ES2643992T3 - Procedimiento para el pretratamiento de lignocelulosa usando un disolvente de supercelulosa y disolventes altamente volátiles - Google Patents
Procedimiento para el pretratamiento de lignocelulosa usando un disolvente de supercelulosa y disolventes altamente volátiles Download PDFInfo
- Publication number
- ES2643992T3 ES2643992T3 ES09720599.1T ES09720599T ES2643992T3 ES 2643992 T3 ES2643992 T3 ES 2643992T3 ES 09720599 T ES09720599 T ES 09720599T ES 2643992 T3 ES2643992 T3 ES 2643992T3
- Authority
- ES
- Spain
- Prior art keywords
- cellulose
- hemicellulose
- solvent
- lignocellulose
- lignin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B1/00—Preparatory treatment of cellulose for making derivatives thereof, e.g. pre-treatment, pre-soaking, activation
- C08B1/003—Preparation of cellulose solutions, i.e. dopes, with different possible solvents, e.g. ionic liquids
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H8/00—Macromolecular compounds derived from lignocellulosic materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/04—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Processing Of Solid Wastes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Compounds Of Unknown Constitution (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3681308P | 2008-03-14 | 2008-03-14 | |
| US36813P | 2008-03-14 | ||
| PCT/US2009/037234 WO2009114843A1 (en) | 2008-03-14 | 2009-03-16 | Method and apparatus for lignocellulose pretreatment using a super-cellulose-solvent and highly volatile solvents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2643992T3 true ES2643992T3 (es) | 2017-11-27 |
Family
ID=41061622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09720599.1T Active ES2643992T3 (es) | 2008-03-14 | 2009-03-16 | Procedimiento para el pretratamiento de lignocelulosa usando un disolvente de supercelulosa y disolventes altamente volátiles |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US8663392B2 (enExample) |
| EP (2) | EP2254913B1 (enExample) |
| JP (2) | JP5551091B2 (enExample) |
| CN (2) | CN102027021B (enExample) |
| AU (1) | AU2009223302B2 (enExample) |
| BR (1) | BRPI0909297B1 (enExample) |
| CA (1) | CA2718427C (enExample) |
| DK (1) | DK2254913T3 (enExample) |
| ES (1) | ES2643992T3 (enExample) |
| NO (1) | NO2254913T3 (enExample) |
| PL (1) | PL2254913T3 (enExample) |
| PT (1) | PT2254913T (enExample) |
| RU (1) | RU2509778C2 (enExample) |
| WO (1) | WO2009114843A1 (enExample) |
| ZA (1) | ZA201006622B (enExample) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007111605A1 (en) | 2006-03-29 | 2007-10-04 | Virginia Tech Intellectual Properties, Inc. | Cellulose-solvent-based lignocellulose fractionation with modest reaction conditions and reagent cycling |
| US7674608B2 (en) | 2007-02-23 | 2010-03-09 | The University Of Toledo | Saccharifying cellulose |
| JP5563313B2 (ja) | 2007-03-14 | 2014-07-30 | ザ・ユニバーシティ・オブ・トレド | バイオマス前処理 |
| NO2254913T3 (enExample) * | 2008-03-14 | 2017-12-16 | ||
| US7999355B2 (en) * | 2008-07-11 | 2011-08-16 | Air Products And Chemicals, Inc. | Aminosilanes for shallow trench isolation films |
| US8546560B2 (en) | 2008-07-16 | 2013-10-01 | Renmatix, Inc. | Solvo-thermal hydrolysis of cellulose |
| EP3778717A1 (en) | 2008-07-16 | 2021-02-17 | Renmatix Inc. | Nano-catalytic-solvo-thermal technology platform bio-refineries |
