ES2652520T3 - Composiciones ignífugas de PVC - Google Patents
Composiciones ignífugas de PVC Download PDFInfo
- Publication number
- ES2652520T3 ES2652520T3 ES12745901.4T ES12745901T ES2652520T3 ES 2652520 T3 ES2652520 T3 ES 2652520T3 ES 12745901 T ES12745901 T ES 12745901T ES 2652520 T3 ES2652520 T3 ES 2652520T3
- Authority
- ES
- Spain
- Prior art keywords
- pvc
- plasticizer
- flame retardant
- resin composition
- hypophosphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000203 mixture Substances 0.000 title claims abstract description 63
- 239000003063 flame retardant Substances 0.000 title claims description 72
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 50
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 115
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 31
- 239000003381 stabilizer Substances 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 21
- 239000000654 additive Substances 0.000 claims abstract description 11
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 5
- 229910001376 inorganic hypophosphite Inorganic materials 0.000 claims abstract description 5
- 239000000975 dye Substances 0.000 claims abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 110
- 239000004014 plasticizer Substances 0.000 claims description 78
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 58
- -1 diaryl phosphates Chemical class 0.000 claims description 23
- 239000011342 resin composition Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- 235000021317 phosphate Nutrition 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 10
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000004801 Chlorinated PVC Substances 0.000 claims description 7
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 claims description 7
- 229910001377 aluminum hypophosphite Inorganic materials 0.000 claims description 7
- 239000012757 flame retardant agent Substances 0.000 claims description 7
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- 229910001382 calcium hypophosphite Inorganic materials 0.000 claims description 6
- 229940064002 calcium hypophosphite Drugs 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- CNALVHVMBXLLIY-IUCAKERBSA-N tert-butyl n-[(3s,5s)-5-methylpiperidin-3-yl]carbamate Chemical compound C[C@@H]1CNC[C@@H](NC(=O)OC(C)(C)C)C1 CNALVHVMBXLLIY-IUCAKERBSA-N 0.000 claims description 6
- 125000005498 phthalate group Chemical group 0.000 claims description 5
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- BCSGAWBQJHXXSE-UHFFFAOYSA-N bis(11-methyldodecyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC(C)C BCSGAWBQJHXXSE-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- FLFJVPPJGJSHMF-UHFFFAOYSA-L manganese hypophosphite Chemical compound [Mn+2].[O-]P=O.[O-]P=O FLFJVPPJGJSHMF-UHFFFAOYSA-L 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 229910001378 barium hypophosphite Inorganic materials 0.000 claims description 2
- SEQVSYFEKVIYCP-UHFFFAOYSA-L magnesium hypophosphite Chemical compound [Mg+2].[O-]P=O.[O-]P=O SEQVSYFEKVIYCP-UHFFFAOYSA-L 0.000 claims description 2
- 229910001381 magnesium hypophosphite Inorganic materials 0.000 claims description 2
- 239000010690 paraffinic oil Substances 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 2
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims 2
