RU2013113169A - Аморфный поли-альфа-олефиновый клей с низкой температурой нанесения - Google Patents

Аморфный поли-альфа-олефиновый клей с низкой температурой нанесения Download PDF

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RU2013113169A
RU2013113169A RU2013113169/05A RU2013113169A RU2013113169A RU 2013113169 A RU2013113169 A RU 2013113169A RU 2013113169/05 A RU2013113169/05 A RU 2013113169/05A RU 2013113169 A RU2013113169 A RU 2013113169A RU 2013113169 A RU2013113169 A RU 2013113169A
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hot
melt adhesive
wax
adhesive according
polybutene copolymer
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Юйхун ХУ
Чарльз У. ПОЛ
Даршак ДЕСАЙ
Сальвадор АЛЬВАРАДО
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Хенкель Корпорейшн
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
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    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/18—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
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    • C09J11/08—Macromolecular additives
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    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
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    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
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    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C09J123/14—Copolymers of propene
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    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
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    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35—Heat-activated
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B32B2037/1215—Hot-melt adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00—Personal care
    • B32B2555/02—Diapers or napkins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
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    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/26—Presence of textile or fabric
    • C09J2400/263—Presence of textile or fabric in the substrate
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    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Adhesive Tapes (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)

Abstract

1. Термоплавкий клей, содержащий, по меньшей мере, 45 масс.%, исходя из массы клея, аморфного сополимера полибутена, который имеет температуру размягчения примерно от 70 до 105°C и вязкость меньше чем примерно 1900 сП при 190°C, и где термоплавкий клей имеет вязкость меньше чем примерно 6000 сП при 150°C.2. Термоплавкий клей по п.1, где аморфный сополимер полибутена имеет значение tan(δ) больше чем 30 при 140°C.3. Термоплавкий клей по п.1, где аморфный сополимер полибутена дополнительно включает пропиленовый сомономер.4. Термоплавкий клей по п.1, где реагент, придающий клейкость, имеет температуру размягчения больше или равную 100°C, и где реагент, придающий клейкость, выбран из группы, состоящей из C5 смол, нефтяных дистиллятов, гидрированных углеводородов, C5/C9 политерпенов, канифоли, гидрированной канифоли, эфиров канифоли и их смесей.5. Термоплавкий клей по п.1, дополнительно включающий кристаллический воск, который имеет температуру плавления больше чем 60°C, и где кристаллический воск выбран из группы, состоящей из воска Фишера-Тропша, нефтяного воска, обычного воска, природного воска, функционализированного воска, сополимеров полиолефинов и их смесей.6. Термоплавкий клей по п.1, который, по существу, не содержит воска и/или пластификатора.7. Термоплавкий клей по п.1, который содержит более чем 60% аморфного сополимера полибутена.8. Термоплавкий клей по п.1, где клей имеет максимальную величину прочности при растяжении больше чем 55 фунт/кв. дюйм (0,38 кПа) при 23°C при скорости вытягивания 12 дюймов/мин (30,5 см/мин).9. Изделие, содержащее клей по п.1, которое представляет собой продукт личной гигиены, продукт медицинского назначения, изделие медицинского

Claims (10)

1. Термоплавкий клей, содержащий, по меньшей мере, 45 масс.%, исходя из массы клея, аморфного сополимера полибутена, который имеет температуру размягчения примерно от 70 до 105°C и вязкость меньше чем примерно 1900 сП при 190°C, и где термоплавкий клей имеет вязкость меньше чем примерно 6000 сП при 150°C.
2. Термоплавкий клей по п.1, где аморфный сополимер полибутена имеет значение tan(δ) больше чем 30 при 140°C.
3. Термоплавкий клей по п.1, где аморфный сополимер полибутена дополнительно включает пропиленовый сомономер.
4. Термоплавкий клей по п.1, где реагент, придающий клейкость, имеет температуру размягчения больше или равную 100°C, и где реагент, придающий клейкость, выбран из группы, состоящей из C5 смол, нефтяных дистиллятов, гидрированных углеводородов, C5/C9 политерпенов, канифоли, гидрированной канифоли, эфиров канифоли и их смесей.
5. Термоплавкий клей по п.1, дополнительно включающий кристаллический воск, который имеет температуру плавления больше чем 60°C, и где кристаллический воск выбран из группы, состоящей из воска Фишера-Тропша, нефтяного воска, обычного воска, природного воска, функционализированного воска, сополимеров полиолефинов и их смесей.
6. Термоплавкий клей по п.1, который, по существу, не содержит воска и/или пластификатора.
7. Термоплавкий клей по п.1, который содержит более чем 60% аморфного сополимера полибутена.
8. Термоплавкий клей по п.1, где клей имеет максимальную величину прочности при растяжении больше чем 55 фунт/кв. дюйм (0,38 кПа) при 23°C при скорости вытягивания 12 дюймов/мин (30,5 см/мин).
9. Изделие, содержащее клей по п.1, которое представляет собой продукт личной гигиены, продукт медицинского назначения, изделие медицинского назначения, товар для дома или промышленный продукт.
10. Способ, включающий:
- нанесение клея по п.1 на подложку напылением расплава, вихревым нанесением рисунка, случайным напылением и/или нанесением покрытия через щелевую головку с диапазоном привеса по клею примерно от 0,1 до 20 г/м2 при 150°C или ниже на первую подложку;
- наложение второй подложки на клей, посредством этого формируя соединение,
в котором, по меньшей мере, одна подложка представляет собой нетканую пленку.
RU2013113169/05A 2010-08-26 2011-08-24 Аморфный поли-альфа-олефиновый клей с низкой температурой нанесения RU2585640C2 (ru)

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US37743310P 2010-08-26 2010-08-26
US61/377,433 2010-08-26
PCT/US2011/048933 WO2012027450A2 (en) 2010-08-26 2011-08-24 LOW APPLICATION TEMPERATURE AMORPHOUS POLY-α-OLEFIN ADHESIVE

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CN (1) CN103189461B (ru)
BR (1) BR112013004339B1 (ru)
CA (1) CA2807966C (ru)
ES (1) ES2540079T3 (ru)
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CN105907337B (zh) * 2011-08-04 2018-06-22 汉高知识产权控股有限责任公司 粘合剂及其用途
US8865824B2 (en) 2012-09-19 2014-10-21 IFS Industries Inc. Hot melt adhesive
US9944043B2 (en) 2012-10-02 2018-04-17 3M Innovative Properties Company Laminates and methods of making the same
WO2014059055A1 (en) 2012-10-09 2014-04-17 Avery Dennison Corporation Adhesives and related methods
WO2014204775A1 (en) * 2013-06-20 2014-12-24 The Procter & Gamble Company Absorbent articles with activation-friendly laminates
CN105324451A (zh) * 2013-06-21 2016-02-10 汉高知识产权控股有限责任公司 粘合剂组合物及其应用
CN104419349A (zh) * 2013-09-10 2015-03-18 杭州邦林热熔胶有限公司 食品及日化品瓶盖用热熔胶及其制备方法
US10639210B2 (en) 2013-12-19 2020-05-05 The Procter & Gamble Company Article with tackifier-free adhesive
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