| US20100044210A1 (en) * | 2008-08-20 | 2010-02-25 | The Board Of Regents Of The University Of Texas System | METHOD OF DIGESTING CELLULOSE TO GLUCOSE USING SALTS AND MICROWAVE (muWAVE) ENERGY |
| US20100206499A1 (en) * | 2009-02-13 | 2010-08-19 | Zilkha Biomass Acquisitions Company L.L.C. | Methods for Producing Biomass-Based Fuel With Pulp Processing Equipment |
| GB0907879D0 (en) * | 2009-05-07 | 2009-06-24 | Weyland As | Process |
| WO2011041455A1 (en) | 2009-09-29 | 2011-04-07 | The Regents Of The University Of California | Recovery of sugars from ionic liquid biomass liquor by solvent extraction |
| US8790542B2 (en) * | 2009-09-30 | 2014-07-29 | Sandia Corporation | Compositions and methods useful for ionic liquid treatment of biomass |
| WO2011044378A1 (en) * | 2009-10-09 | 2011-04-14 | American Process, Inc. | Alcohol sulfite biorefinery process |
| US8618280B2 (en) * | 2009-11-30 | 2013-12-31 | Applied Biorefinery Sciences Llc | Biorefinery process for extraction, separation, and recovery of fermentable saccharides, other useful compounds, and yield of improved lignocellulosic material from plant biomass |
| EP2333151A1 (en) * | 2009-12-11 | 2011-06-15 | Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO | Novel method for processing lignocellulose containing material |
| CA2769746C (en) | 2010-01-19 | 2013-10-15 | Renmatix, Inc. | Production of fermentable sugars and lignin from biomass using supercritical fluids |
| EP2403861A1 (en) * | 2010-05-07 | 2012-01-11 | Abengoa Bioenergy New Technologies, Inc. | Process for recovery of values from a fermentation mass obtained in producing ethanol and products thereof |
| EP3401410B1 (en) | 2010-06-26 | 2020-12-30 | Virdia, Inc. | Methods for production of sugar mixtures |
| IL206678A0 (en) | 2010-06-28 | 2010-12-30 | Hcl Cleantech Ltd | A method for the production of fermentable sugars |
| US8497097B2 (en) * | 2010-08-11 | 2013-07-30 | Georgia Tech Research Corporation | Chlorine dioxide treatment of biomass feedstock |
| IL207945A0 (en) | 2010-09-02 | 2010-12-30 | Robert Jansen | Method for the production of carbohydrates |
| CN102086611B (zh) * | 2010-11-30 | 2012-11-14 | 王祥槐 | 一种用于改变和改善纤维表面性质的组合物和造纸方法 |
| PT106039A (pt) * | 2010-12-09 | 2012-10-26 | Hcl Cleantech Ltd | Processos e sistemas para o processamento de materiais lenhocelulósicos e composições relacionadas |
| AU2012209451B2 (en) * | 2011-01-24 | 2014-10-02 | Buckman Laboratories International, Inc. | Processes and systems for enzymatically isolating lignin and other bioproducts from herbaceous plants |
| US9309577B2 (en) * | 2011-01-28 | 2016-04-12 | Institute Of Process Engineering, Chinese Academy Of Sciences | Process for producing bio-based product from straw hemicellulose and fully utilizing the components thereof |
| CN102690899A (zh) * | 2011-03-21 | 2012-09-26 | 帅科 | 一种浓磷酸水解木质纤维素原料并回收磷酸的方法 |
| EP3401322B1 (en) | 2011-04-07 | 2022-06-08 | Virdia, LLC | Lignocellulose conversion processes and products |
| US8801859B2 (en) | 2011-05-04 | 2014-08-12 | Renmatix, Inc. | Self-cleaning apparatus and method for thick slurry pressure control |
| AU2012250575B2 (en) | 2011-05-04 | 2015-03-26 | Renmatix, Inc. | Lignin production from lignocellulosic biomass |
| US8926794B2 (en) * | 2011-07-07 | 2015-01-06 | Tate & Lyle Ingredients Americas Llc | Process of extraction of hemicellulose from corn fiber |
| JP2013066420A (ja) * | 2011-09-22 | 2013-04-18 | Equos Research Co Ltd | セルロース系バイオマス原料の可溶化方法 |
