ES2540079T3 - Adhesivo de poli-alfa-olefina amorfa de baja temperatura de aplicación - Google Patents

Adhesivo de poli-alfa-olefina amorfa de baja temperatura de aplicación Download PDF

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ES2540079T3
ES2540079T3 ES11820578.0T ES11820578T ES2540079T3 ES 2540079 T3 ES2540079 T3 ES 2540079T3 ES 11820578 T ES11820578 T ES 11820578T ES 2540079 T3 ES2540079 T3 ES 2540079T3
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copolymer
adhesive
application
alpha
low temperature
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Yuhong Hu
Charles W. Paul
Darshak Desai
Salvador Alvarado
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Henkel IP and Holding GmbH
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/18—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C09J123/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35—Heat-activated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B32B2037/1215—Hot-melt adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00—Personal care
    • B32B2555/02—Diapers or napkins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/26—Presence of textile or fabric
    • C09J2400/263—Presence of textile or fabric in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Adhesive Tapes (AREA)

Abstract

Un adhesivo termofusible que comprende al menos el 45 %, basado en el adhesivo, de un copolímero de polibuteno amorfo que tiene una temperatura de reblandecimiento de 70 a 105 ºC y una viscosidad inferior a 1.900 mPa(1.900 cP) a 190 ºC, así como un valor de tan (δ) superior a 30 a 140 ºC, y en el que el adhesivo termofusible tiene una viscosidad inferior a 6.000 mPa(6.000 cP) a 150 ºC.

Description

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E11820578
19-06-2015
Tabla 1. Ejemplos de copolímeros de buteno-propileno amorfo
Polímero
Viscosidad a 190 ºC (mPa[cps]) Temperatura de reblandecimiento de anillo y bola (ºC) Tan a 140 ºC
Copolímero 1
840 88,4 59,0
Copolímero 2
1.550 90,8 53,0
Copolímero A
3.375 91,5 17,0
Copolímero B
3.560 105,2 22,8
Copolímero C
3.100 103,0 15,4
Copolímero D
1.560 145,0 10,5
Copolímero E
3.025 108,0 21,0
Copolímero F
2.200 111,5 31,3
Copolímero G
8.100 118,0 8,5
El copolímero útil para la invención tiene una viscosidad inferior a 1.900 mPa(1.900 cP) medida a 190 ºC, intervalos de temperatura de reblandecimiento de anillo y bola de 70 a 105 ºC y valor de tan  superior a 30 a 140 ºC. Solo los 5 Copolímeros 1 y 2 cumplen los tres criterios, y los Copolímeros comparativos A-G tienen al menos un criterio fuera de los intervalos útiles.
La Tabla 2 enumera muestras de adhesivo preparadas con el Copolímero 2 con diversos tipos y cantidades de agentes de pegajosidad. El adhesivo y la resina/el agente de pegajosidad, que se enumeran en la Tabla 2, se
10 fundieron entre sí con calor (a una temperatura de o superior a 140 ºC) hasta que se formó una masa fundida homogénea. Se ensayaron las características adhesivas resultantes de las muestras, presentándose los resultados en la Tabla 2.
Tabla 2. Composición adhesiva
Componentes
Muestra 1 Muestra 2 Muestra 3 Muestra 4
Copolímero 2
40 45 70 80
Resina/agente de pegajosidad - Escorez 5380
59,5 54,5 29,5
Resina/agente de pegajosidad - Eastotac H130
19,5
Antioxidante - Irganox 1010
0,5 0,5 0,5 0,5
Características adhesivas
Viscosidad a 150 ºC (mPa [cP])
1290 1465 2700 4150
Tan  a 140 ºC
61 67 75 58
Temperatura de reblandecimiento de anillo y bola (ºC)
66,4 69,3 84,6 91,6
Tg (ºC)
22,8 18,4 -5,0 -7,1
15 Todas las muestras de adhesivo anteriores tienen viscosidad inferior a 6.000 mPa(6.000 cP) a 150 ºC. Las formulaciones adhesivas comprenden un amplio intervalo de cantidades de copolímero y de resina como se ha demostrado anteriormente, y también pueden comprender predominantemente copolímero.
20 Se prepararon varias muestras de adhesivo con diferente polímero base y se ensayaron frente al adhesivo de la invención para determinar sus propiedades de rendimiento de la Tabla 3. En la Tabla 3, se indican el tipo de polímero base y el contenido. Se mezcló cada muestra con un agente de pegajosidad bajo calor (temperatura superior a 140 ºC) hasta que se formó una masa fundida homogénea. Se midieron las características adhesivas y se presentaron en la Tabla 3. A continuación, se aplicó cada adhesivo entre un sustrato no tejido y un sustrato de
25 polipelícula con un nivel de adición especificado, mostrándose la resistencia al desprendimiento resultante en la Tabla 3.
7
E11820578
19-06-2015
Tabla 3. Adhesivos para la construcción con diversos polímeros base
Muestra 4
Muestra X Muestra Y Muestra Z
Polímero base
Copolímero de buteno amorfo (Copolímero 2) (80 % en peso) Estireno/butadieno/estireno (19,5 % en peso) Poliolefina de metaloceno (16 % en peso) Copolímero de buteno amorfo (Copolímero E) (80 % en peso)
Características adhesivas
Viscosidad a 150 ºC
4.150 2.400 5.375 7.800
Temperatura de reblandecimiento de anillo y bola (ºC)
91,6 73 82 110
Tan  a 140 ºC
57 128 37,3 23,8
Tracción máxima (kPa [psi])
710,16 [103] 551,58 [80] 151,68 [22] 379,21 [55]
La resistencia al desprendimiento se midió tras unir los sustratos entre sí con el adhesivo de muestra especificado (material no tejido termosoldado de 13,5 g/m2 (13,5 gsm) de uso general y polipelícula Pliant de 0,5 mm, Pliant Corporation)
Aplicación de diseño en espirala Temp (ºC [ºF])
127 [260] 138 [280] 143 [290] 163 [325]
Resistencia al desprendimiento (kg/m [g/pulgada]) (Espiral a 3 g/m2 en sustratos GP)
23,58 [600] 18,47 [470] 15,92 [405] 18,08 [460]
Patrón aleatoriob Temperatura de aplicación (ºC [ºF])
149 [300] 149 [300] 160 [320] 177 [350]
Resistencia al desprendimiento (kg/m [g/pulgada]) (Distintivo a 1,5 g/m2 en sustratos GP)
12,50 [318] 5,85 [149] 6,01 [153] 4,72 [120]
aCabeza de boquilla en espiral Nordson que pulveriza diseños en espiral de adhesivo termofusible. bBoquilla de pulverización de distintivos Nordson que pulveriza diseños aleatorios con una cobertura uniforme y densa de adhesivo termofusible.
Para las muestras comparativas X e Y de la Tabla 3, menos del 20 % en peso de la composición total se compone del polímero base. Aunque la muestra comparativa Z (preparada con Copolímero E) también utiliza el 80 % en peso de copolímero de buteno amorfo, esta temperatura de aplicación es superior a la temperatura de aplicación de la Muestra 4 (preparada con Copolímero 2). Además, el uso del Copolímero base 2 en el adhesivo de la Muestra 4 generó la mayor resistencia al desprendimiento.
8

