ES2391248T3 - Espuma moldeada elástica a base de mezclas poliméricas de poliolefina/estireno - Google Patents
Espuma moldeada elástica a base de mezclas poliméricas de poliolefina/estireno Download PDFInfo
- Publication number
- ES2391248T3 ES2391248T3 ES09720933T ES09720933T ES2391248T3 ES 2391248 T3 ES2391248 T3 ES 2391248T3 ES 09720933 T ES09720933 T ES 09720933T ES 09720933 T ES09720933 T ES 09720933T ES 2391248 T3 ES2391248 T3 ES 2391248T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- percent
- styrene
- expandable thermoplastic
- propellant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 40
- 239000013518 molded foam Substances 0.000 title claims description 28
- 229920002959 polymer blend Polymers 0.000 title claims description 12
- 239000002245 particle Substances 0.000 claims abstract description 139
- 239000003380 propellant Substances 0.000 claims abstract description 76
- 229920000642 polymer Polymers 0.000 claims abstract description 72
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 62
- 229920001400 block copolymer Polymers 0.000 claims abstract description 51
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 24
- 238000002844 melting Methods 0.000 claims abstract description 23
- 230000008018 melting Effects 0.000 claims abstract description 23
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002667 nucleating agent Substances 0.000 claims abstract description 14
- 239000002174 Styrene-butadiene Substances 0.000 claims abstract description 12
- 239000011115 styrene butadiene Substances 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims abstract description 5
- 239000006260 foam Substances 0.000 claims description 104
- 239000000203 mixture Substances 0.000 claims description 50
- 239000012071 phase Substances 0.000 claims description 48
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 37
- 229920006248 expandable polystyrene Polymers 0.000 claims description 31
- 229920001577 copolymer Polymers 0.000 claims description 29
- 239000004416 thermosoftening plastic Substances 0.000 claims description 29
- -1 polyethylene Polymers 0.000 claims description 23
- 239000004698 Polyethylene Substances 0.000 claims description 22
- 238000005187 foaming Methods 0.000 claims description 21
- 239000004793 Polystyrene Substances 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 19
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 18
- 229920000573 polyethylene Polymers 0.000 claims description 17
- 229920002223 polystyrene Polymers 0.000 claims description 17
- 150000001993 dienes Chemical class 0.000 claims description 16
- 230000009477 glass transition Effects 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 2
- 238000005227 gel permeation chromatography Methods 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical group C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 abstract description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 28
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000008187 granular material Substances 0.000 description 24
- 238000009826 distribution Methods 0.000 description 19
- 238000005452 bending Methods 0.000 description 16
- 238000003860 storage Methods 0.000 description 12
- 239000011324 bead Substances 0.000 description 11
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 238000010276 construction Methods 0.000 description 10
- 229920002633 Kraton (polymer) Polymers 0.000 description 9
- 230000003068 static effect Effects 0.000 description 9
- 238000003466 welding Methods 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 238000005469 granulation Methods 0.000 description 8
- 230000003179 granulation Effects 0.000 description 8