- 239000008029 phthalate plasticizer Substances 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 34
- 229920000642 polymer Polymers 0.000 description 22
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 19
- 239000011575 calcium Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 10
- 229910052801 chlorine Inorganic materials 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 6
- 229910052794 bromium Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 6
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 229910052787 antimony Inorganic materials 0.000 description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- MTJUVXNNYAOALD-UHFFFAOYSA-K phoslite ip-a Chemical compound [Al+3].[O-]P=O.[O-]P=O.[O-]P=O MTJUVXNNYAOALD-UHFFFAOYSA-K 0.000 description 5
- 239000000779 smoke Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 4
- CMCJNODIWQEOAI-UHFFFAOYSA-N bis(2-butoxyethyl)phthalate Chemical compound CCCCOCCOC(=O)C1=CC=CC=C1C(=O)OCCOCCCC CMCJNODIWQEOAI-UHFFFAOYSA-N 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 230000002950 deficient Effects 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000004677 hydrates Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
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- 150000003254 radicals Chemical class 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OYYXZGFIZTYYRB-UHFFFAOYSA-N 2-octyldecanoic acid Chemical compound CCCCCCCCC(C(O)=O)CCCCCCCC OYYXZGFIZTYYRB-UHFFFAOYSA-N 0.000 description 2
- QKUNKVYPGIOQNP-UHFFFAOYSA-N 4,8,11,14,17,21-hexachlorotetracosane Chemical compound CCCC(Cl)CCCC(Cl)CCC(Cl)CCC(Cl)CCC(Cl)CCCC(Cl)CCC QKUNKVYPGIOQNP-UHFFFAOYSA-N 0.000 description 2
- 239000004605 External Lubricant Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920001944 Plastisol Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 150000001860 citric acid derivatives Chemical class 0.000 description 2
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
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- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 1
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- 238000012552 review Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000007847 structural defect Effects 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 238000009492 tablet coating Methods 0.000 description 1
- 239000002700 tablet coating Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IB2012/001392 WO2014013284A1 (en) | 2012-07-17 | 2012-07-17 | Pvc flame retardant compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2652520T3 true ES2652520T3 (es) | 2018-02-02 |
Family
ID=46642582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12745901.4T Active ES2652520T3 (es) | 2012-07-17 | 2012-07-17 | Composiciones ignífugas de PVC |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20150353711A1 (OSRAM) |
| EP (1) | EP2875069B1 (OSRAM) |
| JP (1) | JP2015522691A (OSRAM) |
| KR (1) | KR20150042159A (OSRAM) |
| DK (1) | DK2875069T3 (OSRAM) |
| ES (1) | ES2652520T3 (OSRAM) |
| PL (1) | PL2875069T3 (OSRAM) |
| PT (1) | PT2875069T (OSRAM) |
| WO (1) | WO2014013284A1 (OSRAM) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109323B (zh) * | 2014-07-31 | 2016-06-15 | 东莞市祺龙电业有限公司 | 一种耐迁移环保pvc改性材料及其制备方法 |
| JP6461531B2 (ja) * | 2014-09-19 | 2019-01-30 | リケンテクノス株式会社 | 塩化ビニル系樹脂組成物 |
