FI66621C - N n'-metylenbis-(0,0-diaryl-n-fosfonmetylglycinnitriler) derasframstaellning herbicidiska kompositioner innehaollande d emch herbicidisk metod - Google Patents

N n'-metylenbis-(0,0-diaryl-n-fosfonmetylglycinnitriler) derasframstaellning herbicidiska kompositioner innehaollande d emch herbicidisk metod Download PDF

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Publication number
FI66621C
FI66621C FI773496A FI773496A FI66621C FI 66621 C FI66621 C FI 66621C FI 773496 A FI773496 A FI 773496A FI 773496 A FI773496 A FI 773496A FI 66621 C FI66621 C FI 66621C
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FI
Finland
Prior art keywords
compound
formula
phenyl
halogen
plant
Prior art date
Application number
FI773496A
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English (en)
Finnish (fi)
Other versions
FI773496A (fi
FI66621B (fi
Inventor
Gerard Anthony Dutra
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/750,327 external-priority patent/US4067719A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of FI773496A publication Critical patent/FI773496A/fi
Application granted granted Critical
Publication of FI66621B publication Critical patent/FI66621B/fi
Publication of FI66621C publication Critical patent/FI66621C/fi

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • C07F9/4071Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4084Esters with hydroxyaryl compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/22Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/24Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing heterocyclic radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • C07F9/4003Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006Esters of acyclic acids which can have further substituents on alkyl

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Molecular Biology (AREA)
  • Agronomy & Crop Science (AREA)
  • Biochemistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Claims (10)

1. Som herbicid användbar förening raed formeln: 0 II (RO) 2-P-CH2-N--CH2 nc-ch2 (i) J2 där R är fenyl, som kan vara substituerad med 1-2 halogen-, lägrealk-yl-, lägrealkoxi- och/eller lägrealkyltiosubstituenter.
2. Förening enligt patentkravet 1, kännetecknad därav, att R är fenyl, toluyl, metoxifenyl, xylyl, klorfenyl, metyl-tiofenyl eller klortoluyl.
3. Herbicidisk komposition, kännetecknad därav, att den innehäller en herbicidiskt effektiv mängd av en förening med formeln: O II (RO) 2-P-CH2-N---CH2 nc-ch2 (i) 2 där R är fenyl, som kan vara substituerad med 1-2 halogen-, lägre alkyl- , lägre alkoxi- och/eller lägre alkyltiosubstituenter, och att inert utspädningsmedel.
4. Herbicidisk komposition enligt patentkravet 3, kännetecknad därav, att den innehäller en herbicidiskt effektiv mängd av en förening med formeln (I), där R är fenyl, toluyl, metoxifenyl, xylyl, klorfenyl, metyltiofenyl eller klortoluyl, och ett inert utspädningsmedel.
5. Herbicidisk metod, kännetecknad därav, att en växt bringas i kontakt med en förening med formeln: 20 6 6 6 21 O II (RO) _-P-CH0-N--CH„ £, £ | ^ NC—CH~ L 2 J2 m där R är fenyl, som kan vara substituerad med 1-2 halogen-, lägrealk-yl-» lägrealkoxi- och/eller lägrealkyltiosubstituenter, genom att ut-sprida föreningen i en mängd av ca 0 ,25 - ca 25 kg/ha pä växtens till-växtställe.
6. Herbicidisk metod enligt patentkravet 5, känneteck-n a d därav, att en växt bringas i kontakt med en förening enligt formeln (I), där R är fenyl, toluyl, metoxifenyl, xylyl, klorfenyl, metyltiofenyl eller klortoluyl genom att utsprida föreningen i en mängd av ca 0,25 - 25 kg/ha pä växtens tillväxtställe.
7. Förfarande för framställning av en förening med formeln: O ~~ II (RO) _-P-CH0-N--CH0 £ £ | / NC-CH2 (i) O L· där R är fenyl, som kan vara substituerad med 1-2 halogen-, lägrealk-yl-, lägrealkoxi- och/eller lägrealkyltiosubstituenter, känne-t e c k n a t därav, att en blandning bildas av en hindrad fenyl-azometin och en förening med formeln: O II (ro)2-p-ch2-nh-ch2-cn där R har den ovan definierade betydelsen, och upphettas under vakuum tills utvecklingen av en hindrad anilin upphör.
8. Förfarande enligt patentkravet 7, kännetecknat därav,att den hindrade fenylazometinen har formeln:
FI773496A 1976-12-13 1977-11-18 N n'-metylenbis-(0,0-diaryl-n-fosfonmetylglycinnitriler) derasframstaellning herbicidiska kompositioner innehaollande d emch herbicidisk metod FI66621C (fi)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US75032776 1976-12-13
US05/750,327 US4067719A (en) 1976-12-13 1976-12-13 O-Aryl N-phosphonomethylglycinonitriles and the herbicidal use thereof
US05/807,954 US4089671A (en) 1976-12-13 1977-06-20 N,N'-methylenebis-[O,O-diaryl N-phosphonomethylglycinonitriles]
US80795477 1977-06-20

