FR3029189B1 - Tamis moleculaire de type na-y, tamis moleculaire de type h-y, et leurs procedes de preparation, catalyseur d'hydrocraquage, et procede d'hydrocraquage - Google Patents

Tamis moleculaire de type na-y, tamis moleculaire de type h-y, et leurs procedes de preparation, catalyseur d'hydrocraquage, et procede d'hydrocraquage Download PDF

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Publication number
FR3029189B1
FR3029189B1 FR1561443A FR1561443A FR3029189B1 FR 3029189 B1 FR3029189 B1 FR 3029189B1 FR 1561443 A FR1561443 A FR 1561443A FR 1561443 A FR1561443 A FR 1561443A FR 3029189 B1 FR3029189 B1 FR 3029189B1
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Prior art keywords
molecular sieve
type molecular
hydrocracking
hydrocracking catalyst
preparation methods
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FR3029189A1 (fr
Inventor
Chang Liu
Fenglai Wang
Minghua Guan
Yanze Du
Wei Huang
Hong Zhao
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China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
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China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
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Priority claimed from CN201410711228.1A external-priority patent/CN105621449B/zh
Priority claimed from CN201410711239.XA external-priority patent/CN105712369B/zh
Priority claimed from CN201410711208.4A external-priority patent/CN105712368B/zh
Application filed by China Petroleum and Chemical Corp, Sinopec Fushun Research Institute of Petroleum and Petrochemicals filed Critical China Petroleum and Chemical Corp
Publication of FR3029189A1 publication Critical patent/FR3029189A1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/106—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/618—Surface area more than 1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • C01P2006/17—Pore diameter distribution

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)
  • Catalysts (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)

Abstract

La présente invention divulgue un tamis moléculaire de type Na-Y et un procédé de préparation du tamis moléculaire de type Na-Y, un tamis moléculaire de type H-Y et un procédé de préparation du tamis moléculaire de type H-Y, un catalyseur d'hydrocraquage, et un procédé d'hydrocraquage. Le diamètre moyen du grain du tamis moléculaire de type Na-Y est de 2 à 5 µm, et la somme des volumes des pores de diamètre de 1 à 10 nm représente 70 à 90 % du volume total des pores du tamis moléculaire de type Na-Y. Le tamis moléculaire de type H-Y obtenu à partir du tamis moléculaire de type Na-Y à gros grain peut être utilisé comme un composant acide dans le catalyseur d'hydrocraquage. Lorsque le catalyseur d'hydrocraquage contenant le tamis moléculaire de type H-Y est appliqué dans la réaction d'hydrocraquage d'huiles lourdes qui contiennent des macromolécules, il peut fournir une meilleure activité de craquage et une meilleure capacité de sélection de produit dans la réaction d'hydrocraquage.
FR1561443A 2014-12-01 2015-11-27 Tamis moleculaire de type na-y, tamis moleculaire de type h-y, et leurs procedes de preparation, catalyseur d'hydrocraquage, et procede d'hydrocraquage Active FR3029189B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201410711228.1A CN105621449B (zh) 2014-12-01 2014-12-01 一种NaY型分子筛及其制备方法
CN201410711239.XA CN105712369B (zh) 2014-12-01 2014-12-01 一种改性y型分子筛及其制备方法
CN201410711208.4A CN105712368B (zh) 2014-12-01 2014-12-01 一种y型分子筛及其制备方法

Publications (2)

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FR3029189A1 FR3029189A1 (fr) 2016-06-03
FR3029189B1 true FR3029189B1 (fr) 2021-12-10

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Country Status (5)

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US (2) US10265687B2 (fr)
KR (1) KR101792229B1 (fr)
CA (1) CA2913269C (fr)
FR (1) FR3029189B1 (fr)
GB (2) GB2535584B (fr)