| WO2016101979A1 (en) | 2014-12-22 | 2016-06-30 | Prysmian S.P.A. | Flame-retardant heavy metal-free coating for an electrical cable |
| KR101845338B1 (ko) * | 2015-02-04 | 2018-04-04 | 한화케미칼 주식회사 | 친환경 가소제 조성물, 및 이를 포함하는 염화비닐 수지 조성물 |
| KR101616675B1 (ko) * | 2015-08-13 | 2016-04-28 | 주식회사 세명산업 | 부분 점착면을 가지며 선박의 비철 및 파이프를 보호하는 충격주의 난연 테이프 |
| MX2018014011A (es) | 2016-05-17 | 2019-02-26 | Gen Cable Technologies Corp | Composiciones retardantes de incendios y separadores de cables formados de las mismas. |
| US11393609B2 (en) | 2017-06-29 | 2022-07-19 | Prysmian S.P.A. | Flame retardant, low smoke, cold resistant electric cable |
| CN107474429A (zh) * | 2017-08-15 | 2017-12-15 | 安徽嘉阳新材料科技有限公司 | 一种耐磨阻燃地板膜及其制备方法 |
| KR102108875B1 (ko) | 2017-08-25 | 2020-05-20 | 애경유화주식회사 | 복합 가소제 조성물, 이의 제조방법 및 이를 이용한 고분자 수지 조성물 |
| CA3075852C (en) * | 2017-09-15 | 2024-02-13 | Geon Performance Solutions, Llc | Flame retardant poly(vinyl chloride) compounds |
| JP2019162831A (ja) * | 2018-03-20 | 2019-09-26 | ダイヤプラスフィルム株式会社 | 透明不燃性シート、該透明不燃性シートを用いた防煙垂壁、防煙スクリーン・カーテン、並びに透明不燃性シートの製造方法 |
| KR102354744B1 (ko) | 2018-03-21 | 2022-01-25 | 애경케미칼주식회사 | 복합 가소제 조성물, 이의 제조방법 및 이를 이용한 고분자 수지 조성물 |
| CN108892800A (zh) * | 2018-05-10 | 2018-11-27 | 安徽华塑股份有限公司 | 一种高抗弯强度pvc型材的生产工艺 |
| CN108929504A (zh) * | 2018-08-17 | 2018-12-04 | 扬州新奇特电缆材料有限公司 | 一种电线电缆聚烯烃护套专用阻燃剂的制备方法 |
| WO2020115522A1 (en) | 2018-12-03 | 2020-06-11 | Italmatch Chemicals S.P.A. | Polyolefins halogen-free flame retardant moulding compositions comprising an inorganic hypophosphorous acid metal salt |
| KR102152066B1 (ko) * | 2019-03-04 | 2020-09-04 | 프로켐 주식회사 | 액상 및 분말을 포함하는 하이브리드 타입 pvc용 복합 안정제 및 이를 포함하는 pvc 수지 조성물 |
| KR102708333B1 (ko) | 2019-04-02 | 2024-09-20 | 이탈마치 케미칼스 에스피에이 | 불연성 하이포포스파이트 금속염 분말 및 난연 성분으로서의 용도 |
| CN110204842A (zh) * | 2019-04-30 | 2019-09-06 | 佛山唯尔塑胶制品有限公司 | 一种pvc转移印刷复合台布及其制造方法 |
| CN110204843B (zh) * | 2019-05-17 | 2021-08-06 | 揭西县三明塑料有限公司 | 一种阻燃pvc材料 |
| CN110885508A (zh) * | 2019-11-22 | 2020-03-17 | 浙江海啊汽车用品有限公司 | 一种环保脚垫材料及其制备方法 |
| KR102473992B1 (ko) * | 2020-12-18 | 2022-12-05 | 프로켐 주식회사 | 액상 및 분말을 포함하는 하이브리드 타입 pvc용 복합 안정제의 제조방법 |
| CN112812459A (zh) * | 2020-12-30 | 2021-05-18 | 江西博硕电子有限公司 | 一种无锑阻燃聚氯乙烯电缆料及其制备方法和应用 |
| CN113278234B (zh) * | 2021-06-15 | 2022-08-12 | 江苏宝源高新电工有限公司 | 一种低烟低卤阻燃pvc电缆料及其制备方法 |
| CN114960204B (zh) * | 2022-06-13 | 2024-02-23 | 温多利遮阳材料（德州）股份有限公司 | Pvc复合材料，含其产品及其原料、制备方法和应用 |
| KR20250099752A (ko) * | 2022-11-14 | 2025-07-02 | 네오 케미컬스 앤드 옥사이드스, 엘엘씨 | 공침된 희토류 첨가제를 함유하는 pvc 조성물 |
| CN119684807B (zh) * | 2025-02-25 | 2025-05-06 | 潍坊迪蒙化工有限公司 | 一种增塑剂及其制备方法 |
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| DE2965759D1 (en) | 1978-11-15 | 1983-07-28 | Ciba Geigy Ag | Flame-retardant plastified pvc-composition |
| FR2448544A1 (fr) | 1979-02-12 | 1980-09-05 | Synthelabo | Derives de thiazole et leur application en therapeutique |
| US4397977A (en) | 1979-08-23 | 1983-08-09 | Pennwalt Corporation | Tetrahalophthalates as flame retardant plasticizers for halogenated resins |
| CA1206700A (en) * | 1982-01-04 | 1986-06-24 | David M. Florence | Low density cellular polyvinyl chloride |
| JPS58185637A (ja) | 1982-04-23 | 1983-10-29 | Hitachi Cable Ltd | ポリ塩化ビニル組成物 |
| JPS606749A (ja) * | 1983-06-25 | 1985-01-14 | Katsuta Kako Kk | 含ハロゲン樹脂組成物 |
| JPS62285940A (ja) * | 1986-06-04 | 1987-12-11 | Nippon Carbide Ind Co Ltd | 軟質難燃樹脂組成物 |
