ES2972060T3 - Material compuesto de azufre-carbono, método de preparación del mismo, electrodo positivo para batería secundaria de litio y batería secundaria de litio que comprende el mismo - Google Patents

Material compuesto de azufre-carbono, método de preparación del mismo, electrodo positivo para batería secundaria de litio y batería secundaria de litio que comprende el mismo Download PDF

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Publication number
ES2972060T3
ES2972060T3 ES19863294T ES19863294T ES2972060T3 ES 2972060 T3 ES2972060 T3 ES 2972060T3 ES 19863294 T ES19863294 T ES 19863294T ES 19863294 T ES19863294 T ES 19863294T ES 2972060 T3 ES2972060 T3 ES 2972060T3
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Prior art keywords
sulfur
carbon
composite material
porous carbon
carbon composite
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ES19863294T
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English (en)
Spanish (es)
Inventor
Minsu Kim
Eunkyung Cho
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LG Energy Solution Ltd
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LG Energy Solution Ltd
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Priority claimed from PCT/KR2019/011540 external-priority patent/WO2020060084A1/ko
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Publication of ES2972060T3 publication Critical patent/ES2972060T3/es
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/0243Other after-treatment of sulfur
    • C01B17/0248Other after-treatment of sulfur of particulate sulfur
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • C01B32/174Derivatisation; Solubilisation; Dispersion in solvents
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1393Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581Chalcogenides or intercalation compounds thereof
    • H01M4/5815Sulfides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/021Physical characteristics, e.g. porosity, surface area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Nanotechnology (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Carbon And Carbon Compounds (AREA)
ES19863294T 2018-09-20 2019-09-06 Material compuesto de azufre-carbono, método de preparación del mismo, electrodo positivo para batería secundaria de litio y batería secundaria de litio que comprende el mismo Active ES2972060T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR20180112639 2018-09-20
KR1020190109637A KR102854271B1 (ko) 2018-09-20 2019-09-04 황-탄소 복합체, 이의 제조방법, 이를 포함하는 리튬 이차전지용 양극 및 리튬 이차전지
PCT/KR2019/011540 WO2020060084A1 (ko) 2018-09-20 2019-09-06 황-탄소 복합체, 이의 제조방법, 이를 포함하는 리튬 이차전지용 양극 및 리튬 이차전지

Publications (1)

Publication Number Publication Date
ES2972060T3 true ES2972060T3 (es) 2024-06-11

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ES19863294T Active ES2972060T3 (es) 2018-09-20 2019-09-06 Material compuesto de azufre-carbono, método de preparación del mismo, electrodo positivo para batería secundaria de litio y batería secundaria de litio que comprende el mismo

Country Status (7)

Country Link
US (2) US12191477B2 (enExample)
EP (1) EP3767715B1 (enExample)
JP (1) JP7167299B2 (enExample)
KR (2) KR102854271B1 (enExample)
CN (1) CN112088453B (enExample)
ES (1) ES2972060T3 (enExample)
HU (1) HUE064994T2 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102848102B1 (ko) * 2021-01-08 2025-08-19 주식회사 엘지에너지솔루션 황-탄소 복합체, 이의 제조방법, 및 이를 포함하는 리튬-황 전지
CN119111002A (zh) * 2022-04-27 2024-12-10 日亚化学工业株式会社 锂硫电池用碳材料及其制造方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
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CN102530926A (zh) * 2010-12-10 2012-07-04 东丽纤维研究所(中国)有限公司 一种基于连二亚硫酸盐制备石墨烯的方法
CN104094457B (zh) 2011-09-30 2017-06-23 加州大学校务委员会 在高性能锂/硫电池中作为硫固定剂的氧化石墨烯
DE102012209635A1 (de) * 2012-06-08 2013-12-12 Robert Bosch Gmbh Verfahren zum Herstellen eines Polyacrylnitril-Schwefel-Kompositwerkstoffs
JP6011787B2 (ja) 2012-08-09 2016-10-19 ソニー株式会社 電極材料及びその製造方法、並びに、リチウム−硫黄二次電池
KR20140079036A (ko) 2012-12-18 2014-06-26 삼성전기주식회사 절연층 조성물, 및 이를 이용한 절연층을 포함하는 기판, 및 상기 기판의 제조방법
KR101686640B1 (ko) 2015-05-14 2016-12-14 부산대학교 산학협력단 고분자 코팅층을 갖는 질소도핑된 그래핀-유황 복합체의 제조방법, 이에 의하여 제조된 복합체 및 이를 이용한 리튬-황 이차전지
KR101775782B1 (ko) 2015-08-31 2017-09-11 국방과학연구소 단일벽 탄소나노튜브의 작용기 제거 방법
EP3377444A4 (en) * 2015-11-13 2019-04-03 Robert Bosch GmbH SULFUR-CARBON COMPOUND WITH HIGHLY GRAPHITE CARBON MATERIAL FOR LITHIUM SULFUR BATTERIES AND METHOD FOR THE PRODUCTION THEREOF
US10381646B2 (en) 2015-12-24 2019-08-13 Semiconductor Energy Laboratory Co., Ltd. Secondary battery, graphene oxide, and manufacturing method thereof
KR101951275B1 (ko) 2016-05-30 2019-02-22 한국화학연구원 카본블랙의 표면처리 방법
KR20180017796A (ko) 2016-08-11 2018-02-21 주식회사 엘지화학 황-탄소 복합체, 이의 제조방법 및 이를 포함하는 리튬-황 전지
CN106602063B (zh) 2016-12-30 2020-08-11 长兴德烯科技有限公司 一种石墨烯花的制备方法及其在锂硫电池中的应用
CN107611395B (zh) 2017-09-08 2020-10-27 中国科学院山西煤炭化学研究所 小尺寸石墨烯锂硫电池正极材料、其制备的锂硫电池及制备方法
CN107946553B (zh) 2017-10-25 2021-03-26 温州大学 高石墨化三维碳纳米管石墨烯复合材料及其制备与应用
US11658293B2 (en) * 2017-11-16 2023-05-23 Lg Energy Solution, Ltd. Sulfur-carbon composite, preparation method therefor, and lithium secondary battery comprising same
KR102229453B1 (ko) * 2017-11-24 2021-03-17 주식회사 엘지화학 황-탄소 복합체, 그의 제조방법 및 이를 포함하는 리튬 이차전지

Also Published As

Publication number Publication date
EP3767715A4 (en) 2021-06-30
JP2021517110A (ja) 2021-07-15
KR102854271B1 (ko) 2025-09-03
US12191477B2 (en) 2025-01-07
US20250046787A1 (en) 2025-02-06
KR20200033736A (ko) 2020-03-30
EP3767715A1 (en) 2021-01-20
JP7167299B2 (ja) 2022-11-08
KR20250088696A (ko) 2025-06-17
CN112088453B (zh) 2023-11-24
US20210036306A1 (en) 2021-02-04
CN112088453A (zh) 2020-12-15
EP3767715B1 (en) 2023-11-01
HUE064994T2 (hu) 2024-04-28

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