FR3080114B1 - Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides - Google Patents

Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides Download PDF

Info

Publication number
FR3080114B1
FR3080114B1 FR1853263A FR1853263A FR3080114B1 FR 3080114 B1 FR3080114 B1 FR 3080114B1 FR 1853263 A FR1853263 A FR 1853263A FR 1853263 A FR1853263 A FR 1853263A FR 3080114 B1 FR3080114 B1 FR 3080114B1
Authority
FR
France
Prior art keywords
diglycolamides
rare earths
aqueous solutions
acidic aqueous
amphiphilic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1853263A
Other languages
English (en)
Other versions
FR3080114A1 (fr
Inventor
Eugen Andreiadis
Guillaume Mossand
Damien Rinsant
Marie-Therese Duchesne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1853263A priority Critical patent/FR3080114B1/fr
Priority to AU2019250770A priority patent/AU2019250770A1/en
Priority to PCT/FR2019/050883 priority patent/WO2019197792A1/fr
Priority to CA3092179A priority patent/CA3092179A1/fr
Priority to EP19742823.8A priority patent/EP3749641A1/fr
Publication of FR3080114A1 publication Critical patent/FR3080114A1/fr
Application granted granted Critical
Publication of FR3080114B1 publication Critical patent/FR3080114B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C235/06—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/32—Carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B59/00—Obtaining rare earth metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/007—Wet processes by acid leaching
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

L'invention se rapporte à de nouveaux diglycolamides dissymétriques au caractère amphiphile optimisé, propres à être utilisés comme extractants des terres rares. Ces diglycolamides répondent aux formules générales (I) et (II) : dans lesquelles : R1 = groupe alkyle, linéaire ou ramifié, en C2 à C4 ; R2 = groupe alkyle, linéaire ou ramifié, en C9 à C14 ; à l'exception toutefois du diglycolamide de formule générale (I) dans laquelle R1 = groupe n-butyle et R2 = groupe n-dodécyle et du diglycolamide de formule générale (II) dans laquelle R1 = groupe éthyle et R2 = groupe n-dodécyle. L'invention se rapporte également à l'utilisation de ces diglycolamides pour extraire les terres rares de solutions aqueuses acides. Applications : production de terres rares à partir de concentrés issus de « minerais urbains », de concentrés issus de minerais naturels riches en terres rares ou de concentrés issus de résidus de minerais naturels.
FR1853263A 2018-04-13 2018-04-13 Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides Active FR3080114B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1853263A FR3080114B1 (fr) 2018-04-13 2018-04-13 Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides
AU2019250770A AU2019250770A1 (en) 2018-04-13 2019-04-15 Amphiphilic asymmetrical diglycolamides and use thereof for extracting rare earth metals from acidic aqueous solutions
PCT/FR2019/050883 WO2019197792A1 (fr) 2018-04-13 2019-04-15 Diglycolamides dissymétriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides
CA3092179A CA3092179A1 (fr) 2018-04-13 2019-04-15 Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides
EP19742823.8A EP3749641A1 (fr) 2018-04-13 2019-04-15 Diglycolamides dissymétriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1853263 2018-04-13
FR1853263A FR3080114B1 (fr) 2018-04-13 2018-04-13 Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides

Publications (2)

Publication Number Publication Date
FR3080114A1 FR3080114A1 (fr) 2019-10-18
FR3080114B1 true FR3080114B1 (fr) 2021-10-08

Family

ID=62751114

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1853263A Active FR3080114B1 (fr) 2018-04-13 2018-04-13 Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides

Country Status (5)

Country Link
EP (1) EP3749641A1 (fr)
AU (1) AU2019250770A1 (fr)
CA (1) CA3092179A1 (fr)
FR (1) FR3080114B1 (fr)
WO (1) WO2019197792A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4175941A2 (fr) * 2020-07-06 2023-05-10 UT-Battelle, LLC Procédés de séparation et de récupération d'éléments de terres rares contenus dans solutions aqueuses faisant appel à des dérivés de diglycolamide
CN114058023B (zh) * 2020-08-07 2022-12-09 厦门稀土材料研究所 一种三齿酰胺基修饰mil型晶态材料及其制备方法和应用
CN115417787B (zh) * 2022-09-19 2024-02-02 四川大学 一种快速高效分离提取锶的萃取剂及其制备方法
FR3140634A1 (fr) 2022-10-06 2024-04-12 Commissariat A L'energie Atomique Et Aux Energies Alternatives Utilisation de dérivés lipophiles d’acides aminopolycarboxyliques pour l’extraction de terres rares d’une solution aqueuse acide

