FI90063B - Fluorerade akrylmonomerer, polymerisering av dessa och polymerer haerledda daerav samt anvaendning av dessa som hydrofoba och oleofoba aemnen - Google Patents
Fluorerade akrylmonomerer, polymerisering av dessa och polymerer haerledda daerav samt anvaendning av dessa som hydrofoba och oleofoba aemnen Download PDFInfo
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- FI90063B FI90063B FI864949A FI864949A FI90063B FI 90063 B FI90063 B FI 90063B FI 864949 A FI864949 A FI 864949A FI 864949 A FI864949 A FI 864949A FI 90063 B FI90063 B FI 90063B
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- fluorinated
- monomers
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- QJWFJOSRSZOLKK-UHFFFAOYSA-N prop-2-enamide Chemical compound NC(=O)C=C.NC(=O)C=C QJWFJOSRSZOLKK-UHFFFAOYSA-N 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/02—Monothiocarbamic acids; Derivatives thereof
- C07C333/08—Monothiocarbamic acids; Derivatives thereof having nitrogen atoms of thiocarbamic groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/18—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by doubly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/26—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
- C07C271/28—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
- C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
Claims (9)
1. Fluorerade akrylmonomerer, kännetecknade av att de sva-rar mot den allmänna formeln: CH. p JC I f/^nVnH-C-0-A-0C-C=CHo (II) I O I II II 2 O O NH-C-Q-W-R„ II O i vilken Rp representerar en perfluoralkylradikal med rak eller gre-nad kedja innehällande frän 2 tili 20 kolatomer, R representerar en väteatom eller företrädesvis en metylra-dikal, A representerar en tvävärd kedja med frän 2 tili 9 kolatomer, vilken kan innefatta en eller flera syreatomer, 31 9006.5 Q representerar en syre- eller svavelatom, eller gruppen -NR'-, där R' betecknar en väteatom eller alkylradikal inne-hällande 1-4 kolatomer, och W representerar en tvävärd ked, som är ansluten till Q via en kolatom och till gruppen Rp via en alkylenbro antingen direkt eller via en sulfonamido-, karbonamido-, eter-, tio-eter-, sulfonyl- eller karboxylestergrupp.
2. Monomerer enligt patentkravet 1, kännetecknade av att perfluoralkylradikalen RF innehäller frän 4 till 16 kolatomer, R är en metylradikal, A är en -CH2CH2-bro, och -Q-W- är en -0-CH2CH2-, -S-CH2CH2- eller -0-CH2CH2N(R')S02CH2CH2-kedja, varvid R' representerar en väteatom eller en metylradikal.
3. Förfarande för framställning av monomerer enligt patentkravet 1, kännetecknat av att man i ett första steg bringar 2,4 -toluendiisocyanat att reagera med en i huvudsak ekvimolär mängd av en polyfluorerad förening med formeln: Rf - W - Q - H (III) tili bildning av en fluorerad isocyanat-uretan med formeln: CH3 J'q^N-C-O (IV) nh-c-q-w-rf o vilken man därefter omsätter med en i huvudsak ekvimolär mängd av en akrylester med formeln: R HO - A - O - C - C = CH, (V) II o 32 9 0 063 varvid symbolerna A, R, Rp, Q och W har samma betydelser som i patentkravet 1.
4. Förfarande enligt patentkravet 3, kännetecknat av att man arbetar under inert atmosfär vid en temperatur frän av 30 till 90°C och i ett inert organiskt lösningsmedel.
5. Förfarande enligt patentkravet 3 eller 4, kännetecknat av att den polyfluorerade föreningen svarar mot en av föl-jande formler: Rp - CH2-CH2-OH rf - ch2-ch2-so2-n(r')-ch2ch2oh RF " CH2*CH2'SH i vilka Rp innehäller frdn 4 till 16 kolatomer och R' är en väteatom eller en metylradikal.
6. Förfarande enligt nägot av patentkraven 3-5, kännetecknat av att estern enligt formeln (V) är 2-hydroxietylmetak-rylat.
