FR2356455A1 - Catalyseur perfectionne de polymerisation des olefines, son obtention et son application - Google Patents

Catalyseur perfectionne de polymerisation des olefines, son obtention et son application

Info

Publication number
FR2356455A1
FR2356455A1 FR7719840A FR7719840A FR2356455A1 FR 2356455 A1 FR2356455 A1 FR 2356455A1 FR 7719840 A FR7719840 A FR 7719840A FR 7719840 A FR7719840 A FR 7719840A FR 2356455 A1 FR2356455 A1 FR 2356455A1
Authority
FR
France
Prior art keywords
application
perfected
obtaining
polymerization catalyst
olefin polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7719840A
Other languages
English (en)
Other versions
FR2356455B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of FR2356455A1 publication Critical patent/FR2356455A1/fr
Application granted granted Critical
Publication of FR2356455B1 publication Critical patent/FR2356455B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention décrit l'obtention et l'application d'un catalyseur perfectionné pour la polymérisation des oléfines. On dépose un composé organique du chrome (de type indényle et/ou fluorényle) sur un support de silice qui a éte fluorée à basse température (100 degrés C à 400 degrés C). Ce catalyseur peut servir à l'homopolymérisation de l'éthylène et sa copolymérisation avec d'autres oléfines.
FR7719840A 1976-06-29 1977-06-28 Catalyseur perfectionne de polymerisation des olefines, son obtention et son application Granted FR2356455A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/700,843 US4077904A (en) 1976-06-29 1976-06-29 Olefin polymerization process and catalyst therefor

Publications (2)

Publication Number Publication Date
FR2356455A1 true FR2356455A1 (fr) 1978-01-27
FR2356455B1 FR2356455B1 (fr) 1983-12-23

Family

ID=24815102

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7719840A Granted FR2356455A1 (fr) 1976-06-29 1977-06-28 Catalyseur perfectionne de polymerisation des olefines, son obtention et son application

Country Status (16)

Country Link
US (2) US4077904A (fr)
JP (1) JPS533985A (fr)
AU (1) AU518530B2 (fr)
BE (1) BE856205A (fr)
BR (1) BR7704206A (fr)
CA (1) CA1091645A (fr)
DE (1) DE2729122C3 (fr)
DK (1) DK149204C (fr)
ES (2) ES460163A1 (fr)
FI (1) FI64943C (fr)
FR (1) FR2356455A1 (fr)
GB (1) GB1583803A (fr)
IT (1) IT1077540B (fr)
NL (1) NL178325C (fr)
NO (2) NO150399C (fr)
SE (1) SE440659B (fr)