- 239000012768 molten material Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 239000004604 Blowing Agent Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000005336 cracking Methods 0.000 description 6
- 229920000578 graft copolymer Polymers 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000454 talc Substances 0.000 description 6
- 229910052623 talc Inorganic materials 0.000 description 6
- 101000983970 Conus catus Alpha-conotoxin CIB Proteins 0.000 description 5
- 239000011162 core material Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- 101000932768 Conus catus Alpha-conotoxin CIC Proteins 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 4
- 238000004455 differential thermal analysis Methods 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000000265 homogenisation Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 230000008092 positive effect Effects 0.000 description 4
- 159000000001 potassium salts Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 230000001143 conditioned effect Effects 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000004620 low density foam Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000004627 transmission electron microscopy Methods 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- ZMYIIHDQURVDRB-UHFFFAOYSA-N 1-phenylethenylbenzene Chemical group C=1C=CC=CC=1C(=C)C1=CC=CC=C1 ZMYIIHDQURVDRB-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011258 core-shell material Substances 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 238000001493 electron microscopy Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 235000013847 iso-butane Nutrition 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- OBTSLRFPKIKXSZ-UHFFFAOYSA-N lithium potassium Chemical compound [Li].[K] OBTSLRFPKIKXSZ-UHFFFAOYSA-N 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000011326 mechanical measurement Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 229920006327 polystyrene foam Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 229920002397 thermoplastic olefin Polymers 0.000 description 2
- 229920000428 triblock copolymer Polymers 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
- MJYQFWSXKFLTAY-OVEQLNGDSA-N (2r,3r)-2,3-bis[(4-hydroxy-3-methoxyphenyl)methyl]butane-1,4-diol;(2r,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O.C1=C(O)C(OC)=CC(C[C@@H](CO)[C@H](CO)CC=2C=C(OC)C(O)=CC=2)=C1 MJYQFWSXKFLTAY-OVEQLNGDSA-N 0.000 description 1
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 1
- 229920002438 Oppanol® B 150 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- STLLXWLDRUVCHL-UHFFFAOYSA-N [2-[1-[2-hydroxy-3,5-bis(2-methylbutan-2-yl)phenyl]ethyl]-4,6-bis(2-methylbutan-2-yl)phenyl] prop-2-enoate Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(C(C)C=2C(=C(C=C(C=2)C(C)(C)CC)C(C)(C)CC)OC(=O)C=C)=C1O STLLXWLDRUVCHL-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 229940042935 dichlorodifluoromethane Drugs 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940073584 methylene chloride Drugs 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 150000002848 norbornenes Chemical class 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- ZRLVQFQTCMUIRM-UHFFFAOYSA-N potassium;2-methylbutan-2-olate Chemical compound [K+].CCC(C)(C)[O-] ZRLVQFQTCMUIRM-UHFFFAOYSA-N 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
- C08J9/232—Forming foamed products by sintering expandable particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
- B29B9/065—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion under-water, e.g. underwater pelletizers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/036—Use of an organic, non-polymeric compound to impregnate, bind or coat a foam, e.g. fatty acid ester