7. Polymerer innehällande frän 10 tili 100 vikt-% enheter med den allmänna formeln: CH3 r JC I f^YNH-C-0-A-0C-C-CHo— (VIII) I OI il im 2 o o NH-C-Q-W-R- II O erhällna genom homopolymerisation av monomererna enligt patentkravet 1, genom sampolymerisation av nämnda monomerer med andra eventuellt fluorerade monomerer eller genom ymp-ning av en fluorerad isocyanat-uretan med formeln: 33 90 063 ch3 |^qJ-N=C=0 (IV) NH-C-Q-W-Rp II F 0 pä en akrylesterhomopolymer med formeln: R HO - A -OC - C = CH, (V) II 2 0 eller en sampolymer av en sädan ester med andra eventuellt fluorerade monomerer, varvid symbolen Rp, R, A, Q och W har samma betydelser som i patentkravet 1.
8. Sampolymerer enligt patentkravet 7, k&nnetecknade av att sammonomeren eller sammonomererna är valda bland alkyl-akrylater eller -metakrylater med formeln: R Rp - W - OC - C = CH~ F II 2 o och blandningar av dessa, varvid symbolerna Rp och R har samma betydelser som i patentkravet 1, W representerar en tvävärd kedja vald bland dem med formler-na: -(CH2)p- -(CH2)p-S02N-(CH2)q- R' och varvid symbolen R' betecknar detsamma som ovan och p samt q betecknar ett heltal 1-20.
9. Användning av polymererna enligt patentkravet 7 eller 8 för att göra olika substrat, särskilt hudar, oleofoba och hydrofoba.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8517882 | 1985-12-03 | ||
| FR8517882A FR2590895B1 (fr) | 1985-12-03 | 1985-12-03 | Monomeres acryliques fluores, polymeres en derivant et leur application comme agents hydrophobes et oleophobes |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI864949A0 FI864949A0 (fi) | 1986-12-03 |
| FI864949A FI864949A (fi) | 1987-06-04 |
| FI90063B true FI90063B (fi) | 1993-09-15 |
| FI90063C FI90063C (sv) | 1993-12-27 |
Family
ID=9325392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI864949A FI90063C (sv) | 1985-12-03 | 1986-12-03 | Fluorerade akrylmonomerer, polymerisering av dessa och polymerer härle dda därav samt användning av dessa som hydrofoba och oleofoba ämnen |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4920190A (sv) |
| EP (1) | EP0225826B1 (sv) |
| JP (2) | JPS62132850A (sv) |
| KR (1) | KR900004647B1 (sv) |
| CN (1) | CN1010309B (sv) |
| AT (1) | ATE53990T1 (sv) |
| AU (1) | AU596131B2 (sv) |
| CA (1) | CA1260492A (sv) |
| DE (1) | DE3672129D1 (sv) |
| DK (1) | DK578886A (sv) |
| ES (1) | ES2004866A6 (sv) |
| FI (1) | FI90063C (sv) |
| FR (1) | FR2590895B1 (sv) |
| GR (1) | GR862835B (sv) |
| NO (1) | NO167396C (sv) |
| ZA (1) | ZA869088B (sv) |
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| US4900615A (en) * | 1986-03-11 | 1990-02-13 | Union Oil Company Of California | Textile materials and compositions for use therein |
| DE3710279A1 (de) * | 1987-03-28 | 1988-10-06 | Hoechst Ag | Polymerisierbare verbindungen und diese enthaltendes durch strahlung polymerisierbares gemisch |
| US5310828A (en) * | 1989-04-20 | 1994-05-10 | Peach State Labs, Inc. | Superior stain resistant compositions |
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| DE4006097A1 (de) * | 1990-02-27 | 1991-08-29 | Hoechst Ag | Ethylenisch ungesaettigte, fluorhaltige urethanderivate und verfahren zu ihrer herstellung |
| DE4113634A1 (de) * | 1991-04-26 | 1992-10-29 | Minnesota Mining & Mfg | Fluoracryl-polymere, verfahren zu ihrer herstellung und ihre anwendung |
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| US20060216524A1 (en) * | 2005-03-23 | 2006-09-28 | 3M Innovative Properties Company | Perfluoropolyether urethane additives having (meth)acryl groups and hard coats |
