FR2489816A1 - Procede d'hydroxylation des hydrocarbures aromatiques - Google Patents

Procede d'hydroxylation des hydrocarbures aromatiques Download PDF

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Publication number
FR2489816A1
FR2489816A1 FR8117023A FR8117023A FR2489816A1 FR 2489816 A1 FR2489816 A1 FR 2489816A1 FR 8117023 A FR8117023 A FR 8117023A FR 8117023 A FR8117023 A FR 8117023A FR 2489816 A1 FR2489816 A1 FR 2489816A1
Authority
FR
France
Prior art keywords
hydroxylation
hydrogen peroxide
reaction
phenol
titanium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8117023A
Other languages
English (en)
French (fr)
Other versions
FR2489816B1 (de
Inventor
Antonio Esposito
Marco Taramasso
Carlo Neri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anic SpA
Original Assignee
Anic SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anic SpA filed Critical Anic SpA
Publication of FR2489816A1 publication Critical patent/FR2489816A1/fr
Application granted granted Critical
Publication of FR2489816B1 publication Critical patent/FR2489816B1/fr
Granted legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/046—Chromiasilicates; Aluminochromosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/26—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR8117023A 1980-09-09 1981-09-08 Procede d'hydroxylation des hydrocarbures aromatiques Granted FR2489816A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT24547/80A IT1195029B (it) 1980-09-09 1980-09-09 Procedimento per la ossidrilazione di idrocarburi aromatici

Publications (2)

Publication Number Publication Date
FR2489816A1 true FR2489816A1 (fr) 1982-03-12
FR2489816B1 FR2489816B1 (de) 1984-08-31

Family

ID=11213933

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8117023A Granted FR2489816A1 (fr) 1980-09-09 1981-09-08 Procede d'hydroxylation des hydrocarbures aromatiques

Country Status (11)

Country Link
US (1) US4396783A (de)
BE (1) BE890290A (de)
CH (1) CH648278A5 (de)
DE (1) DE3135559C2 (de)
DK (1) DK156715C (de)
FR (1) FR2489816A1 (de)
GB (1) GB2083816B (de)
IT (1) IT1195029B (de)
NL (1) NL191629C (de)
NO (1) NO154631C (de)
SE (1) SE449992B (de)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2523575A1 (fr) * 1982-03-19 1983-09-23 Anic Spa Procede pour l'hydroxylation d'hydrocarbures aromatiques
EP0299893A2 (de) * 1987-07-17 1989-01-18 Rhone-Poulenc Chimie Verfahren zur Hydroxylierung von Phenolen und Phenolethern
EP0346250A1 (de) * 1988-06-08 1989-12-13 Rhone-Poulenc Chimie Verfahren zur Hydroxylierung von Phenolen und Phenoläthern
US8247620B2 (en) 2006-09-04 2012-08-21 Rhodia Operations Production of highly pure hydroquinone
US8628849B2 (en) 2007-12-19 2014-01-14 Rhodia Operations Method for preparing purified pyrocatechol
WO2018229033A1 (fr) 2017-06-13 2018-12-20 Rhodia Operations Compositions comprenant de l'hydroquinone et du catechol, procede de preparation de ces compositions
WO2019106142A1 (fr) 2017-11-30 2019-06-06 Rhodia Operations Compositions comprenant du 4-alkoxyphénol et du 2-alkoxyphénol, et leur procede de preparation
WO2019115760A1 (fr) 2017-12-15 2019-06-20 Rhodia Operations Procédé d'hydroxylation d'un composé aromatique