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08152693 | 2008-03-13 | ||
| EP08152693 | 2008-03-13 | ||
| EP08173086 | 2008-12-30 | ||
| EP08173086 | 2008-12-30 | ||
| EP08173087 | 2008-12-30 | ||
| EP08173084 | 2008-12-30 | ||
| EP08173087 | 2008-12-30 | ||
| EP08173084 | 2008-12-30 | ||
| EP09154432 | 2009-03-05 | ||
| EP09154432 | 2009-03-05 | ||
| PCT/EP2009/052920 WO2009112549A1 (de) | 2008-03-13 | 2009-03-12 | Elastischer partikelschaumstoff auf basis von polyolefin/styrol-polymer-mischungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2391248T3 true ES2391248T3 (es) | 2012-11-22 |
Family
ID=40661863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09720933T Active ES2391248T3 (es) | 2008-03-13 | 2009-03-12 | Espuma moldeada elástica a base de mezclas poliméricas de poliolefina/estireno |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20110065819A1 (enExample) |
| EP (1) | EP2254937B1 (enExample) |
| JP (1) | JP5248630B2 (enExample) |
| KR (1) | KR101554377B1 (enExample) |
| CN (1) | CN101970554B (enExample) |
| BR (1) | BRPI0909438A2 (enExample) |
| CA (1) | CA2718001A1 (enExample) |
| DK (1) | DK2254937T3 (enExample) |
| ES (1) | ES2391248T3 (enExample) |
| MX (1) | MX2010009533A (enExample) |
| MY (1) | MY156035A (enExample) |
| PL (1) | PL2254937T3 (enExample) |
| TW (1) | TWI441864B (enExample) |
| WO (1) | WO2009112549A1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8759445B2 (en) | 2008-06-27 | 2014-06-24 | Styrolution GmbH | Styrene butadiene block copolymer mixtures for shrink-wrap films |
| EP2382250B1 (de) * | 2008-12-23 | 2018-05-16 | INEOS Styrolution Europe GmbH | Phasenseparierende blockcopolymere aus unverträglichen hartblöcken und formmassen mit hoher steifigkeit |
| JP5684141B2 (ja) | 2008-12-23 | 2015-03-11 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 非親和性の硬質ブロック及び高い剛性を有する成形組成物を含む相分離ブロック又はグラフトコポリマー |
| KR20110110280A (ko) * | 2008-12-30 | 2011-10-06 | 바스프 에스이 | 폴리올레핀/스티렌 중합체 혼합물 기재의 탄성 입자 발포체 |
| WO2010076185A1 (de) * | 2008-12-30 | 2010-07-08 | Basf Se | Expandierbare, thermoplastische polymerpartikel auf basis von polyolefin/styrolpolymer-mischungen mit iso-pentan oder cyclopentan als treibmittel |
| CN102272222B (zh) | 2008-12-30 | 2013-10-16 | 巴斯夫欧洲公司 | 基于聚烯烃/苯乙烯聚合物混合物的弹性粒子泡沫 |
| WO2010100101A1 (de) * | 2009-03-05 | 2010-09-10 | Basf Se | Elastischer partikelschaumstoff auf basis von polyolefin/styrolpolymer-mischungen |
| EP2287241A1 (de) * | 2009-08-20 | 2011-02-23 | Basf Se | Dämmstoffe aus unterschiedlichen pigmentierten Partikeln |
| WO2011042405A1 (de) * | 2009-10-09 | 2011-04-14 | Basf Se | Polymermischungen von polystyrol mit styrol-butadien-blockcopolymeren |
| WO2011089130A2 (de) | 2010-01-19 | 2011-07-28 | Basf Se | Verfahren zur herstellung von hohlkörpern mit eingeschlossenen frei beweglichen partikeln |
| TWI443141B (zh) * | 2010-03-08 | 2014-07-01 | Asahi Kasei Chemicals Corp | A composition for a foam, a method for producing the same, and a foam |
| JP5603628B2 (ja) * | 2010-03-26 | 2014-10-08 | 積水化成品工業株式会社 | 発泡性ポリスチレン系樹脂粒子とその製造方法、ポリスチレン系樹脂予備発泡粒子の製造方法及びポリスチレン系樹脂発泡成形体の製造方法 |
| JP5704831B2 (ja) * | 2010-03-26 | 2015-04-22 | 積水化成品工業株式会社 | 気泡含有発泡性ポリスチレン系樹脂粒子とその製造方法、ポリスチレン系樹脂予備発泡粒子及びポリスチレン系樹脂発泡成形体の製造方法 |
| KR101477124B1 (ko) * | 2010-03-26 | 2014-12-29 | 세키스이가세이힝코교가부시키가이샤 | 발포성 폴리스티렌계 수지 입자와 그 제조 방법, 폴리스티렌계 수지 예비 발포 입자, 폴리스티렌계 수지 발포 성형체, 열가소성 수지 예비 발포 입자와 그 제조 방법, 및 열가소성 수지 발포 성형체 |
| FR2961517B1 (fr) * | 2010-06-18 | 2014-04-11 | Thermoplastiques Cousin Tessier | Composition elastomerique reticulee, et produit comprenant une telle composition |
| CN101983897A (zh) * | 2010-10-01 | 2011-03-09 | 黄祖良 | 航空托盘及其制造方法 |
| EP2452968A1 (de) | 2010-11-11 | 2012-05-16 | Basf Se | Verfahren zur Herstellung von expandierbaren thermoplastischen Partikeln mit Verbesserter Expandierbarkeit |