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4524394B2 (ja) * 2000-06-21 2010-08-18 独立行政法人 日本原子力研究開発機構 酸性溶液中に存在するアメリシウム及びネオジムの抽出方法
FR3026099B1 (fr) 2014-09-24 2017-06-02 Commissariat Energie Atomique Procedes de recuperation selective de terres rares presentes dans des phases aqueuses acides issues du traitement d'aimants permanents usages ou rebutes
CN106834681B (zh) * 2017-01-19 2018-07-10 济南大学 一种使用酰胺荚醚类萃取剂去除Pr中Fe杂质的方法

Also Published As

Publication number Publication date
AU2019250770A2 (en) 2020-11-19
WO2019197792A1 (fr) 2019-10-17
CA3092179A1 (fr) 2019-10-17
EP3749641A1 (fr) 2020-12-16
AU2019250770A1 (en) 2020-10-08
FR3080114A1 (fr) 2019-10-18

Similar Documents

Publication Publication Date Title
FR3080114B1 (fr) Diglycolamides dissymetriques amphiphiles et leur utilisation pour extraire les terres rares de solutions aqueuses acides
MA46325B1 (fr) Composés dinucléotidiques cycliques
FR2956863B1 (fr) Emulsion acrylique associative contenant un monomere a base d'alcool oxo, son procede de fabrication et procede d'epaississement d'une formulation aqueuse a partir de cette emulsion.
MA27725A1 (fr) Benzopyrannes utiles pour le traitement d'etats inflammatoires
MA38194B1 (fr) Anticorps anti-ceacam5 et leurs utilisations
TN2014000463A1 (fr) Nouveaux composés bifonctionnels utiles comme ligands de l'uranium(vi), leurs procédés de synthèse et leurs utilisations
NZ591789A (en) Preparation of canola protein isolate from canola oil seeds ("blendertein")
MXPA06000303A (es) Un proceso para fabricar una toallita limpiadora humeda usando una emulsion concentrada.
MA35895B1 (fr) Inhibiteurs d'iap
MX2017015453A (es) Procedimiento para producir acido acetico.
MA41356A1 (fr) Utilisation de nouveaux composés pour l'extraction sélective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procédé d'extraction associé
PH12016500647A1 (en) Antiperspirant emulsion sticks
FR3075636B1 (fr) Utilisation d'alcool de guerbet et/ou de triglyceride caprylique/caprique comme solvant d'extraction
JP2018507175A5 (fr)
EA201490777A1 (ru) Способ добычи нефти с применением поверхностно-активных соединений на основе смеси с20-гуэрбет-, с22-гуэрбет-, с24- гуэрбет- содержащих углеводород-алкоксилаты
BR112014010009A2 (pt) "anticorpo que se liga a cd44, seus métodos de produção e usos no tratamento ou prevenção de malignidade hematológica ou leucemia linfocítica crônica, método de alvejar anticorpo, kit de detecção, bem como composição farmacêutica, molécula de ácido nucleico e vetor de expressão"
FR2950807B1 (fr) Composition cosmetique contenant des liposomes encapsules dans un compose oxazolidin-2-one
EA201692234A1 (ru) Композиция в форме эмульсии "масло-в-воде", содержащая молотое семя белой или желтой горчицы
EA202090758A1 (ru) Стабильная смесь алкилэфирсульфата для повышения нефтеотдачи
MY144469A (en) Process for the distillative separation of mixtures comprising monoethylene glycol and diethylentriamine
FR3034417B1 (fr) Composes a fonctions oxyde de phosphine et amine, utiles comme ligands de l'uranium(vi), et leurs utilisations, notamment pour extraire l'uranium(vi) de solutions aqueuses d'acide sulfurique
FR3067349B1 (fr) Nouveaux agents mono et di-antennes complexants hydrosolubles et complexes de lanthanide correspondants
MA44930B1 (fr) "nouvel extractant , utile pour extraire des terres rares d'une solution aqueuse d'acide phosphorique , et ses applications."
IL166182A0 (en) Simmondsin for use as an angiogenesis inhibitor
TN2010000111A1 (fr) Nouveaux sels d'addition d'inhibiteurs d'enzyme de conversion de l'angiotensine a des acides donneurs de no, leur procede de preparation et les compositions pharmaceutiques qui les contiennent

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20191018

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5

PLFP Fee payment

Year of fee payment: 6

PLFP Fee payment

Year of fee payment: 7