Publications (3)

Publication Number Publication Date
FI773496A FI773496A (fi) 1978-06-14
FI66621B FI66621B (fi) 1984-07-31
FI66621C true FI66621C (fi) 1984-11-12

Family

ID=27115260

Family Applications (1)

Application Number Title Priority Date Filing Date
FI773496A FI66621C (fi) 1976-12-13 1977-11-18 N n'-metylenbis-(0,0-diaryl-n-fosfonmetylglycinnitriler) derasframstaellning herbicidiska kompositioner innehaollande d emch herbicidisk metod

Country Status (30)

Country Link
JP (1) JPS601319B2 (sv)
AR (1) AR227502A1 (sv)
AT (1) AT358318B (sv)
AU (1) AU509848B2 (sv)
BG (1) BG28424A3 (sv)
BR (1) BR7707672A (sv)
CA (1) CA1085415A (sv)
CH (1) CH638533A5 (sv)
CS (1) CS199209B2 (sv)
DD (1) DD136095A5 (sv)
DE (1) DE2751630A1 (sv)
DK (1) DK144334C (sv)
EG (1) EG12897A (sv)
ES (1) ES464221A1 (sv)
FI (1) FI66621C (sv)
FR (1) FR2373555A1 (sv)
GB (1) GB1561317A (sv)
HU (1) HU177354B (sv)
IE (1) IE46094B1 (sv)
IN (1) IN146348B (sv)
IT (1) IT1114670B (sv)
MX (1) MX4713E (sv)
MY (1) MY8100165A (sv)
NL (1) NL7712654A (sv)
NO (1) NO151706C (sv)
NZ (1) NZ185721A (sv)
PH (1) PH13235A (sv)
PL (1) PL107838B1 (sv)
PT (1) PT67296B (sv)
SE (2) SE440359B (sv)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PH16509A (en) * 1971-03-10 1983-11-08 Monsanto Co N-phosphonomethylglycine phytotoxicant composition

Also Published As

Publication number Publication date
DK511877A (da) 1978-06-14
FI773496A (fi) 1978-06-14
AR227502A1 (es) 1982-11-15
NO151706B (no) 1985-02-11
NO151706C (no) 1985-05-22
BR7707672A (pt) 1978-06-13
IE46094B1 (en) 1983-02-23
CS199209B2 (en) 1980-07-31
BG28424A3 (en) 1980-04-15
DK144334C (da) 1982-07-19
CH638533A5 (en) 1983-09-30
CA1085415A (en) 1980-09-09
ES464221A1 (es) 1978-12-01
SE7713048L (sv) 1978-06-14
PL107838B1 (pl) 1980-03-31
NL7712654A (nl) 1978-06-15
JPS5373544A (en) 1978-06-30
FR2373555B1 (sv) 1981-12-04
IN146348B (sv) 1979-05-05
MX4713E (es) 1982-08-11
AU509848B2 (en) 1980-05-29
DD136095A5 (de) 1979-06-20
AT358318B (de) 1980-09-10
PT67296B (en) 1979-04-20
FI66621B (fi) 1984-07-31
AU3075377A (en) 1979-05-24
DE2751630A1 (de) 1978-06-15
SE440359B (sv) 1985-07-29
IE46094L (en) 1978-06-13
PL202251A1 (pl) 1978-10-23
SE8301673D0 (sv) 1983-03-25
HU177354B (en) 1981-09-28
SE8301673L (sv) 1983-03-25
NO773960L (no) 1978-06-14
EG12897A (en) 1980-07-31
NZ185721A (en) 1980-10-08
PH13235A (en) 1980-02-14
PT67296A (en) 1977-12-01
JPS601319B2 (ja) 1985-01-14
IT1114670B (it) 1986-01-27
MY8100165A (en) 1981-12-31
DK144334B (da) 1982-02-22
ATA825077A (de) 1980-01-15
GB1561317A (en) 1980-02-20
FR2373555A1 (fr) 1978-07-07

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Owner name: MONSANTO COMPANY