FR2461948A1 - Procede de production d'une couche plate d'un electrolyte solide pour un capteur d'oxygene du type en pellicule plate - Google Patents
Procede de production d'une couche plate d'un electrolyte solide pour un capteur d'oxygene du type en pellicule plate Download PDFInfo
- Publication number
- FR2461948A1 FR2461948A1 FR8015698A FR8015698A FR2461948A1 FR 2461948 A1 FR2461948 A1 FR 2461948A1 FR 8015698 A FR8015698 A FR 8015698A FR 8015698 A FR8015698 A FR 8015698A FR 2461948 A1 FR2461948 A1 FR 2461948A1
- Authority
- FR
- France
- Prior art keywords
- electrolyte
- paste
- layer
- stabilizing agent
- solid electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007784 solid electrolyte Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 34
- 239000001301 oxygen Substances 0.000 title claims abstract description 33
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 33
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000003792 electrolyte Substances 0.000 claims abstract description 49
- 239000003381 stabilizer Substances 0.000 claims abstract description 34
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 7
- 238000010411 cooking Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 claims description 2
- 235000015927 pasta Nutrition 0.000 claims 3
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 239000007789 gas Substances 0.000 abstract description 7
- 239000010410 layer Substances 0.000 description 68
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 11
- 238000009826 distribution Methods 0.000 description 5
- -1 oxygen ion Chemical class 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 238000007650 screen-printing Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 3
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- SKBXVAOMEVOTGJ-UHFFFAOYSA-N xi-Pinol Chemical compound CC1=CCC2C(C)(C)OC1C2 SKBXVAOMEVOTGJ-UHFFFAOYSA-N 0.000 description 2
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 1
- 235000017274 Diospyros sandwicensis Nutrition 0.000 description 1
- 241000282838 Lama Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000012749 thinning agent Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
- H01M8/1253—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing zirconium oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Molecular Biology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8924379A JPS5614149A (en) | 1979-07-16 | 1979-07-16 | Forming method for solid-state electrolyte thin film for oxygen sensor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2461948A1 true FR2461948A1 (fr) | 1981-02-06 |
| FR2461948B1 FR2461948B1 (https=) | 1982-04-02 |
Family
ID=13965302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8015698A Granted FR2461948A1 (fr) | 1979-07-16 | 1980-07-16 | Procede de production d'une couche plate d'un electrolyte solide pour un capteur d'oxygene du type en pellicule plate |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4338356A (https=) |
| JP (1) | JPS5614149A (https=) |
| DE (1) | DE3026780C2 (https=) |
| FR (1) | FR2461948A1 (https=) |
| GB (1) | GB2054168B (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6036949A (ja) * | 1983-08-09 | 1985-02-26 | Ngk Insulators Ltd | 酸素センサ素子 |
| DE3529335A1 (de) * | 1985-08-16 | 1987-02-26 | Draegerwerk Ag | Festkoerperkette zur aktivitaetsmessung mit festem ionenleiter |
| DE3723051A1 (de) * | 1987-07-11 | 1989-01-19 | Kernforschungsz Karlsruhe | Halbleiter fuer einen resistiven gassensor mit hoher ansprechgeschwindigkeit |
| JPS6439307A (en) * | 1987-08-04 | 1989-02-09 | Nippon Dia Clevite Co | Copper base sliding bearing material |
| JP2648341B2 (ja) * | 1988-07-29 | 1997-08-27 | 田中貴金属工業株式会社 | 薄膜酸素センサの製造方法 |
| US5273640A (en) * | 1990-06-11 | 1993-12-28 | Matsushita Electric Works, Ltd. | Electrochemical gas sensor |
| JPH04149064A (ja) * | 1990-10-08 | 1992-05-22 | Nissan Chem Ind Ltd | 固体電解質磁器 |
| US5273779A (en) * | 1991-12-09 | 1993-12-28 | Industrial Technology Research Institute | Method of fabricating a gas sensor and the product fabricated thereby |
| DE102012218649A1 (de) * | 2012-10-12 | 2014-04-17 | Robert Bosch Gmbh | Sensorelement zur Erfassung mindestens einer Eigenschaft eines Messgases in einem Messgasraum |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2045054A5 (en) * | 1969-05-30 | 1971-02-26 | Gen Electric | High temperature oxygen measuring apparatus - with solid oxygen ion electrolyte |
| DE2304464A1 (de) * | 1973-01-31 | 1974-08-08 | Bosch Gmbh Robert | Messfuehler fuer die ueberwachung der funktionsfaehigkeit von katalysatoren in abgasentgiftungsanlagen von brennkraftmaschinen |
| US3843400A (en) * | 1972-09-18 | 1974-10-22 | Westinghouse Electric Corp | Solid electrolyte cell |
| US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
| DE2742279A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| DE2709173A1 (de) * | 1977-03-03 | 1978-09-07 | Bosch Gmbh Robert | Messfuehler zum messen der abgaszusammensetzung |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5348594A (en) * | 1976-10-14 | 1978-05-02 | Nissan Motor | Oxygen sensor |
| JPS5439191A (en) * | 1977-09-02 | 1979-03-26 | Hitachi Ltd | Oxygen detector |
| JPS5523426A (en) * | 1978-08-08 | 1980-02-19 | Toyota Motor Corp | Oxygen sensor element |
| DE2852638C2 (de) | 1978-12-06 | 1986-01-16 | Robert Bosch Gmbh, 7000 Stuttgart | Gassensor mit Cermet- Elektroden |
-
1979
- 1979-07-16 JP JP8924379A patent/JPS5614149A/ja active Pending
-
1980
- 1980-07-15 DE DE3026780A patent/DE3026780C2/de not_active Expired
- 1980-07-15 US US06/169,031 patent/US4338356A/en not_active Expired - Lifetime
- 1980-07-16 GB GB8023211A patent/GB2054168B/en not_active Expired
- 1980-07-16 FR FR8015698A patent/FR2461948A1/fr active Granted
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2045054A5 (en) * | 1969-05-30 | 1971-02-26 | Gen Electric | High temperature oxygen measuring apparatus - with solid oxygen ion electrolyte |
| US3843400A (en) * | 1972-09-18 | 1974-10-22 | Westinghouse Electric Corp | Solid electrolyte cell |
| DE2304464A1 (de) * | 1973-01-31 | 1974-08-08 | Bosch Gmbh Robert | Messfuehler fuer die ueberwachung der funktionsfaehigkeit von katalysatoren in abgasentgiftungsanlagen von brennkraftmaschinen |
| US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
| DE2742279A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| DE2709173A1 (de) * | 1977-03-03 | 1978-09-07 | Bosch Gmbh Robert | Messfuehler zum messen der abgaszusammensetzung |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2054168B (en) | 1983-04-20 |
| DE3026780A1 (de) | 1981-01-29 |
| DE3026780C2 (de) | 1984-02-23 |
| US4338356A (en) | 1982-07-06 |
| JPS5614149A (en) | 1981-02-10 |
| GB2054168A (en) | 1981-02-11 |
| FR2461948B1 (https=) | 1982-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |