FR2375262A1 - Copolymere statistique de propylene et 1-butene et procede de production - Google Patents

Copolymere statistique de propylene et 1-butene et procede de production

Info

Publication number
FR2375262A1
FR2375262A1 FR7739071A FR7739071A FR2375262A1 FR 2375262 A1 FR2375262 A1 FR 2375262A1 FR 7739071 A FR7739071 A FR 7739071A FR 7739071 A FR7739071 A FR 7739071A FR 2375262 A1 FR2375262 A1 FR 2375262A1
Authority
FR
France
Prior art keywords
jis
copolymer
butene
propylene
measured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7739071A
Other languages
English (en)
Other versions
FR2375262B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Publication of FR2375262A1 publication Critical patent/FR2375262A1/fr
Application granted granted Critical
Publication of FR2375262B1 publication Critical patent/FR2375262B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/906—Comminution of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un copolymère statistique. Selon l'invention, il se compose essentiellement de 40 à 90 % en moles de propylène et de 60 à 10 % en moles de 1-butène, et il a : a. une teneur insoluble dans n-heptane bouillant qui n'est pas supérieure à 5 % en poids en se basant sur le poids du copolymère; b. une teneur soluble dans l'acétate de méthyle bouillant qui n'est pas supérieure à 2 % en poids en se basant sur le poids du copolymère; c. un point de fusion déterminé par analyse thermique différentielle, de 40 à 140 degrés C; d. une viscosité intrinsèque, déterminée dans la décaline à 135 degrés C, de 0,5 à 6 dl/g; e. un allongement à la rupture, mesuré par la norme JIS K6301, d'au moins 300 %; f. une résistance à la traction ultime mesurée par la norme JIS K6301 d'au moins 50 kg/cm**2, et g. un voile, mesuré par la norme JIS K6714 qui n'est pas supérieur à 40 %. L'invention permet notamment d'obtenir un copolymère statistique ayant les propriétés typiques du caoutchouc et de la matiere plastique, et permettant d'obtenir diverses sortes d'articles en forme comme des pellicules, feuilles, récipients et tubes.
FR7739071A 1976-12-24 1977-12-23 Copolymere statistique de propylene et 1-butene et procede de production Granted FR2375262A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15506876A JPS5379984A (en) 1976-12-24 1976-12-24 Copolymer and production

Publications (2)

Publication Number Publication Date
FR2375262A1 true FR2375262A1 (fr) 1978-07-21
FR2375262B1 FR2375262B1 (fr) 1980-10-24

Family

ID=15597954

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7739071A Granted FR2375262A1 (fr) 1976-12-24 1977-12-23 Copolymere statistique de propylene et 1-butene et procede de production

Country Status (8)

Country Link
US (1) US4168361A (fr)
JP (1) JPS5379984A (fr)
CA (1) CA1070900A (fr)
DE (1) DE2757863C2 (fr)
FR (1) FR2375262A1 (fr)
GB (1) GB1563977A (fr)
IT (1) IT1089076B (fr)
NL (1) NL171454C (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2462449A1 (fr) * 1979-07-30 1981-02-13 Naphtachimie Sa Procede de fabrication de copolymeres de propylene et de butene-1, produits en resultant et leurs applications
EP0682042A1 (fr) * 1993-11-29 1995-11-15 Mitsui Petrochemical Industries, Ltd. Elastomere a base de propylene

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1495776A (en) * 1975-06-11 1977-12-21 Ici Ltd Film-forming olefin polymer compositions
US4258167A (en) * 1978-02-13 1981-03-24 Nissan Chemical Industries, Ltd. Process for producing powdery isotactic polyolefin
JPS54158489A (en) * 1978-06-05 1979-12-14 Mitsubishi Petrochem Co Ltd Polymerization of olefin
JPS5757771Y2 (fr) * 1978-06-30 1982-12-11
DE2830929A1 (de) * 1978-07-14 1980-01-24 Basf Ag Verfahren zum herstellen einer titan-komponente fuer polymerisationskatalysatoren des ziegler-natta-typs
JPS5534238A (en) * 1978-08-31 1980-03-10 Chisso Corp Preparation of alpha-olefin polymer
JPS5582103A (en) * 1978-12-15 1980-06-20 Mitsubishi Petrochem Co Ltd Production of alpha-olefin polymer
PT70691A (fr) * 1979-01-17 1980-02-01 Naphtachimie Sa Procede pour la fabrication de copolymeres de propylene etde butene-1 et leurs applications
JPS55102606A (en) * 1979-01-30 1980-08-06 Mitsui Toatsu Chem Inc Polymerization of alpha-olefin
JPS6042805B2 (ja) * 1979-02-27 1985-09-25 日石三菱株式会社 共重合体の製法
JPS55115416A (en) * 1979-02-27 1980-09-05 Nippon Oil Co Ltd Manufacture of copolymer
ZA801724B (en) * 1979-04-01 1981-03-25 Stamicarbon Catalytic titanium compound,process for the manufacture thereof,and process for the polymerization of lakenes-1 with application of such a titanium component
JPS55135105A (en) * 1979-04-10 1980-10-21 Mitsui Petrochem Ind Ltd Titanium catalyst component for olefin polymerization
JPS5611908A (en) * 1979-07-11 1981-02-05 Mitsui Petrochem Ind Ltd Preparation of olefin polymer
DE2930108C2 (de) * 1979-07-25 1982-11-25 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von weitgehend amorphen Buten-1 Propen-Ethen-Terpolymeren mit hohem Erweichungspunkt
JPS6024805B2 (ja) * 1979-09-05 1985-06-14 日石三菱株式会社 共重合体の製法
US4339495A (en) * 1979-10-05 1982-07-13 Mobil Oil Corporation Heat sealable packaging film comprising propylene polymer substrate and olefin surface layer blend of polybutene-1 and ethylene or a propylene copolymer
WO1982000826A1 (fr) * 1980-01-10 1982-03-18 J Collette Poly(1-butene)elastomere fractionnable
JPS56136805A (en) * 1980-03-29 1981-10-26 Mitsui Petrochem Ind Ltd Titanium catalyst component for olefin polymerization
US4347158A (en) * 1980-05-02 1982-08-31 Dart Industries, Inc. Supported high efficiency polyolefin catalyst component and methods of making and using the same
US4425257A (en) 1980-05-02 1984-01-10 Phillips Petroleum Company Supported high efficiency polyolefin catalyst component and methods of making and using the same
US4422957A (en) * 1980-05-02 1983-12-27 Phillips Petroleum Company Methods of producing polyolefins using supported high efficiency polyolefin catalyst components
JPS57125207A (en) * 1981-01-29 1982-08-04 Mitsui Toatsu Chem Inc Preparation of terpolymer by solution process
DE3269975D1 (en) * 1981-08-07 1986-04-24 Ici Plc Spraying solid
EP0072129B2 (fr) * 1981-08-07 1990-02-28 Imperial Chemical Industries Plc Composition à base d'un métal de transition sur un support
US4431572A (en) * 1982-05-14 1984-02-14 Standard Oil Company (Indiana) Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound, a chlorocarbon and an ester
US4431570A (en) * 1982-05-14 1984-02-14 Standard Oil Company (Indiana) Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound and an ester
US4431571A (en) * 1982-05-14 1984-02-14 Standard Oil Company (Indiana) Retreating comminuted olefin polymerization catalyst with a titanium(IV) compound, a haloalkylchlorosilane and an ester
US4555496A (en) * 1982-08-20 1985-11-26 Phillips Petroleum Company Supported polyolefin catalyst components and methods of making and using the same
US4461872A (en) * 1983-02-22 1984-07-24 E. I. Du Pont De Nemours And Company Blends of a propylene/α-olefin copolymer with isotactic prolypropylene
JPS6038414A (ja) * 1983-08-12 1985-02-28 Mitsui Petrochem Ind Ltd 熱可塑性樹脂共重合体
US4761462A (en) * 1983-09-20 1988-08-02 Sumitomo Chemical Company, Limited Packaging propylene copolymer film
US4540756A (en) * 1983-11-01 1985-09-10 Hercules Incorporated Process for making low crystallinity polyolefins
JPS62121711A (ja) * 1985-11-21 1987-06-03 Mitsui Petrochem Ind Ltd 低結晶性エチレン系ランダム共重合体
US4826939A (en) * 1987-08-31 1989-05-02 Eastman Kodak Company Highly amorphous olefin terpolymer
US5204182A (en) * 1990-05-04 1993-04-20 Imperial Chemical Industries Plc Polyolefin film
GB9010092D0 (en) * 1990-05-04 1990-06-27 Ici Plc Polyolefin film
US5714554A (en) * 1992-09-08 1998-02-03 Rexene Corporation High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers
US5302675A (en) * 1992-09-08 1994-04-12 Rexene Corporation High tensile strength amorphous 1-butene/propylene copolymers
DE69434709T2 (de) 1993-06-07 2006-10-19 Mitsui Chemicals, Inc. Propylenelastomere
JPH07196717A (ja) * 1994-10-24 1995-08-01 Mitsui Petrochem Ind Ltd 低結晶性エチレン系ランダム共重合体
US5922471A (en) * 1996-03-04 1999-07-13 Union Carbide Chemicals & Plastics Technology Corporation Metallizable polypropylene random copolymer compositions
SG60151A1 (en) * 1996-11-15 1999-02-22 Sumitomo Chemical Co Propylene-1-butene copolymer
JPH11181179A (ja) * 1997-12-22 1999-07-06 Sumitomo Chem Co Ltd 粉末成形用オレフィン系熱可塑性エラストマー組成物、粉末成形用粉末及び成形体
US6780808B2 (en) * 2002-07-15 2004-08-24 Univation Technologies, Llc Enhanced solubility of magnesium halides and catalysts and polymerization process using same
RU2006138354A (ru) * 2004-03-29 2008-05-10 Базелль Полиолефин Италия С.Р.Л. (It) Аддукты на основе хлорида магния и компоненты катализатора, полученные из них
KR20090034350A (ko) * 2006-06-23 2009-04-07 바셀 폴리올레핀 이탈리아 에스.알.엘 마그네슘 클로로알콜레이트계 촉매 전구체