| CN103958689A (zh) * | 2011-09-23 | 2014-07-30 | 阿彻丹尼尔斯米德兰德公司 | C1-c2有机酸处理木质纤维素生物质以制造酰化纤维素纸浆、半纤维素、木质素以及糖和糖的发酵 |
| US9617608B2 (en) | 2011-10-10 | 2017-04-11 | Virdia, Inc. | Sugar compositions |
| US9518729B2 (en) | 2011-12-13 | 2016-12-13 | Renmatix, Inc. | Lignin fired supercritical or near critical water generator, system and method |
| US8759498B2 (en) | 2011-12-30 | 2014-06-24 | Renmatix, Inc. | Compositions comprising lignin |
| EP2620442A1 (en) | 2012-01-27 | 2013-07-31 | BIOeCON International Holding N.V. | Process for recovering saccharides from cellulose hydrolysis reaction mixture |
| BR112014027474B1 (pt) * | 2012-05-03 | 2020-03-17 | Virdia, Inc. | Métodos de processamento de materiais lingnocelulósicos |
| US20140366870A1 (en) * | 2012-12-31 | 2014-12-18 | Api Intellectual Property Holdings, Llc | Methods for recovering and recycling salt byproducts in biorefinery processes |
| US20140187759A1 (en) * | 2012-12-31 | 2014-07-03 | Api Intellectual Property Holdings, Llc | Biorefining processes and apparatus for separating cellulose hemicellulose, and lignin from biomass |
| EP2956465B1 (en) * | 2013-02-15 | 2024-10-16 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO | Process for the treatment of lignocellulosic biomass |
| US9657146B2 (en) | 2013-03-14 | 2017-05-23 | Virdia, Inc. | Methods for treating lignocellulosic materials |
| CN105358608B (zh) | 2013-05-03 | 2018-11-16 | 威尔迪亚公司 | 用于制备热稳定的木质素级分的方法 |
| AU2013388054B2 (en) | 2013-05-03 | 2017-09-21 | Virdia, Inc. | Methods for treating lignocellulosic materials |
| JP6182369B2 (ja) * | 2013-06-24 | 2017-08-16 | 花王株式会社 | リグニン分解物の製造方法 |
| JP6182368B2 (ja) * | 2013-06-24 | 2017-08-16 | 花王株式会社 | リグニン分解物の製造方法 |
| US20150034109A1 (en) * | 2013-08-02 | 2015-02-05 | R.J. Reynolds Tobacco Company | Process for Producing Lignin from Tobacco |
| CN103483596A (zh) * | 2013-08-21 | 2014-01-01 | 安徽格义循环经济产业园有限公司 | 生化木素生产方法 |
| CN103483595A (zh) * | 2013-08-21 | 2014-01-01 | 安徽格义循环经济产业园有限公司 | 以木材加工剩余物为原料的高效综合利用的方法 |
| US20150136345A1 (en) * | 2013-11-19 | 2015-05-21 | Api Intellectual Property Holdings, Llc | Methods of washing cellulose-rich solids from biomass fractionation to reduce lignin and ash content |
| US10240006B2 (en) | 2014-05-01 | 2019-03-26 | Renmatix, Inc. | Upgrading lignin from lignin-containing residues through reactive extraction |
| JP6687594B2 (ja) * | 2014-07-09 | 2020-04-22 | ヴァーディア, インコーポレイテッド | 黒液からリグニンを分離および精製する方法ならびにその組成物 |
| EP4357434A3 (en) | 2014-09-26 | 2024-11-20 | Renmatix, Inc. | Adhesive compositions comprising type-ii cellulose |
| WO2016112134A1 (en) | 2015-01-07 | 2016-07-14 | Virdia, Inc. | Methods for extracting and converting hemicellulose sugars |
| BR112017025322A8 (pt) | 2015-05-27 | 2022-08-23 | Virdia Inc | Processos integrados para recuperação de hidrolisato celulósico após hidrólise de polpa de celulose |
| FI127740B (en) * | 2015-05-29 | 2019-01-15 | Upm Kymmene Corp | A method and an apparatus for forming a lignin fraction, a lignin composition and its use |
| JP2017000093A (ja) * | 2015-06-11 | 2017-01-05 | 出光興産株式会社 | セルロース含有固形物の製造方法及びグルコースの製造方法 |
| WO2017093511A1 (en) | 2015-12-04 | 2017-06-08 | Biométhodes S.A. | A method for fractionating a lignocellulosic biomass |
| EP3383971A1 (en) * | 2015-12-04 | 2018-10-10 | Arbiom SAS | System and method for treatment of biomass for the production of biofuels and biochemicals |
| JP6728720B2 (ja) * | 2016-02-01 | 2020-07-22 | 王子ホールディングス株式会社 | リグニン組成物 |