| US4764539A (en) | 1987-11-24 | 1988-08-16 | Norton Company | Flame resistant polymers |
| GB8916670D0 (en) | 1989-07-21 | 1989-09-06 | Alcan Int Ltd | Flame retardant polymer formulation |
| US5342874A (en) | 1989-07-21 | 1994-08-30 | Alcan International Limited | Flame retardant polymer formulation |
| US5084499A (en) * | 1990-05-09 | 1992-01-28 | Rhone-Poulenc Inc. | Phosphite as a light stabilizer and functional additive for polyvinyl chloride |
| US5227417A (en) | 1992-01-24 | 1993-07-13 | Cooper Industries, Inc. | Polyvinyl chloride based plenum cable |
| FR2748496B1 (fr) | 1996-05-07 | 1998-06-26 | Chavanoz Ind | Fil composite |
| ZA9837B (en) | 1997-01-08 | 1998-10-08 | Alcan Int Ltd | Fire-resistant polymer formulations |
| DE19752481A1 (de) | 1997-11-27 | 1999-06-02 | Cit Alcatel | Isoliermaterial auf der Basis von Polyvinylchlorid |
| KR20040099130A (ko) * | 2003-05-16 | 2004-11-26 | 주식회사 엘지화학 | 저발연 난연성 장식시트 |
| ES2305710T3 (es) | 2004-01-07 | 2008-11-01 | Italmatch Chemicals S.P.A. | Composiciones de poliamida con retardo de llama por hipofosfito de aluminio. |
| US8034860B2 (en) * | 2006-07-21 | 2011-10-11 | Eastman Specialties Holdings Corporation | Organosol plastisol compositions |
| JP5431300B2 (ja) * | 2007-04-03 | 2014-03-05 | ビーエーエスエフ ソシエタス・ヨーロピア | Ｄｏｐｏ難燃性組成物 |
| EP2178960B1 (en) | 2007-07-13 | 2011-05-25 | Italmatch Chemicals S.P.A. | Halogen-free flame retardant additive |
| WO2009102877A1 (en) * | 2008-02-15 | 2009-08-20 | Union Carbide Chemicals & Plastics Technology Llc (Formerly Union Carbide Chemicals & Plastics Technology Corporation) | A replacement plasticizer system for phthalate-plasticized formulations |
| US20100003879A1 (en) | 2008-07-02 | 2010-01-07 | Porcher Industries | Composition ignifugee a base de PVC |
| CN101870790A (zh) * | 2010-06-29 | 2010-10-27 | 广州大学 | 聚氯乙烯用Ca/Mg/Zn复合稳定剂及其制备方法 |
| DE102010035103A1 (de) * | 2010-08-23 | 2012-02-23 | Catena Additives Gmbh & Co. Kg | Flammschutzmittelzusammensetzungen enthaltend Triazin-interkalierte Metall-Phosphate |
| WO2012113145A1 (en) * | 2011-02-24 | 2012-08-30 | Rhodia (China) Co., Ltd. | Flame retardant polymer compositions comprising stabilized hypophosphite salts |
| WO2012113146A1 (en) * | 2011-02-24 | 2012-08-30 | Rhodia (China) Co., Ltd. | Flame retardant polymer compositions comprising stabilized hypophosphite salts |
-
2012
- 2012-07-17 ES ES12745901.4T patent/ES2652520T3/es active Active
- 2012-07-17 PT PT127459014T patent/PT2875069T/pt unknown
- 2012-07-17 DK DK12745901.4T patent/DK2875069T3/en active
- 2012-07-17 US US14/409,359 patent/US20150353711A1/en not_active Abandoned
- 2012-07-17 EP EP12745901.4A patent/EP2875069B1/en not_active Not-in-force
- 2012-07-17 PL PL12745901T patent/PL2875069T3/pl unknown
- 2012-07-17 WO PCT/IB2012/001392 patent/WO2014013284A1/en not_active Ceased
- 2012-07-17 KR KR20147036953A patent/KR20150042159A/ko not_active Ceased
- 2012-07-17 JP JP2015522177A patent/JP2015522691A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| KR20150042159A (ko) | 2015-04-20 |
| US20150353711A1 (en) | 2015-12-10 |
| WO2014013284A1 (en) | 2014-01-23 |
| DK2875069T3 (en) | 2018-01-02 |
| JP2015522691A (ja) | 2015-08-06 |
| PT2875069T (pt) | 2017-12-29 |
| PL2875069T3 (pl) | 2018-03-30 |
| EP2875069B1 (en) | 2017-09-20 |
| EP2875069A1 (en) | 2015-05-27 |
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