Claims (1)

  1. imagen1
ES11820578.0T 2010-08-26 2011-08-24 Adhesivo de poli-alfa-olefina amorfa de baja temperatura de aplicación Active ES2540079T3 (es)

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US37743310P 2010-08-26 2010-08-26
US377433P 2010-08-26
PCT/US2011/048933 WO2012027450A2 (en) 2010-08-26 2011-08-24 LOW APPLICATION TEMPERATURE AMORPHOUS POLY-α-OLEFIN ADHESIVE

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US (3) US9000079B2 (es)
EP (1) EP2609167B1 (es)
JP (1) JP5919273B2 (es)
KR (1) KR101732344B1 (es)
CN (1) CN103189461B (es)
BR (1) BR112013004339B1 (es)
CA (1) CA2807966C (es)
ES (1) ES2540079T3 (es)
MX (1) MX2013002214A (es)
PT (1) PT2609167E (es)
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WO2012027450A2 (en) * 2010-08-26 2012-03-01 Henkel Corporation LOW APPLICATION TEMPERATURE AMORPHOUS POLY-α-OLEFIN ADHESIVE
PT2739695T (pt) 2011-08-04 2019-11-29 Henkel IP & Holding GmbH Adesivos e respetiva utilização
US8865824B2 (en) 2012-09-19 2014-10-21 IFS Industries Inc. Hot melt adhesive
US9944043B2 (en) * 2012-10-02 2018-04-17 3M Innovative Properties Company Laminates and methods of making the same
AU2013329252B2 (en) 2012-10-09 2017-05-18 Avery Dennison Corporation Adhesives and related methods
DE112014002940T5 (de) * 2013-06-20 2016-03-24 The Procter & Gamble Company Absorptionsartikel mit leicht zu aktivierenden Laminaten
JP2016528323A (ja) * 2013-06-21 2016-09-15 ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング 接着剤組成物およびその使用
CN104419349A (zh) * 2013-09-10 2015-03-18 杭州邦林热熔胶有限公司 食品及日化品瓶盖用热熔胶及其制备方法
US10639210B2 (en) 2013-12-19 2020-05-05 The Procter & Gamble Company Article with tackifier-free adhesive
RU2677155C1 (ru) 2015-02-05 2019-01-15 Авери Деннисон Корпорейшн Этикеточные узлы для неблагоприятной окружающей среды
CN104715830A (zh) * 2015-03-11 2015-06-17 上海军信船舶科技有限公司 一种电缆用水密封热熔胶及其应用
BR112017019937A2 (pt) 2015-03-20 2018-06-12 Henkel IP & Holding GmbH composição adesiva de fusão a quente e uso do mesmo
CN108463530B (zh) 2016-01-14 2021-03-02 波士胶公司 使用单位点催化剂和方法制备的基于丙烯共聚物的共混物的热熔性粘合剂组合物
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