FR2810679B1 - Procede d'extraction d'americium, de curium et de lanthanides de solutions acides - Google Patents

Procede d'extraction d'americium, de curium et de lanthanides de solutions acides

Info

Publication number
FR2810679B1
FR2810679B1 FR0108134A FR0108134A FR2810679B1 FR 2810679 B1 FR2810679 B1 FR 2810679B1 FR 0108134 A FR0108134 A FR 0108134A FR 0108134 A FR0108134 A FR 0108134A FR 2810679 B1 FR2810679 B1 FR 2810679B1
Authority
FR
France
Prior art keywords
curium
americium
lanthanides
extraction
acidic solutions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0108134A
Other languages
English (en)
Other versions
FR2810679A1 (fr
Inventor
Yuji Sasaki
Tsuyoshi Yaita
Hirokazu Narira
Shoichi Tachimori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Atomic Energy Agency
Original Assignee
Japan Atomic Energy Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Atomic Energy Research Institute filed Critical Japan Atomic Energy Research Institute
Publication of FR2810679A1 publication Critical patent/FR2810679A1/fr
Application granted granted Critical
Publication of FR2810679B1 publication Critical patent/FR2810679B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0295—Obtaining thorium, uranium, or other actinides obtaining other actinides except plutonium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/302—Ethers or epoxides
    • C22B3/304—Crown ethers
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/42—Reprocessing of irradiated fuel
    • G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
    • G21C19/46—Aqueous processes, e.g. by using organic extraction means, including the regeneration of these means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Plasma & Fusion (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Manufacture And Refinement Of Metals (AREA)
FR0108134A 2000-06-21 2001-06-20 Procede d'extraction d'americium, de curium et de lanthanides de solutions acides Expired - Fee Related FR2810679B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000186323A JP4524394B2 (ja) 2000-06-21 2000-06-21 酸性溶液中に存在するアメリシウム及びネオジムの抽出方法

Publications (2)

Publication Number Publication Date
FR2810679A1 FR2810679A1 (fr) 2001-12-28
FR2810679B1 true FR2810679B1 (fr) 2004-04-02

Family

ID=18686505

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0108134A Expired - Fee Related FR2810679B1 (fr) 2000-06-21 2001-06-20 Procede d'extraction d'americium, de curium et de lanthanides de solutions acides

Country Status (2)

Country Link
JP (1) JP4524394B2 (fr)
FR (1) FR2810679B1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2560603C2 (ru) * 2009-07-27 2015-08-20 Коммиссариат А Л' Энержи Атомик Э Оз Энержи Альтернатив Повышение коэффициента разделения америция и кюрия и/или лантанидов в процедуре экстракции жидкости жидкостью с применением дигликольмида и другого экстрагирующего вещества