Families Citing this family (110)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2734928A1 (de) * 1977-08-03 1979-02-22 Basf Ag Verfahren zum herstellen eines chromoxid-traegerkatalysators zur olefin-polymerisation
US4170589A (en) * 1978-02-22 1979-10-09 Union Carbide Corporation Catalytic polymerization of ethylene with supported chromium [II] catalyst in the presence of a phenolic antioxidant
DE3369398D1 (en) * 1982-05-19 1987-02-26 Ciba Geigy Ag Curable compositions containing metallocen complexes, activated primers obtained therefrom and their use
US4596862A (en) * 1984-12-24 1986-06-24 Phillips Petroleum Company Olefin polymerization using chromium on fluorided aluminophosphate
US5096868A (en) * 1987-10-21 1992-03-17 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins and alpha-olefins polymerization therewith
GB8919925D0 (en) * 1989-09-04 1989-10-18 Bp Chem Int Ltd Chromium-containing complex polymerisation catalyst
GB8919926D0 (en) * 1989-09-04 1989-10-18 Bp Chem Int Ltd Chromium-containing complex polymerisation catalyst
GB8919924D0 (en) * 1989-09-04 1989-10-18 Bp Chem Int Ltd Chromium-containing complex polymerisation catalyst
US5064796A (en) * 1991-01-07 1991-11-12 Exxon Chemical Patents Inc. Support adjuvant for improved vanadium polymerization catalyst
BE1005795A3 (fr) * 1992-05-13 1994-02-01 Solvay Procede de polymerisation d'olefines et (co)polymeres a blocs derives d'au moins une olefine.
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5885924A (en) 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
DE19645939A1 (de) * 1996-11-07 1998-05-14 Buna Sow Leuna Olefinverb Gmbh Verfahren zur Herstellung von ultrahochmolekularem Polyethylen und Methode zur Aktivierung des Katalysatorträgers
US6071614A (en) * 1997-07-14 2000-06-06 3M Innovative Properties Company Microporous fluorinated silica agglomerate and method of preparing and using same
FR2769245B1 (fr) * 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
BR9910611B1 (pt) * 1998-05-18 2009-05-05 processo para produção de uma composição de catalisador.
US6300271B1 (en) * 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) * 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6548442B1 (en) * 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6576583B1 (en) * 2000-02-11 2003-06-10 Phillips Petroleum Company Organometal catalyst composition
CA2357385C (fr) * 2001-09-17 2010-06-15 Nova Chemicals Corporation Catalyseur de polymerisation a base de phosphinimine sur support
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
ATE469927T1 (de) * 2003-03-21 2010-06-15 Dow Global Technologies Inc Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
CA2423921A1 (fr) * 2003-03-28 2004-09-28 Nova Chemicals Corporation Particules de composes organiques halogenes pour supports de catalyseur
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US7393910B2 (en) 2003-09-23 2008-07-01 Dow Global Technologies Inc. Catalyst composition for ethylene polymerization
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
US7629422B2 (en) 2004-12-21 2009-12-08 Univation Technologies, Llc Process for transitioning between Ziegler-Natta-based and chromium-based catalysts
US6987152B1 (en) 2005-01-11 2006-01-17 Univation Technologies, Llc Feed purification at ambient temperature
US7312279B2 (en) * 2005-02-07 2007-12-25 Univation Technologies, Llc Polyethylene blend compositions
US7947797B2 (en) 2005-09-14 2011-05-24 Univation Technologies, Llc Method for operating a gas-phase reactor at or near maximum production rates while controlling polymer stickiness
US7714082B2 (en) * 2005-10-04 2010-05-11 Univation Technologies, Llc Gas-phase polymerization process to achieve a high particle density
US20070109911A1 (en) * 2005-11-16 2007-05-17 Neubauer Anthony C High speed and direct driven rotating equipment for polyolefin manufacturing
EP1803747A1 (fr) 2005-12-30 2007-07-04 Borealis Technology Oy Catalyseur de polymérisation à surface modifiée pour réduire la formation de gels dans des films
DE102006004429A1 (de) * 2006-01-31 2007-08-02 Advanced Micro Devices, Inc., Sunnyvale Halbleiterbauelement mit einem Metallisierungsschichtstapel mit einem porösen Material mit kleinem ε mit einer erhöhten Integrität
EP3467077A1 (fr) 2006-10-03 2019-04-10 Univation Technologies, LLC Système pour la polymérisation des oléfines
CN101274968B (zh) * 2007-03-28 2012-11-21 中国石油化工股份有限公司 一种用于生产宽分子量分布的聚乙烯的复合催化剂
US7754834B2 (en) * 2007-04-12 2010-07-13 Univation Technologies, Llc Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density
TW200936564A (en) * 2007-11-15 2009-09-01 Univation Tech Llc Methods for the removal of impurities from polymerization feed streams
BRPI0922454A2 (pt) 2008-12-18 2018-05-22 Univation Tech Llc método para tratamento de leito de semente para uma reação de polimerização
WO2010080871A1 (fr) 2009-01-08 2010-07-15 Univation Technologies, Llc Additif pour procédés de polymérisation en phase gazeuse
RU2527945C2 (ru) 2009-01-08 2014-09-10 Юнивейшн Текнолоджиз, Ллк Добавка для процессов полимеризации полиолефинов
US20100326017A1 (en) * 2009-06-25 2010-12-30 Darla Kindel Protective Cover
CN102498136A (zh) 2009-07-09 2012-06-13 联合碳化化学及塑料技术有限责任公司 在用基于铬的催化剂制备聚烯烃的方法中增强的冷凝模式操作
CN102482372B (zh) 2009-07-23 2013-09-04 尤尼威蒂恩技术有限公司 聚合反应系统
WO2011078923A1 (fr) 2009-12-23 2011-06-30 Univation Technologies, Llc Procédés pour produire des systèmes de catalyseur
US8598283B2 (en) 2010-02-18 2013-12-03 Univation Technologies, Llc Methods for operating a polymerization reactor
MY162328A (en) 2010-02-22 2017-05-31 Univation Tech Llc Catalyst systems and methods for using same to produce polyolefin products
EP2558531B1 (fr) 2010-04-13 2017-02-15 Univation Technologies, LLC Mélanges de polymères et des films réalisés
WO2012009215A1 (fr) 2010-07-16 2012-01-19 Univation Technologies, Llc Systèmes et procédés pour mesurer la charge statique portée par des particules
