FI112911B - Förbättrat viskosbaserat förfarande för framställning av pigmenterade cellulosa skinn - Google Patents
Förbättrat viskosbaserat förfarande för framställning av pigmenterade cellulosa skinn Download PDFInfo
- Publication number
- FI112911B FI112911B FI992311A FI19992311A FI112911B FI 112911 B FI112911 B FI 112911B FI 992311 A FI992311 A FI 992311A FI 19992311 A FI19992311 A FI 19992311A FI 112911 B FI112911 B FI 112911B
- Authority
- FI
- Finland
- Prior art keywords
- cellulose
- weight
- pigments
- bath
- pigment
- Prior art date
Links
- 229920002678 cellulose Polymers 0.000 title claims description 49
- 239000001913 cellulose Substances 0.000 title claims description 49
- 238000000034 method Methods 0.000 title claims description 32
- 230000008569 process Effects 0.000 title claims description 22
- 229920000297 Rayon Polymers 0.000 title claims description 15
- 150000003839 salts Chemical class 0.000 title description 13
- 238000002360 preparation method Methods 0.000 title description 11
- 239000000049 pigment Substances 0.000 claims description 27
- 241000158728 Meliaceae Species 0.000 claims description 10
- 235000013305 food Nutrition 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 6
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 5
- 238000006386 neutralization reaction Methods 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 claims description 3
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 claims description 3
- -1 perylene tartaric acid Chemical compound 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 239000010985 leather Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 230000019612 pigmentation Effects 0.000 claims 1
- 210000000936 intestine Anatomy 0.000 description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- 239000000975 dye Substances 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 239000003086 colorant Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000968 intestinal effect Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 235000013580 sausages Nutrition 0.000 description 6
- 210000001035 gastrointestinal tract Anatomy 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 3
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000012991 xanthate Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- GJEAMHAFPYZYDE-UHFFFAOYSA-N [C].[S] Chemical compound [C].[S] GJEAMHAFPYZYDE-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- FVDOBFPYBSDRKH-UHFFFAOYSA-N perylene-3,4,9,10-tetracarboxylic acid Chemical compound C=12C3=CC=C(C(O)=O)C2=C(C(O)=O)C=CC=1C1=CC=C(C(O)=O)C2=C1C3=CC=C2C(=O)O FVDOBFPYBSDRKH-UHFFFAOYSA-N 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000004627 regenerated cellulose Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000006194 liquid suspension Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002685 pulmonary effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 210000005239 tubule Anatomy 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A22—BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
- A22C—PROCESSING MEAT, POULTRY, OR FISH
- A22C13/00—Sausage casings
- A22C13/0013—Chemical composition of synthetic sausage casings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1324—Flexible food casing [e.g., sausage type, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
- Y10T428/1345—Single layer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1348—Cellular material derived from plant or animal source [e.g., wood, cotton, wool, leather, etc.]
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Processing Of Meat And Fish (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Claims (5)
1. Förbättrat viskosbaserat förfarande för tillverkning av pigmenterade cellulosaskinn som när det är stoppat med livsmedelsprodukter fär utseendet av produkten som blivit naturligt rökt, burgundyfärgat, mahognyfärgat eller vilken som heist nyans av röd farg, kännetecknat därav, att pigment av perylentetrakarboxylsyra blandat med ett eller flera tilläggspigment bringas före skinn extrusionmynning att ingä i viskos som extruderas tili skinn, som koaguleras, regenereras, tvättas och plasticeras, och ingen reduction med en hydrosulfitbad, oxidering med peroxidbad och neutralisering med syrebaden behövs; och skinnet, när det är stoppat med livsmedelsprodukter har utseendet och smakfullheten av de skinn som grundar sig pä Indanthren-pigmenteringssystemet.
2. Förfarande enligt patentkravet 1, kännetecknat därav, att tilläggspigmentet väljs frän gruppen som bestär av β-ftalocyanin-, diazo- och monoazopigment.
3. Förfarande enligt patentkrav 1 eller 2, kännetecknat därav, att mängden av pery- ; lentetrakarboxylsyra är 0,4-4 vikt-%, fördelaktigt 1-2 vikt-% och mängden av β- ftalocyanin är 0,01-3 vikt-% och den totala mängden av diazo- och/eller monoazopigment är 0.03-2 vikt-%, beräknat frän den torra vikten av skinnet.