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087206B2 (en) 2002-04-12 2006-08-08 Pg Research Foundation Multicolumn selectivity inversion generator for production of high purity actinium for use in therapeutic nuclear medicine
JP4534000B2 (ja) * 2004-09-02 2010-09-01 独立行政法人 日本原子力研究開発機構 有機溶媒中のＡｍ（ＩＩＩ），Ｐｕ（ＩＶ）をＮ，Ｎ−ジプロピルジグリコールアミド酸（ＰＤＧＡＡ）化合物を溶解した０．１Ｍ以上の濃度の硝酸溶液を用いて逆抽出する方法
JP5035788B2 (ja) * 2006-06-06 2012-09-26 独立行政法人日本原子力研究開発機構 希土類金属の抽出剤と抽出方法
ATE471993T1 (de) * 2006-10-17 2010-07-15 Univ Madrid Autonoma Bis-diglykolamide (bisdga) als neue extraktionsmittel für lanthanoide äla(iii)ü und actinide äan(iii)ü in wässrigem, hochradioaktivem abfall
FR2907346B1 (fr) * 2006-10-23 2009-01-30 Commissariat Energie Atomique Separation groupee des actinides a partir d'une phase aqueuse fortement acide, utilisant un extractant solvatant en milieu relargant.
FR2948385B1 (fr) * 2009-07-27 2011-09-23 Commissariat Energie Atomique Procede de recuperation selective de l'americium a partir d'une phase aqueuse nitrique
EP2459522B1 (fr) * 2009-07-30 2013-06-26 Secretary, Department Of Atomic Energy Dérivés dialkyldiaza-tetraalkyloctane diamide pour la séparation des actinides trivalentes de lanthanoides et procédé pour leur préparation
JP5526434B2 (ja) * 2010-01-20 2014-06-18 独立行政法人日本原子力研究開発機構 Ｎ，Ｎ，Ｎ’，Ｎ’−テトラアルキル−３，６−ジオキサオクタン−１，８−ジアミド（ＤＯＯＤＡ）とＴＡＤＧＡ（Ｎ，Ｎ，Ｎ’，Ｎ’−テトラアルキル−ジグリコールアミド）を併用するＡｍ，ＣｍとＳｍ，Ｅｕ，Ｇｄとの相互分離法
CN102002590B (zh) * 2010-12-20 2012-06-20 四川大学 含三中心氢键的环芳酰胺化合物作为萃取剂在分离稀土元素中的应用
JP6216206B2 (ja) * 2012-10-23 2017-10-18 国立大学法人横浜国立大学 希土類元素の回収方法及び希土類元素の回収装置
FR3015760B1 (fr) 2013-12-20 2016-01-29 Commissariat Energie Atomique Procede de traitement d'un combustible nucleaire use comprenant une etape de decontamination de l'uranium(vi) en au moins un actinide(iv) par complexation de cet actinide(iv)
FR3026099B1 (fr) * 2014-09-24 2017-06-02 Commissariat Energie Atomique Procedes de recuperation selective de terres rares presentes dans des phases aqueuses acides issues du traitement d'aimants permanents usages ou rebutes
RU2603405C1 (ru) * 2015-05-13 2016-11-27 Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" Способ выделения америция из жидких радиоактивных отходов и отделения его от редкоземельных элементов
JP6614654B2 (ja) * 2015-11-25 2019-12-04 国立研究開発法人日本原子力研究開発機構 ニトリロ酢酸ジアセトアミド化合物、抽出剤、及び抽出方法
CN106929675A (zh) * 2017-01-04 2017-07-07 北京科技大学 一种分别富集14种稀土元素的方法
FR3080114B1 (fr) * 2018-04-13 2021-10-08 Commissariat Energie Atomique Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides
CN114113284B (zh) * 2021-11-26 2023-10-20 中国辐射防护研究院 一种钇-90作为镅和锔化学分离示踪剂的分析方法
CN114525419B (zh) * 2022-01-04 2024-05-14 中国原子能科学研究院 烷基二硫代膦酸与含氮试剂分离三价镅锔的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2316091A1 (de) * 1973-03-30 1974-10-10 Kernforschung Gmbh Ges Fuer Verfahren zur reindarstellung von americium und curium aus waessrigen loesungen bestrahlter kernbrenn- und/oder brutstoffe
FR2438625A1 (fr) * 1978-10-11 1980-05-09 Commissariat Energie Atomique Procede de separation de l'americium du curium
JPH07101933A (ja) * 1993-10-06 1995-04-18 Kawaken Fine Chem Co Ltd 脂肪酸ジグリコールアミドスルホコハク酸エステル塩を製造する方法およびこの方法の製品を含有する洗浄剤組成物
CN1032765C (zh) * 1993-12-17 1996-09-11 清华大学 镅和锔与裂变产物稀土分离的方法
JP3310765B2 (ja) * 1994-02-25 2002-08-05 三菱重工業株式会社 再処理施設の高レベル廃液処理方法
JP2977744B2 (ja) * 1995-09-12 1999-11-15 核燃料サイクル開発機構 三価アクチニドと希土類元素の分離方法
JPH09113689A (ja) * 1995-10-16 1997-05-02 Hitachi Ltd アメリシウム及びキュリウムの分離方法
US5966584A (en) * 1997-09-17 1999-10-12 Forschungszentrum Julich Gmbh Method of separating trivalent actinides from trivalent lanthanides
FR2786487B1 (fr) * 1998-11-26 2001-01-05 Commissariat Energie Atomique Derives de calixarenes, leur procede de preparation et leur utilisation pour l'extraction des actinides et des lanthanides
EP1063239A1 (fr) * 1999-06-25 2000-12-27 Societe De Conseils De Recherches Et D'applications Scientifiques (S.C.R.A.S.) Nouveaux composés possédant un lanthanide et un ligand tridentate, leur procédé de préparation et leur application notamment comme catalyseurs de polymérisation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2560603C2 (ru) * 2009-07-27 2015-08-20 Коммиссариат А Л' Энержи Атомик Э Оз Энержи Альтернатив Повышение коэффициента разделения америция и кюрия и/или лантанидов в процедуре экстракции жидкости жидкостью с применением дигликольмида и другого экстрагирующего вещества

Also Published As

Publication number Publication date
JP2002001007A (ja) 2002-01-08
FR2810679A1 (fr) 2001-12-28
JP4524394B2 (ja) 2010-08-18

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Effective date: 20150227