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| CN101671279B (zh) * | 2009-09-30 | 2012-12-12 | 浙江工业大学 | 一种含有六氟丙烯齐聚体的聚合单体及其合成方法和应用 |
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| GB0919014D0 (en) | 2009-10-30 | 2009-12-16 | 3M Innovative Properties Co | Soll and stain resistant coating composition for finished leather substrates |
| CN102597025B (zh) | 2009-11-02 | 2014-08-06 | 旭硝子株式会社 | 含氟化合物、含氟聚合物及含氟共聚物 |
| KR100988201B1 (ko) * | 2010-07-15 | 2010-10-18 | 케이엘건설 주식회사 | 불소 변성 폴리우레탄 도막방수재 및 그 제조 방법, 불소 변성 폴리우레탄 도막방수재를 이용한 방수 시공 방법 |
| US9221939B2 (en) * | 2013-06-14 | 2015-12-29 | Benq Materials Corporation | Fluoro-containing ether monomer for fabricating contact lenses, contact lenses materials and contact lenses obtained therefrom |
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| CN105542608A (zh) * | 2015-11-25 | 2016-05-04 | 中国科学院兰州化学物理研究所 | 一种含氟烷基改性的丙烯酸酯低表面能减阻防污涂料及其制备方法 |
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| GB1231946A (sv) * | 1969-03-20 | 1971-05-12 | ||
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-
1985
- 1985-12-03 FR FR8517882A patent/FR2590895B1/fr not_active Expired
-
1986
- 1986-11-06 NO NO864430A patent/NO167396C/no unknown
- 1986-11-21 AT AT86402600T patent/ATE53990T1/de not_active IP Right Cessation
- 1986-11-21 EP EP86402600A patent/EP0225826B1/fr not_active Expired - Lifetime
- 1986-11-21 DE DE8686402600T patent/DE3672129D1/de not_active Expired - Fee Related
- 1986-11-29 CN CN86108160A patent/CN1010309B/zh not_active Expired
- 1986-12-01 CA CA000524223A patent/CA1260492A/fr not_active Expired
- 1986-12-02 ES ES8603251A patent/ES2004866A6/es not_active Expired
- 1986-12-02 DK DK578886A patent/DK578886A/da not_active Application Discontinuation
- 1986-12-02 ZA ZA869088A patent/ZA869088B/xx unknown
- 1986-12-02 GR GR862835A patent/GR862835B/el unknown
- 1986-12-02 KR KR1019860010287A patent/KR900004647B1/ko not_active IP Right Cessation
- 1986-12-02 AU AU65900/86A patent/AU596131B2/en not_active Ceased
- 1986-12-03 JP JP61288618A patent/JPS62132850A/ja active Granted
- 1986-12-03 FI FI864949A patent/FI90063C/sv not_active IP Right Cessation
-
1988
- 1988-06-21 US US07/209,388 patent/US4920190A/en not_active Expired - Fee Related
-
1990
- 1990-05-21 JP JP2131126A patent/JPH0328207A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2590895A1 (fr) | 1987-06-05 |
| ATE53990T1 (de) | 1990-07-15 |
| JPH0328207A (ja) | 1991-02-06 |
| NO167396C (no) | 1991-10-30 |
| KR870005980A (ko) | 1987-07-08 |
| FI864949A0 (fi) | 1986-12-03 |
| JPH034542B2 (sv) | 1991-01-23 |
| DE3672129D1 (de) | 1990-07-26 |
| CN86108160A (zh) | 1987-06-17 |
| DK578886A (da) | 1987-06-04 |
| GR862835B (en) | 1987-03-30 |
| FI864949A (fi) | 1987-06-04 |
| AU6590086A (en) | 1987-06-11 |
| ES2004866A6 (es) | 1989-02-16 |
| EP0225826A3 (en) | 1988-06-01 |
| EP0225826A2 (fr) | 1987-06-16 |
| ZA869088B (en) | 1987-08-26 |
| NO864430D0 (no) | 1986-11-06 |
| JPS62132850A (ja) | 1987-06-16 |
| NO864430L (no) | 1987-06-04 |
| FR2590895B1 (fr) | 1988-01-15 |
| DK578886D0 (da) | 1986-12-02 |
| CN1010309B (zh) | 1990-11-07 |
| US4920190A (en) | 1990-04-24 |
| CA1260492A (fr) | 1989-09-26 |
| NO167396B (no) | 1991-07-22 |
| KR900004647B1 (ko) | 1990-07-02 |
| FI90063C (sv) | 1993-12-27 |
| EP0225826B1 (fr) | 1990-06-20 |
| AU596131B2 (en) | 1990-04-26 |
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