4. Förfarande enligt vilket som heist av patentkraven 1-3, kännetecknat därav, att i skinnet är ett fiberskmn.
5. Förfarande enligt vilket som heist av patentkraven 1-4, kännetecknat därav, att livsmedelsprodukten är balkanskorven.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI992311A FI112911B (sv) | 1999-10-26 | 1999-10-26 | Förbättrat viskosbaserat förfarande för framställning av pigmenterade cellulosa skinn |
| EP00969621A EP1223812A1 (en) | 1999-10-26 | 2000-10-25 | Cellulose casing for food products |
| JP2001532603A JP2003517298A (ja) | 1999-10-26 | 2000-10-25 | 食品用セルロース系ケーシング |
| AU79292/00A AU7929200A (en) | 1999-10-26 | 2000-10-25 | Cellulose casing for food products |
| RU2002113665/13A RU2267273C2 (ru) | 1999-10-26 | 2000-10-25 | Целлюлозная оболочка для пищевых продуктов |
| US10/111,677 US6756093B1 (en) | 1999-10-26 | 2000-10-25 | Cellulose casing for food products |
| PCT/FI2000/000922 WO2001030165A1 (en) | 1999-10-26 | 2000-10-25 | Cellulose casing for food products |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI992311A FI112911B (sv) | 1999-10-26 | 1999-10-26 | Förbättrat viskosbaserat förfarande för framställning av pigmenterade cellulosa skinn |
| FI992311 | 1999-10-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FI19992311A FI19992311A (sv) | 2001-04-27 |
| FI112911B true FI112911B (sv) | 2004-02-13 |
Family
ID=8555504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI992311A FI112911B (sv) | 1999-10-26 | 1999-10-26 | Förbättrat viskosbaserat förfarande för framställning av pigmenterade cellulosa skinn |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6756093B1 (sv) |
| EP (1) | EP1223812A1 (sv) |
| JP (1) | JP2003517298A (sv) |
| AU (1) | AU7929200A (sv) |
| FI (1) | FI112911B (sv) |
| RU (1) | RU2267273C2 (sv) |
| WO (1) | WO2001030165A1 (sv) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10124581A1 (de) * | 2001-05-21 | 2002-11-28 | Wolff Walsrode Ag | Verfahren zur Herstellung von rauchimprägnierten Schlauchhüllen |
| CZ2020219A3 (cs) * | 2020-04-16 | 2021-11-10 | Univerzita Pardubice | Použití solí kyseliny perylenové jako antikorozních látek |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1227609B (de) * | 1963-05-02 | 1966-10-27 | Hoechst Ag | Verwendung eines Kondensationsproduktes als Dispergiermittel in Pigmentdispersionen fuer das Faerben von Viskosespinnmassen |
| US4336828A (en) | 1978-10-25 | 1982-06-29 | Wolff Walsrode Ag | Fibre-reinforced metallic luster pigmented tubular casing and a process for its production |
| DE8436989U1 (de) | 1984-12-18 | 1985-09-12 | Hoechst Ag, 6230 Frankfurt | Künstliche Wursthülle für Würste vom Rohwursttyp |
| DE3543633A1 (de) | 1984-12-18 | 1986-06-26 | Hoechst Ag, 6230 Frankfurt | Kuenstliche wursthuelle fuer wuerste vom rohwursttyp |
| DE3801344A1 (de) * | 1988-01-19 | 1989-07-27 | Hoechst Ag | Verpackungsfolie, insbesondere wursthuelle, auf basis von polyamid |
| USH1592H (en) * | 1992-01-17 | 1996-09-03 | Viskase Corporation | Cellulosic food casing |
| DE19814924A1 (de) * | 1998-04-03 | 1999-10-07 | Basf Ag | Schlauchfolien |
| DE19818891A1 (de) * | 1998-04-28 | 1999-11-04 | Wolff Walsrode Ag | Verfahren zur Herstellung von transparent eingefärbten Cellulosehüllen |
-
1999
- 1999-10-26 FI FI992311A patent/FI112911B/sv active
-
2000
- 2000-10-25 RU RU2002113665/13A patent/RU2267273C2/ru not_active IP Right Cessation
- 2000-10-25 US US10/111,677 patent/US6756093B1/en not_active Expired - Fee Related
- 2000-10-25 WO PCT/FI2000/000922 patent/WO2001030165A1/en not_active Application Discontinuation
- 2000-10-25 EP EP00969621A patent/EP1223812A1/en not_active Withdrawn
- 2000-10-25 AU AU79292/00A patent/AU7929200A/en not_active Abandoned
- 2000-10-25 JP JP2001532603A patent/JP2003517298A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003517298A (ja) | 2003-05-27 |
| US6756093B1 (en) | 2004-06-29 |
| EP1223812A1 (en) | 2002-07-24 |
| AU7929200A (en) | 2001-05-08 |
| WO2001030165A1 (en) | 2001-05-03 |
| RU2267273C2 (ru) | 2006-01-10 |
| FI19992311A (sv) | 2001-04-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PC | Transfer of assignment of patent |
Owner name: VISKOTEEPAK BELGIUM NV Free format text: VISKOTEEPAK BELGIUM NV |