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US10265687B2 (en) * 2014-12-01 2019-04-23 China Petroleum & Chemical Corporation Na—Y molecular sieve, H—Y molecular sieve, and preparation methods thereof, hydrocracking catalyst, and hydrocracking method
CN111085251B (zh) * 2018-10-23 2022-06-24 中国石油化工股份有限公司 一种负载金属的催化剂、制备方法和应用
CN111085249B (zh) * 2018-10-23 2022-06-24 中国石油化工股份有限公司 一种负载金属的含酸性材料催化剂的制备方法
CN111085250B (zh) * 2018-10-23 2022-06-28 中国石油化工股份有限公司 一种负载金属的催化剂的制备方法
CN111097486A (zh) * 2018-10-29 2020-05-05 中国石油化工股份有限公司 一种y分子筛及其制备方法和应用
CN109264743A (zh) * 2018-11-23 2019-01-25 福州大学 一种小晶粒高硅铝比NaY分子筛的制备方法
CN110562996A (zh) * 2019-08-10 2019-12-13 桂林理工大学 低温碱溶液直接活化尾矿制备zsm-5分子筛的方法
CN112717981B (zh) * 2019-10-28 2022-04-08 中国石油化工股份有限公司 一种加氢裂化催化剂及其制备方法和应用
CN112934258B (zh) * 2019-11-26 2023-10-13 国家能源投资集团有限责任公司 复合分子筛及其制备方法和加氢异构催化剂及费托合成油加氢异构的方法
CN116062764B (zh) * 2021-10-29 2024-05-10 中国石油化工股份有限公司 具有核壳结构的y-y复合型分子筛及其制备方法和应用
CN116062765B (zh) * 2021-10-29 2024-07-02 中国石油化工股份有限公司 一种纳米y型分子筛的制备方法
CN114920260B (zh) * 2022-05-26 2023-09-01 盐城工学院 一种纳米H-Beta分子筛的制备方法
CN114853453B (zh) * 2022-05-27 2023-03-17 航天特种材料及工艺技术研究所 一种微纳米结构疏水型陶瓷气凝胶材料及其制备方法
CN115404724A (zh) * 2022-08-09 2022-11-29 浙江广源印刷包装有限公司 一种高强度防潮瓦楞纸箱以及制备方法

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CN104591207B (zh) 2013-11-03 2017-03-22 中国石油化工股份有限公司 一种小晶粒NaY型分子筛及其制备方法
CN104591212B (zh) 2013-11-03 2016-06-29 中国石油化工股份有限公司 一种小晶粒y型分子筛的制备方法
CN104591214B (zh) 2013-11-03 2017-03-29 中国石油化工股份有限公司 一种小晶粒y型分子筛及其制备方法
CN104588122B (zh) 2013-11-03 2017-01-25 中国石油化工股份有限公司 一种加氢裂化催化剂载体及其制备方法
CN104828839B (zh) 2014-02-08 2017-08-22 中国石油化工股份有限公司 制备小晶粒y型分子筛的方法
US10265687B2 (en) 2014-12-01 2019-04-23 China Petroleum & Chemical Corporation Na—Y molecular sieve, H—Y molecular sieve, and preparation methods thereof, hydrocracking catalyst, and hydrocracking method
CN105709845B (zh) 2014-12-01 2018-02-09 中国石油化工股份有限公司 加氢裂化催化剂载体及其制备方法
CN104773741B (zh) 2015-03-31 2017-03-08 中国石油天然气集团公司 一种大晶粒NaY分子筛及其制备方法

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US10265687B2 (en) 2019-04-23
CA2913269C (fr) 2018-10-09
KR20160065761A (ko) 2016-06-09
GB201621466D0 (en) 2017-02-01
GB2546614B (en) 2019-02-13
GB201520976D0 (en) 2016-01-13
GB2535584B (en) 2017-02-08
US20190168193A1 (en) 2019-06-06
KR101792229B1 (ko) 2017-11-20
GB2535584A (en) 2016-08-24
CA2913269A1 (fr) 2016-06-01
FR3029189A1 (fr) 2016-06-03
US20160151771A1 (en) 2016-06-02
GB2546614A (en) 2017-07-26

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