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3238146A (en) * 1960-03-21 1966-03-01 Shell Oil Co Catalysts and their preparation
NL128622C (fr) 1963-03-13
US3332921A (en) * 1963-11-01 1967-07-25 Phillips Petroleum Co 1-butene-propylene copolymers
US3278504A (en) * 1965-02-12 1966-10-11 Eastman Kodak Co Hot melt adhesive for bookbinding based on the copolymers of butene-1 and propylene
IL40257A0 (en) * 1971-09-07 1972-10-29 Universal Oil Prod Co Polymerization catalyst systems,their preparation and their use
US3923758A (en) * 1973-07-02 1975-12-02 Eastman Kodak Co Substantially hexane soluble propylene/butene-1 copolymer containing 30 to 75 weight percent butene-1
JPS565404B2 (fr) * 1975-02-14 1981-02-04
JPS51133386A (en) * 1975-05-15 1976-11-19 Nippon Oil Co Ltd A process for manufacturing a polyolefin

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2462449A1 (fr) * 1979-07-30 1981-02-13 Naphtachimie Sa Procede de fabrication de copolymeres de propylene et de butene-1, produits en resultant et leurs applications
EP0682042A1 (fr) * 1993-11-29 1995-11-15 Mitsui Petrochemical Industries, Ltd. Elastomere a base de propylene
EP0682042A4 (fr) * 1993-11-29 1997-03-26 Mitsui Petrochemical Ind Elastomere a base de propylene.
US5677408A (en) * 1993-11-29 1997-10-14 Mitsui Petrochemical Industries, Ltd. Propylene elastomer and process for preparation thereof

Also Published As

Publication number Publication date
FR2375262B1 (fr) 1980-10-24
NL7714321A (nl) 1978-06-27
DE2757863A1 (de) 1978-06-29
CA1070900A (fr) 1980-01-29
JPS5379984A (en) 1978-07-14
US4168361A (en) 1979-09-18
DE2757863C2 (de) 1982-12-02
NL171454C (nl) 1983-04-05
GB1563977A (en) 1980-04-02
JPS5711322B2 (fr) 1982-03-03
IT1089076B (it) 1985-06-10

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