WO2012009216A1 (fr) 2010-07-16 2012-01-19 Univation Technologies, Llc Systèmes et procédés de mesure d'accumulation de particules sur les surfaces d'un réacteur
WO2012015898A1 (fr) 2010-07-28 2012-02-02 Univation Technologies, Llc Systèmes et procédés pour mesurer la vitesse d'un mélange particule/fluide
JP5973462B2 (ja) 2010-12-17 2016-08-23 ユニベーション・テクノロジーズ・エルエルシー ポリオレフィンパージガス生成物から炭化水素を回収するためのシステム及び方法
CN103347905B (zh) 2010-12-22 2015-12-16 尤尼威蒂恩技术有限责任公司 用于聚烯烃聚合方法的添加剂
CA2740755C (fr) 2011-05-25 2019-01-15 Nova Chemicals Corporation Catalyseurs au chrome pour la polymerisation d'olefines
WO2013028283A1 (fr) 2011-08-19 2013-02-28 Univation Technologies, Llc Systèmes de catalyseur et leurs procédés d'utilisation pour la production de produits de polyoléfine
US9181371B2 (en) 2011-11-08 2015-11-10 Univation Technologies, Llc Methods for producing polyolefins with catalyst systems
ES2798272T3 (es) 2011-11-08 2020-12-10 Univation Tech Llc Métodos de preparación de un sistema catalítico
WO2013081748A1 (fr) 2011-11-30 2013-06-06 Univation Technologies, Llc Procédés et systèmes pour la distribution d'un catalyseur
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
IN2015DN02467A (fr) 2012-11-01 2015-09-04 Univation Tech Llc
IN2015DN03103A (fr) 2012-11-12 2015-10-02 Univation Tech Llc
CA2800056A1 (fr) 2012-12-24 2014-06-24 Nova Chemicals Corporation Compositions de melange de polyethylene
WO2014105614A1 (fr) 2012-12-28 2014-07-03 Univation Technologies, Llc Procédés consistant à intégrer la production d'aluminoxane dans la production de catalyseur
US10280283B2 (en) 2012-12-28 2019-05-07 Univation Technologies, Llc Supported catalyst with improved flowability
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
EP3080200B1 (fr) 2013-12-09 2018-11-14 Univation Technologies, LLC Alimentation d'additifs de polymérisation à des procédés de polymérisation
CA2837591A1 (fr) 2013-12-19 2015-06-19 Nova Chemicals Corporation Composition de polyethylene pour revetement par extrusion
CN114957529A (zh) 2014-04-02 2022-08-30 尤尼威蒂恩技术有限责任公司 连续性组合物及其制备和使用方法
CA2870027C (fr) 2014-11-07 2022-04-26 Matthew Zaki Botros Composition et procede de moulage par soufflage
EP3247547B1 (fr) 2015-01-21 2023-03-22 Univation Technologies, LLC Procédés de réduction de la teneur en gel des polyoléfines
SG11201705607QA (en) 2015-01-21 2017-08-30 Univation Tech Llc Methods for controlling polymer chain scission
CN107428875B (zh) 2015-03-10 2021-02-26 尤尼威蒂恩技术有限责任公司 喷雾干燥催化剂组合物、制备方法以及在烯烃聚合工艺中的用途
SG11201708626SA (en) 2015-04-27 2017-11-29 Univation Tech Llc Supported catalyst compositions having improved flow properties and preparation thereof
CN104877051B (zh) * 2015-05-06 2018-04-13 无锡耀汇科技有限公司 一种聚烯烃催化剂
CA2985112C (fr) 2015-05-08 2020-06-30 Exxonmobil Chemical Patents Inc. Procede de polymerisation renfermant du 2,2-dimethylpropane comme agent de condensation
US10975183B2 (en) 2016-09-09 2021-04-13 Exxonmobil Chemical Patents Inc. Pilot plant scale semi-condensing operation
WO2018063764A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
WO2018063767A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Processus de polymérisation
WO2018063765A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
WO2018118155A1 (fr) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
US11186654B2 (en) 2016-12-20 2021-11-30 Exxonmobil Chemical Patents Inc. Methods for controlling start up conditions in polymerization processes
CA3052770C (fr) 2017-02-07 2021-09-07 Exxonmobil Chemical Patents Inc. Procedes de reduction de perte d'activite catalytique d'un catalyseur ziegler-natta
WO2019118073A1 (fr) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Procédés de désactivation pour composants actifs à partir d'un procédé de polymérisation de polyoléfine en phase gazeuse
WO2019173030A1 (fr) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Procédés de préparation et de surveillance d'un lit de germination pour le démarrage d'un réacteur de polymérisation
CN112055719B (zh) 2018-05-02 2022-11-25 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
CN112055720B (zh) 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
CN112384542A (zh) 2018-06-28 2021-02-19 埃克森美孚化学专利公司 聚乙烯组合物、电线和电缆及其制备方法
WO2020014138A1 (fr) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Films coulés de polyéthylène et procédés de fabrication de tels films coulés de polyéthylène
WO2020023207A1 (fr) 2018-07-26 2020-01-30 Exxonmobil Chemical Patents Inc. Films de mousse multicouches et leurs procédés de fabrication
EP3880739A1 (fr) 2018-11-13 2021-09-22 ExxonMobil Chemical Patents Inc. Films de polyéthylène
WO2020102380A1 (fr) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Mélanges et films de polyéthylène
US11866522B2 (en) 2018-12-28 2024-01-09 Braskem S.A. Process for introducing catalyst in a polymerization process
WO2020163079A1 (fr) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films et enveloppes de couche pour articles d'hygiène
US20230018505A1 (en) 2019-12-17 2023-01-19 Exxonmobil Chemical Patents Inc. Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties
WO2021183337A1 (fr) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films constitués de mélanges de polyéthylène pour une rigidité à la flexion améliorée et une résistance à la déchirure en md élevée
WO2021205333A1 (fr) 2020-04-07 2021-10-14 Nova Chemicals (International) S.A. Polyéthylène haute densité pour articles rigides
CN116234837A (zh) 2020-07-22 2023-06-06 埃克森美孚化学专利公司 聚烯烃组合物及其制品
WO2022126068A1 (fr) 2020-12-08 2022-06-16 Exxonmobil Chemical Patents Inc. Compositions de polyéthylène haute densité à ramification à longue chaîne
US20240209124A1 (en) 2021-04-30 2024-06-27 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
WO2023081577A1 (fr) 2021-11-02 2023-05-11 Exxonmobil Chemical Patents Inc. Compositions de polyéthylène, articles associés et procédés associés