| EP2452969A1 (de) | 2010-11-11 | 2012-05-16 | Basf Se | Verfahren zur Herstellung von expandierbaren thermoplastischen Partikeln durch Nachimprägnierung |
| US20120121905A1 (en) * | 2010-11-11 | 2012-05-17 | Basf Se | Process for producing expandable thermoplastic beads with improved expandability |
| WO2012089574A1 (de) * | 2010-12-28 | 2012-07-05 | Basf Se | Schaumstoffplatte auf basis von styrolpolymer-polyolefin-mischungen |
| CN102286159A (zh) * | 2011-07-01 | 2011-12-21 | 广东工业大学 | 低温可膨胀石墨/聚合物发泡材料的制备方法 |
| JP5796390B2 (ja) * | 2011-07-25 | 2015-10-21 | 株式会社カネカ | 発泡性熱可塑性樹脂粒の製造方法 |
| CN103788502B (zh) * | 2012-10-29 | 2016-05-25 | 中国石油化工股份有限公司 | 一种聚丙烯发泡珠粒成型体及其制备方法 |
| ITMI20122153A1 (it) | 2012-12-17 | 2014-06-18 | Versalis Spa | Composizione polimerica espandibile a migliorata flessibilita' e relativo procedimento di preparazione |
| EP3008122B1 (de) * | 2013-06-13 | 2017-08-09 | Basf Se | Verfahren zur herstellung von expandiertem granulat |
| US9499980B2 (en) | 2013-09-16 | 2016-11-22 | National Gypsum Properties, Llc | Lightweight cementitious panel possessing high durability background |
| US9914245B2 (en) * | 2013-09-16 | 2018-03-13 | National Gypsum Properties, Llc | Controlling the embedding depth of reinforcing mesh to cementitious board |
| DE102013224275A1 (de) | 2013-11-27 | 2015-05-28 | Basf Se | Verfahren zur Herstellung von expandierbaren, thermoplastischen Polymerpartikeln mit verbessertem Treibmittelhaltevermögen |
| CN103788522A (zh) * | 2014-01-22 | 2014-05-14 | 南通市海鸥救生防护用品有限公司 | 一种泡沫组合物及其制备方法 |
| CN104592663A (zh) * | 2015-02-13 | 2015-05-06 | 芜湖市伟华泡塑有限公司 | 一种高韧性高弹性可发性聚苯乙烯及其制备方法 |
| WO2017127007A1 (en) | 2016-01-20 | 2017-07-27 | Poypeptide Laboratories Holding (Ppl) Ab | METHOD FOR PREPARATION OF PEPTIDES WITH psWANG LINKER |
| WO2017192846A1 (en) * | 2016-05-06 | 2017-11-09 | The Chemours Company Fc, Llc | Foaming of styrene polymer |
| IT201600079947A1 (it) * | 2016-07-29 | 2018-01-29 | Versalis Spa | Composizione polimerica espandibile contentente copolimeri etilen-vinilacetato |
| IT201600080035A1 (it) | 2016-07-29 | 2018-01-29 | Versalis Spa | Composizioni polimeriche espandibili a blocchi |
| KR102628067B1 (ko) | 2017-08-24 | 2024-01-23 | 에보닉 오퍼레이션스 게엠베하 | 항공기 내부에서의 적용을 위한 pei 입자 발포체 |
| WO2020058313A1 (de) * | 2018-09-21 | 2020-03-26 | Ineos Styrolution Group Gmbh | Verfahren des selektiven lasersinterns unter verwendung von thermoplastischen polymerpulvern |
| EP3853303B1 (de) * | 2018-09-21 | 2022-06-15 | INEOS Styrolution Group GmbH | Thermoplastische polymerpulver und deren anwendung für das selektive lasersintern |
| EP3670600A1 (en) * | 2018-12-21 | 2020-06-24 | Borealis AG | Improved foaming behaviour of polymer compositions using passive nucleation |
| KR102412172B1 (ko) * | 2019-10-30 | 2022-06-22 | 롯데케미칼 주식회사 | 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
| CN116783240A (zh) * | 2021-01-08 | 2023-09-19 | 株式会社钟化 | 聚丙烯系树脂发泡颗粒和聚丙烯系树脂发泡成型体 |
| CN116981553A (zh) * | 2021-03-15 | 2023-10-31 | 巴斯夫欧洲公司 | 制备膨胀热塑性弹性体颗粒的方法 |
| CN114456511B (zh) * | 2022-01-26 | 2023-07-11 | 无锡会通轻质材料股份有限公司 | 一种发泡聚烯烃珠粒及其制备方法 |
| CN114316458B (zh) * | 2022-01-26 | 2023-07-11 | 无锡会通轻质材料股份有限公司 | 一种发泡聚烯烃珠粒及其模塑制件 |
| JP7705819B2 (ja) * | 2022-03-28 | 2025-07-10 | 株式会社ジェイエスピー | 発泡粒子成形体の製造方法及び発泡粒子成形体 |
| KR102892462B1 (ko) * | 2023-03-23 | 2025-12-01 | 에이치디씨현대이피 주식회사 | 고탄성과 단열성을 동시에 갖는 층간차음재용 혼합 조성물 및 이를 이용한 발포성 스티렌 중합체 |
| CN116837687A (zh) * | 2023-07-04 | 2023-10-03 | 青岛中诚高分子科技有限公司 | 复合多相孔结构的轻质弹性地面层及其制备方法 |
| KR102765901B1 (ko) * | 2023-12-27 | 2025-02-11 | 케이엠비(주) | 시멘트계 조성물 첨가용 기능성 입자, 이를 포함하는 시멘트계 복합조성물 및 이의 제조방법 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2413375A1 (de) * | 1974-03-20 | 1975-10-23 | Basf Ag | Verfahren zur herstellung von schaumstoffen aus massen, die styrol- und aethylenpolymerisate enthalten |