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1152299B (it) * 1982-07-28 1986-12-31 Anic Spa Procedimento per l'espossidazione di composti olefinici
IT1152301B (it) * 1982-07-28 1986-12-31 Anic Spa Procedimento per l'ossidazione di composti vinilbenzenici a beta-feniladeidi
IT1152298B (it) * 1982-07-28 1986-12-31 Anic Spa Procedimento per l'ossidazione di alcooli ad aldeidi e/o chetoni
US4588845A (en) * 1983-07-18 1986-05-13 Fmc Corporation Oxidation of unsaturated organic compounds with hydrogen peroxide
US4578521A (en) * 1985-02-04 1986-03-25 Mobil Oil Corporation Shape-selective catalytic oxidation of phenol
IT1187661B (it) * 1985-04-23 1987-12-23 Enichem Sintesi Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica
US4996385A (en) * 1988-11-17 1991-02-26 Aristech Chemical Corporation Use of silica-titania hydrocarbon conversion catalyst in hydrocarbon conversion processes
FR2643633B1 (fr) * 1989-02-28 1991-05-10 Rhone Poulenc Chimie Procede d'hydroxylation de phenols et d'ethers de phenols
IT1246372B (it) * 1990-01-19 1994-11-18 Enichem Sintesi Procedimento per la preparazione di miscele di derivati ossidrilici di idrocarburi aromatici a rapporto controllato dei costituenti
US5214168A (en) * 1992-04-30 1993-05-25 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5233097A (en) * 1992-10-15 1993-08-03 Uop Oxidation of aromatics to hydroxyaromatics using aluminosilicates containing framework titanium
US5493061A (en) * 1994-12-09 1996-02-20 Council Of Scientific & Industrial Research Process for the conversion of phenol to hydroquinone and catechol
CN1049610C (zh) * 1995-06-02 2000-02-23 复旦大学 不含铝的钛(锆、钒)硅五员环沸石催化剂的制备方法
US5874646A (en) * 1996-08-07 1999-02-23 Solutia Inc. Preparation of phenol or phenol derivatives
WO2000004076A2 (en) * 1998-07-14 2000-01-27 Eastman Chemical Company Polyester comprising a residue of isophthalic acid, terephthalic acid, ethylene glycol and an aromatic diol derivative and a method for identifying the polyester by fluorescence
DE19925534A1 (de) 1999-06-04 2000-12-07 Degussa Verfahren zur Aufbereitung von Abwässern
CN1130258C (zh) * 2000-06-15 2003-12-10 中国石油化工集团公司 苯酚氧化制备苯二酚的催化剂
CN1130259C (zh) * 2000-06-15 2003-12-10 中国石油化工集团公司 苯酚直接氧化制备苯二酚的催化剂
US6441250B2 (en) * 2000-06-22 2002-08-27 Ube Industries, Ltd. Process for producing dihydric phenol
AU2002356941A1 (en) * 2001-11-15 2003-06-10 Pq Holding, Inc. Method for controlling synthesis conditions during molecular sieve synthesis using combinations of quaternary ammonium hydroxides and halides
JP4772326B2 (ja) * 2002-05-31 2011-09-14 中國石油化工股▲分▼有限公司 チタン含有触媒の再生方法
DE60328693D1 (de) * 2002-05-31 2009-09-17 China Petroleum & Chemical Verfahren zur oxadimierung von carbonylverbindungen
US6872857B1 (en) * 2003-09-29 2005-03-29 Council Of Scientific And Industrial Research Process for conversion of phenol to hydroquinone and quinones
WO2005063664A1 (en) * 2003-12-31 2005-07-14 Council Of Scientific & Industrial Research Process for conversion of phenol to hydroquinone and quinones
FR2903097B1 (fr) * 2006-06-29 2012-10-19 Rhodia Recherches & Tech Procede de preparation d'hydroquinone purifiee et mise en forme
TWI471299B (zh) 2012-10-04 2015-02-01 China Petrochemical Dev Corp Taipei Taiwan Hydroxylation of phenol
SG11201505970YA (en) * 2013-09-20 2015-11-27 Mitsui Chemicals Inc Process for producing aromatic dihydroxy compound
JP7046498B2 (ja) * 2017-04-17 2022-04-04 三井化学株式会社 アルコキシフェノール類の製造方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1483162A (fr) * 1965-06-10 1967-06-02 Ici Ltd Procédé de production de phénols
FR1501092A (fr) * 1965-10-04 1967-11-10 Ici Ltd Procédé d'oxydation d'un hydrocarbure aromatique en phénol correspondant
US3580956A (en) * 1967-11-03 1971-05-25 Universal Oil Prod Co Hydroxylation of aromatic compounds
US3662006A (en) * 1969-05-12 1972-05-09 Universal Oil Prod Co Hydroxylation of aromatic compounds
FR2121000A5 (de) * 1970-12-29 1972-08-18 Mitsubishi Chem Ind
JPS497234A (de) * 1972-05-25 1974-01-22
FR2290411A1 (fr) * 1974-11-07 1976-06-04 Ube Industries Procede pour la preparation d'ethers hydroxyphenyliques