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3130188A (en) * 1960-10-07 1964-04-21 Phillips Petroleum Co Catalyst and process for producing olefin polymers
US3445367A (en) * 1965-11-22 1969-05-20 Phillips Petroleum Co Catalyst and process for making olefin polymers of narrow molecular weight distribution
US3509640A (en) * 1968-09-03 1970-05-05 Gen Motors Corp Domestic dryer speed control
US3687920A (en) * 1971-01-25 1972-08-29 Union Carbide Corp Polymerization of olefins with silane modified catalyst system
US3761427A (en) * 1971-03-29 1973-09-25 Phillips Petroleum Co Olefin disproportionation catalyst and process for using same
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4011382A (en) * 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
US4015059A (en) * 1975-12-29 1977-03-29 Union Carbide Corporation Fused ring catalyst and ethylene polymerization process therewith

Also Published As

Publication number Publication date
DE2729122C3 (de) 1985-06-20
FR2356455B1 (fr) 1983-12-23
FI64943C (fi) 1984-02-10
JPS533985A (en) 1978-01-14
JPS5622444B2 (fr) 1981-05-25
NL7707148A (nl) 1978-01-02
AU2634977A (en) 1979-01-04
DK149204B (da) 1986-03-10
US4077904A (en) 1978-03-07
FI64943B (fi) 1983-10-31
IT1077540B (it) 1985-05-04
FI772009A (fr) 1977-12-30
AU518530B2 (en) 1981-10-08
DE2729122A1 (de) 1978-01-05
DE2729122B2 (de) 1981-03-12
DK287177A (da) 1977-12-30
NO153690C (no) 1986-05-07
NL178325B (nl) 1985-10-01
NL178325C (nl) 1986-03-03
NO774223L (no) 1977-12-30
BE856205A (fr) 1977-12-28
DK149204C (da) 1986-08-04
NO153690B (no) 1986-01-27
NO150399C (no) 1984-10-10
NO772285L (no) 1977-12-30
NO150399B (no) 1984-07-02
CA1091645A (fr) 1980-12-16
GB1583803A (en) 1981-02-04
ES460163A1 (es) 1978-05-16
BR7704206A (pt) 1978-05-02
SE440659B (sv) 1985-08-12
ES460173A1 (es) 1978-05-16
SE7707470L (sv) 1977-12-30
US4100337A (en) 1978-07-11

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