| JP6945826B2 (ja) * | 2016-09-09 | 2021-10-06 | 国立大学法人京都大学 | セルロース及びヘミセルロースを含む組成物を製造する方法、並びにその組成物を用いて糖化を行う方法 |
| NO20170031A1 (en) * | 2017-01-08 | 2018-07-09 | Abadjom Consulting As | Electron beam and steam explosion pretreatments of biomass for production in a low energy biorefinery |
| EP3666784A4 (en) * | 2017-08-10 | 2021-04-14 | Idemitsu Kosan Co.,Ltd. | Manufacturing method for modified lignin and modified polyphenol, and modified lignin-including resin composition material |
| WO2019149853A1 (en) | 2018-01-31 | 2019-08-08 | Avantium Knowledge Centre B.V. | A process for the conversion of a solid lignocellulosic material |
| CN110272927A (zh) * | 2018-03-13 | 2019-09-24 | 北京化工大学 | 一种利用酮醇类预处理剂预处理木质纤维素的方法 |
| ES2915174B2 (es) * | 2020-12-18 | 2023-01-04 | Instituto Nac De Investigacion Y Tecnologia Agraria Y Alimentaria Inia | Procedimiento de obtencion de papel de embalaje reforzado |
| CN118369147A (zh) * | 2021-10-01 | 2024-07-19 | 斯佩罗可再生能源有限责任公司 | 从生物质中提取和纯化天然阿魏酸并转化为香兰素 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB421379A (en) | 1933-06-12 | 1934-12-12 | Henry Dreyfus | Improvements in or relating to the production of cellulose from lignocellulosic materials |
| US3402997A (en) | 1964-03-25 | 1968-09-24 | Armour Agricult Chem | Concentrating and separating impuritycontaining phosphoric acids |
| FR2264489A1 (en) * | 1974-03-20 | 1975-10-17 | Thomas Charles | Cattle forage upgrading - by conversion of cellulose with phosphoric acid |
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| US4174976A (en) * | 1978-03-08 | 1979-11-20 | Purdue Research Foundation | Acid hydrolysis of cellulose to yield glucose |
| US4265675A (en) | 1978-03-08 | 1981-05-05 | Purdue Research Foundation | Nontoxic cellulose solvent and process for forming and utilizing the same |
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| BR8506701A (pt) | 1984-04-27 | 1986-04-15 | Michelin Rech Tech | Composicoes anisotropicas de esteres de celulose,processo para obter estas composicoes,fibras de esteres de celulose ou celulose |
| SU1348396A1 (ru) | 1985-05-27 | 1987-10-30 | Научно-исследовательский институт физико-химических проблем Белорусского государственного университета им.В.И.Ленина | Способ получени растворов целлюлозы |
| ATA43094A (de) | 1994-03-01 | 1995-04-15 | Chemiefaser Lenzing Ag | Verfahren zur herstellung cellulosischer formkörper, lösung eines tert. aminoxids und ihre aufarbeitung |
| DK0777767T3 (da) | 1994-08-19 | 1999-06-07 | Akzo Nobel Nv | Fremgangsmåde til fremstilling af celluloseekstrudater |
| US6228177B1 (en) | 1996-09-30 | 2001-05-08 | Midwest Research Institute | Aqueous fractionation of biomass based on novel carbohydrate hydrolysis kinetics |
| FR2759094B1 (fr) | 1997-02-06 | 1999-03-05 | Michelin Rech Tech | Fibres cellulosiques d'origine cristal-liquide ayant un allongement a la rupture important ; procedes pour les obtenir |
| RU2189996C2 (ru) * | 1997-11-04 | 2002-09-27 | Дедини С/А. Администрасао е Партисипасоес | Способ быстрого кислотного гидролиза лигноцеллюлозного материала и гидролизный реактор |
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| JP2006149343A (ja) | 2004-11-26 | 2006-06-15 | Daitoo Fujitekku:Kk | 木質系バイオマスからのグルコース生成物とグルコース生成物製造方法 |
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| US20090017503A1 (en) * | 2005-08-05 | 2009-01-15 | The Trustees Of Dartmouth College | Method and Apparatus for Saccharide Precipitation From Pretreated Lignocellulosic Materials |