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1125971A (en) * 1965-06-10 1968-09-05 Ici Ltd Production of phenols
US4045896A (en) * 1975-11-26 1977-09-06 General Electric Company X-ray film storage and viewing device
DE2804537C2 (de) * 1978-02-03 1983-05-19 Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln Verfahren zur katalytischen Isomerisierung von o-Kresol

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1483162A (fr) * 1965-06-10 1967-06-02 Ici Ltd Procédé de production de phénols
FR1501092A (fr) * 1965-10-04 1967-11-10 Ici Ltd Procédé d'oxydation d'un hydrocarbure aromatique en phénol correspondant
US3580956A (en) * 1967-11-03 1971-05-25 Universal Oil Prod Co Hydroxylation of aromatic compounds
US3662006A (en) * 1969-05-12 1972-05-09 Universal Oil Prod Co Hydroxylation of aromatic compounds
FR2121000A5 (de) * 1970-12-29 1972-08-18 Mitsubishi Chem Ind
JPS497234A (de) * 1972-05-25 1974-01-22
FR2290411A1 (fr) * 1974-11-07 1976-06-04 Ube Industries Procede pour la preparation d'ethers hydroxyphenyliques

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CA1974 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2523575A1 (fr) * 1982-03-19 1983-09-23 Anic Spa Procede pour l'hydroxylation d'hydrocarbures aromatiques
EP0299893A2 (de) * 1987-07-17 1989-01-18 Rhone-Poulenc Chimie Verfahren zur Hydroxylierung von Phenolen und Phenolethern
EP0299893A3 (de) * 1987-07-17 1990-08-16 Rhone-Poulenc Chimie Verfahren zur Hydroxylierung von Phenolen und Phenolethern
EP0346250A1 (de) * 1988-06-08 1989-12-13 Rhone-Poulenc Chimie Verfahren zur Hydroxylierung von Phenolen und Phenoläthern
FR2632632A1 (fr) * 1988-06-08 1989-12-15 Rhone Poulenc Chimie Procede d'hydroxylation de phenols et d'ethers de phenols
US8247620B2 (en) 2006-09-04 2012-08-21 Rhodia Operations Production of highly pure hydroquinone
US8628849B2 (en) 2007-12-19 2014-01-14 Rhodia Operations Method for preparing purified pyrocatechol
WO2018229033A1 (fr) 2017-06-13 2018-12-20 Rhodia Operations Compositions comprenant de l'hydroquinone et du catechol, procede de preparation de ces compositions
WO2019106142A1 (fr) 2017-11-30 2019-06-06 Rhodia Operations Compositions comprenant du 4-alkoxyphénol et du 2-alkoxyphénol, et leur procede de preparation
WO2019115760A1 (fr) 2017-12-15 2019-06-20 Rhodia Operations Procédé d'hydroxylation d'un composé aromatique
FR3075198A1 (fr) * 2017-12-15 2019-06-21 Rhodia Operations Procede d'hydroxylation d'un compose aromatique

Also Published As

Publication number Publication date
GB2083816B (en) 1984-07-25
DK156715C (da) 1990-03-05
SE449992B (sv) 1987-06-01
DE3135559A1 (de) 1982-03-25
NL191629C (nl) 1995-11-20
NO813025L (no) 1982-03-10
NL8104175A (nl) 1982-04-01
NL191629B (nl) 1995-07-17
US4396783A (en) 1983-08-02
DK387281A (da) 1982-03-10
GB2083816A (en) 1982-03-31
NO154631C (no) 1986-11-19
BE890290A (fr) 1982-03-09
CH648278A5 (it) 1985-03-15
FR2489816B1 (de) 1984-08-31
NO154631B (no) 1986-08-11
SE8105370L (sv) 1982-03-10
IT1195029B (it) 1988-09-28
DE3135559C2 (de) 1984-12-06
IT8024547A0 (it) 1980-09-09
DK156715B (da) 1989-09-25

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