B1 (fr) | 2019-11-22 |
Family
ID=55590079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR1651084A Active FR3047676B1 (fr) | 2016-02-11 | 2016-02-11 | Procede de traitement hydrophobe d'un substrat en carbone |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US10170769B2 (enExample) |
| EP (1) | EP3206247B1 (enExample) |
| JP (1) | JP6967855B2 (enExample) |
| FR (1) | FR3047676B1 (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3072608B1 (fr) * | 2017-10-20 | 2021-04-02 | Commissariat Energie Atomique | Structure multicouche integrant un tapis de nanotubes de carbone comme couche de diffusion dans une pemfc |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01253162A (ja) * | 1988-03-31 | 1989-10-09 | Tanaka Kikinzoku Kogyo Kk | 燃料電池用電極基材の製造方法 |
| JP4792640B2 (ja) * | 2000-02-15 | 2011-10-12 | 旭硝子株式会社 | ブロックポリマー、重合体の製造方法及びブロックポリマーを含む液状組成物 |
| JP2002216778A (ja) * | 2001-01-15 | 2002-08-02 | Aisin Seiki Co Ltd | 燃料電池用電極およびその製造方法および固体高分子電解質型燃料電池 |
| US6733915B2 (en) * | 2001-12-27 | 2004-05-11 | E. I. Du Pont De Nemours And Company | Gas diffusion backing for fuel cells |
| JP2005093217A (ja) * | 2003-09-17 | 2005-04-07 | Ube Ind Ltd | 燃料電池用電極、その製造方法、膜−電極接合体及び燃料電池 |
| JP2008261063A (ja) * | 2007-04-10 | 2008-10-30 | Sumitomo Electric Ind Ltd | 多孔質材料とそれを用いた防水性空気透過フィルタ |
| JP2009170218A (ja) * | 2008-01-15 | 2009-07-30 | Toyota Motor Corp | 燃料電池用接合体の製造方法 |
| JP5530954B2 (ja) * | 2011-02-21 | 2014-06-25 | 株式会社日本自動車部品総合研究所 | 燃料電池 |
| JP5578134B2 (ja) * | 2011-05-06 | 2014-08-27 | トヨタ自動車株式会社 | 燃料電池の製造方法 |
| CN102627719B (zh) * | 2012-03-23 | 2014-05-07 | 上海三爱富新材料股份有限公司 | 一种高强度耐蠕变性的聚四氟乙烯制备方法 |
| KR20140085148A (ko) * | 2012-12-27 | 2014-07-07 | 현대자동차주식회사 | 연료 전지용 촉매, 이를 포함하는 연료 전지용 전극, 연료 전지용 막-전극 어셈블리 및 연료 전지 시스템 |
| US9403121B2 (en) * | 2013-06-06 | 2016-08-02 | Idex Health & Science, Llc | Carbon nanotube composite membrane |
| US9381449B2 (en) * | 2013-06-06 | 2016-07-05 | Idex Health & Science Llc | Carbon nanotube composite membrane |
-
2016
- 2016-02-11 FR FR1651084A patent/FR3047676B1/fr active Active
-
2017
- 2017-01-24 US US15/414,217 patent/US10170769B2/en active Active
- 2017-01-25 EP EP17152949.8A patent/EP3206247B1/fr active Active
- 2017-01-26 JP JP2017011914A patent/JP6967855B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20170237078A1 (en) | 2017-08-17 |
| JP6967855B2 (ja) | 2021-11-17 |
| EP3206247A1 (fr) | 2017-08-16 |
| US10170769B2 (en) | 2019-01-01 |
| JP2017141153A (ja) | 2017-08-17 |
| EP3206247B1 (fr) | 2017-12-06 |
| FR3047676A1 (fr) | 2017-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PLFP | Fee payment |
Year of fee payment: 2 |
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| PLSC | Publication of the preliminary search report |
Effective date: 20170818 |
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