| JP2795079B2 (ja) * | 1992-08-03 | 1998-09-10 | 住友化学工業株式会社 | ポリスチレン系樹脂発泡体 |
| DE4416852A1 (de) | 1994-05-13 | 1995-11-16 | Basf Ag | Expandierbare Styrolpolymerisate |
| JP2000129027A (ja) * | 1998-10-28 | 2000-05-09 | Jsp Corp | 型内形成用ポリプロピレン系樹脂発泡粒子、型内成形体及び建築用断熱材 |
| AT406477B (de) * | 1999-01-25 | 2000-05-25 | Sunpor Kunststoff Gmbh | Teilchenförmige, expandierbare styrolpolymerisate und verfahren zu ihrer herstellung |
| JP2001310968A (ja) * | 2000-04-28 | 2001-11-06 | Asahi Kasei Corp | ポリエチレン−ポリスチレン系混合樹脂押出発泡体及びその製造方法 |
| JP2003183438A (ja) * | 2001-12-25 | 2003-07-03 | Jsp Corp | 熱成形用発泡シート及び果菜容器 |
| ATE553147T1 (de) * | 2003-01-27 | 2012-04-15 | Nova Chem Inc | Aufschäumbare mischpolymerharzteilchen mit limonen als treibmittel |
| US7358282B2 (en) * | 2003-12-05 | 2008-04-15 | Kimberly-Clark Worldwide, Inc. | Low-density, open-cell, soft, flexible, thermoplastic, absorbent foam and method of making foam |
| JP2007084744A (ja) * | 2005-09-26 | 2007-04-05 | Sekisui Plastics Co Ltd | スチレン系樹脂発泡性粒子とその製造方法及びスチレン系樹脂発泡成形体 |
| CN101652416B (zh) * | 2007-04-11 | 2012-05-02 | 巴斯夫欧洲公司 | 基于聚烯烃/苯乙烯聚合物混合物的弹性粒子泡沫 |
-
2009
- 2009-03-12 PL PL09720933T patent/PL2254937T3/pl unknown
- 2009-03-12 CN CN2009801086986A patent/CN101970554B/zh not_active Expired - Fee Related
- 2009-03-12 ES ES09720933T patent/ES2391248T3/es active Active
- 2009-03-12 BR BRPI0909438A patent/BRPI0909438A2/pt not_active IP Right Cessation
- 2009-03-12 CA CA2718001A patent/CA2718001A1/en not_active Abandoned
- 2009-03-12 MY MYPI2010004064A patent/MY156035A/en unknown
- 2009-03-12 EP EP09720933A patent/EP2254937B1/de not_active Not-in-force
- 2009-03-12 JP JP2010550201A patent/JP5248630B2/ja not_active Expired - Fee Related
- 2009-03-12 US US12/921,526 patent/US20110065819A1/en not_active Abandoned
- 2009-03-12 MX MX2010009533A patent/MX2010009533A/es active IP Right Grant
- 2009-03-12 KR KR1020107022784A patent/KR101554377B1/ko not_active Expired - Fee Related
- 2009-03-12 DK DK09720933.2T patent/DK2254937T3/da active
- 2009-03-12 WO PCT/EP2009/052920 patent/WO2009112549A1/de not_active Ceased
- 2009-03-13 TW TW098108299A patent/TWI441864B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| MX2010009533A (es) | 2010-09-24 |
| EP2254937B1 (de) | 2012-09-05 |
| EP2254937A1 (de) | 2010-12-01 |
| TWI441864B (zh) | 2014-06-21 |
| MY156035A (en) | 2015-12-31 |
| KR101554377B1 (ko) | 2015-09-18 |
| JP2011529105A (ja) | 2011-12-01 |
| CN101970554B (zh) | 2013-06-05 |
| PL2254937T3 (pl) | 2013-02-28 |
| KR20100134031A (ko) | 2010-12-22 |
| US20110065819A1 (en) | 2011-03-17 |
| WO2009112549A1 (de) | 2009-09-17 |
| TW200944558A (en) | 2009-11-01 |
| CN101970554A (zh) | 2011-02-09 |
| JP5248630B2 (ja) | 2013-07-31 |
| BRPI0909438A2 (pt) | 2015-12-22 |
| DK2254937T3 (da) | 2012-12-17 |
| CA2718001A1 (en) | 2009-09-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2391248T3 (es) | Espuma moldeada elástica a base de mezclas poliméricas de poliolefina/estireno | |
| ES2358307T3 (es) | Material espumado elástico en forma de partículas, a base de mezclas poliméricas de poliolefina/estireno. | |
| US8729143B2 (en) | Elastic particle foam based on polyolefin/styrene polymer mixtures | |
| KR101869577B1 (ko) | 발포성이 개선된 발포성 열가소성 비드를 제조하는 방법 | |
| US20110269858A1 (en) | Elastic molded foam based on polyolefin/styrene polymer mixtures | |
| CN102341442B (zh) | 基于聚烯烃/苯乙烯聚合物混合物的弹性颗粒泡沫材料 | |
| US20120121905A1 (en) | Process for producing expandable thermoplastic beads with improved expandability | |
| HK1138029B (en) | Elastic particle foam based on polyolefin/styrene polymer mixtures |