| CN100365099C (zh) | 2006-02-27 | 2008-01-30 | 淮北市辉克药业有限公司 | 全新的生物质生产液体燃料技术 |
| WO2007111605A1 (en) | 2006-03-29 | 2007-10-04 | Virginia Tech Intellectual Properties, Inc. | Cellulose-solvent-based lignocellulose fractionation with modest reaction conditions and reagent cycling |
| JP2008056819A (ja) * | 2006-08-31 | 2008-03-13 | Daicel Chem Ind Ltd | セルロース混合脂肪酸エステル、その製造方法 |
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| CN101121735B (zh) * | 2007-07-06 | 2011-04-06 | 陈培豪 | 植物纤维原料水解液及利用该水解液预处理植物纤维原料的方法 |
| CN101130793A (zh) * | 2007-08-20 | 2008-02-27 | 吉林大学 | 一种稻壳生产燃料乙醇及资源化综合利用的新方法 |
| EP2262902A4 (en) | 2008-02-05 | 2013-08-07 | Lignoil Technologies Private Ltd | COMPLETE LIQUEFACTION OF LIGNOCELLULOSIC AGRODUCTS TO FORM LIQUID BIOCARBURANTS |
| NO2254913T3 (enExample) * | 2008-03-14 | 2017-12-16 |
-
2009
- 2009-03-16 NO NO09720599A patent/NO2254913T3/no unknown
- 2009-03-16 EP EP09720599.1A patent/EP2254913B1/en not_active Not-in-force
- 2009-03-16 BR BRPI0909297-8A patent/BRPI0909297B1/pt not_active IP Right Cessation
- 2009-03-16 PT PT97205991T patent/PT2254913T/pt unknown
- 2009-03-16 RU RU2010141585/05A patent/RU2509778C2/ru not_active IP Right Cessation
- 2009-03-16 PL PL09720599T patent/PL2254913T3/pl unknown
- 2009-03-16 EP EP16200785.0A patent/EP3205672A1/en not_active Withdrawn
- 2009-03-16 CN CN200980117175.8A patent/CN102027021B/zh not_active Expired - Fee Related
- 2009-03-16 AU AU2009223302A patent/AU2009223302B2/en not_active Ceased
- 2009-03-16 CN CN201410067339.3A patent/CN103819688B/zh not_active Expired - Fee Related
- 2009-03-16 DK DK09720599.1T patent/DK2254913T3/en active
- 2009-03-16 JP JP2010550913A patent/JP5551091B2/ja not_active Expired - Fee Related
- 2009-03-16 CA CA2718427A patent/CA2718427C/en not_active Expired - Fee Related
- 2009-03-16 US US12/404,466 patent/US8663392B2/en not_active Expired - Fee Related
- 2009-03-16 ES ES09720599.1T patent/ES2643992T3/es active Active
- 2009-03-16 WO PCT/US2009/037234 patent/WO2009114843A1/en not_active Ceased
-
2010
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2013
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2014
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| RU2010141585A (ru) | 2012-04-20 |
| CN103819688B (zh) | 2017-04-12 |
| US20090229599A1 (en) | 2009-09-17 |
| CN102027021A (zh) | 2011-04-20 |
| BRPI0909297A2 (pt) | 2017-11-21 |
| CN103819688A (zh) | 2014-05-28 |
| US20130236953A1 (en) | 2013-09-12 |
| EP2254913A1 (en) | 2010-12-01 |
| JP2011515082A (ja) | 2011-05-19 |
| CA2718427A1 (en) | 2009-09-17 |
| WO2009114843A1 (en) | 2009-09-17 |
| EP2254913B1 (en) | 2017-07-19 |
| JP5551091B2 (ja) | 2014-07-16 |
| CA2718427C (en) | 2015-01-27 |
| AU2009223302A1 (en) | 2009-09-17 |
| JP2014209906A (ja) | 2014-11-13 |
| PL2254913T3 (pl) | 2018-02-28 |
| ZA201006622B (en) | 2011-11-30 |
| RU2509778C2 (ru) | 2014-03-20 |
| JP5965431B2 (ja) | 2016-08-03 |
| BRPI0909297B1 (pt) | 2019-07-02 |
| DK2254913T3 (en) | 2017-10-30 |
| HK1198447A1 (zh) | 2015-04-24 |
| US8663392B2 (en) | 2014-03-04 |
| US8900369B2 (en) | 2014-12-02 |
| EP3205672A1 (en) | 2017-08-16 |
| CN102027021B (zh) | 2014-03-26 |
| AU2009223302B2 (en) | 2013-12-05 |
| EP2254913A4 (en) | 2013-10-02 |
| PT2254913T (pt) | 2017-10-23 |
| NO2254913T3 (enExample) | 2017-12-16 |
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