ES2376079T3 - Procedimiento acuoso para la preparación de fluorpol�?meros. - Google Patents
Procedimiento acuoso para la preparación de fluorpol�?meros. Download PDFInfo
- Publication number
- ES2376079T3 ES2376079T3 ES06770939T ES06770939T ES2376079T3 ES 2376079 T3 ES2376079 T3 ES 2376079T3 ES 06770939 T ES06770939 T ES 06770939T ES 06770939 T ES06770939 T ES 06770939T ES 2376079 T3 ES2376079 T3 ES 2376079T3
- Authority
- ES
- Spain
- Prior art keywords
- fluorpolymer
- emulsifiers
- polyethylene glycol
- polypropylene glycol
- segments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 238000000034 method Methods 0.000 title claims description 21
- 238000002360 preparation method Methods 0.000 title description 4
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 41
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 35
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 34
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 29
- 229920002313 fluoropolymer Polymers 0.000 claims abstract description 10
- 239000004811 fluoropolymer Substances 0.000 claims abstract description 10
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 25
- 239000000178 monomer Substances 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 24
- 239000000839 emulsion Substances 0.000 abstract description 12
- 239000003999 initiator Substances 0.000 description 19
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 14
- 239000004816 latex Substances 0.000 description 13
- 229920000126 latex Polymers 0.000 description 13
- 229920001577 copolymer Polymers 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000001451 organic peroxides Chemical class 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- -1 sodium hydrocarbon sulfonate salt Chemical class 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- 229940029284 trichlorofluoromethane Drugs 0.000 description 2
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 description 1
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 1
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical compound CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
- MFLLXRJTHGPGEB-UHFFFAOYSA-N 1-propylperoxypropane Chemical compound CCCOOCCC MFLLXRJTHGPGEB-UHFFFAOYSA-N 0.000 description 1
- ODWNBAWYDSWOAF-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-yloxybenzene Chemical compound CC(C)(C)CC(C)(C)OC1=CC=CC=C1 ODWNBAWYDSWOAF-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 1
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- OLGGVYJRMKGTGP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-2,4-dien-6-ol Chemical group C1=CC=CC2(O)C1O2 OLGGVYJRMKGTGP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920002556 Polyethylene Glycol 300 Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- IRVTWLLMYUSKJS-UHFFFAOYSA-N carboxyoxy propyl carbonate Chemical compound CCCOC(=O)OOC(O)=O IRVTWLLMYUSKJS-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 239000007957 coemulsifier Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- ISXSFOPKZQZDAO-UHFFFAOYSA-N formaldehyde;sodium Chemical compound [Na].O=C ISXSFOPKZQZDAO-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US149797 | 1980-05-14 | ||
| US11/149,797 US20060281845A1 (en) | 2005-06-10 | 2005-06-10 | Aqueous process for making fluoropolymers |
| PCT/US2006/019894 WO2006135543A2 (en) | 2005-06-10 | 2006-05-23 | Aqueous process for making fluoropolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2376079T3 true ES2376079T3 (es) | 2012-03-08 |
Family
ID=37524922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06770939T Active ES2376079T3 (es) | 2005-06-10 | 2006-05-23 | Procedimiento acuoso para la preparación de fluorpol�?meros. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US20060281845A1 (enExample) |
| EP (1) | EP1891153B1 (enExample) |
| JP (1) | JP5112303B2 (enExample) |
| KR (1) | KR101298055B1 (enExample) |
| CN (1) | CN101223228B (enExample) |
| AT (1) | ATE535553T1 (enExample) |
| ES (1) | ES2376079T3 (enExample) |
| WO (1) | WO2006135543A2 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8338518B2 (en) * | 2005-06-10 | 2012-12-25 | Arkema Inc. | Aqueous process for making a stable fluoropolymer dispersion |
| US20080015304A1 (en) | 2006-07-13 | 2008-01-17 | Klaus Hintzer | Aqueous emulsion polymerization process for producing fluoropolymers |
| US7728087B2 (en) * | 2005-12-23 | 2010-06-01 | 3M Innovative Properties Company | Fluoropolymer dispersion and method for making the same |
| EP2274345B1 (en) * | 2008-04-07 | 2017-01-04 | Arkema Inc. | Polymerization of fluoropolymers using polycaprolactone |
| CN102549060B (zh) | 2009-07-31 | 2016-01-20 | 3M创新有限公司 | 含有多元醇化合物的含氟聚合物组合物及其制备方法 |
| EP2284200A1 (en) | 2009-07-31 | 2011-02-16 | 3M Innovative Properties Company | Aqueous fluoropolymer dispersions containing a polyol comprising at least one long chain residue and method for producing them |
| US9000069B1 (en) | 2010-07-02 | 2015-04-07 | The Sherwin-Williams Company | Self-stratifying coatings |
| EP2638083B1 (en) | 2010-11-09 | 2019-04-10 | The Chemours Company FC, LLC | Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization |
| WO2012064841A1 (en) | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Aqueous polymerization of fluoromonomer using hydrocarbon surfactant |
| CN103201301B (zh) * | 2010-11-09 | 2017-02-08 | 纳幕尔杜邦公司 | 含氟单体的含水聚合反应中的成核作用 |
| US8735520B2 (en) | 2010-11-09 | 2014-05-27 | E.I. Du Pont De Nemours And Company | Vinyl fluoride polymerization and aqueous dispersion of vinyl fluoride polymer |
| CN106414510B (zh) | 2013-11-26 | 2018-11-30 | 得凯莫斯公司弗罗里达有限公司 | 采用聚环氧烷在含氟单体的水相聚合中成核 |
| JP6722593B2 (ja) | 2014-05-19 | 2020-07-15 | アーケマ・インコーポレイテッド | 高いメルトフロー性のフルオロポリマー組成物 |
| EP3194457B1 (en) * | 2014-09-17 | 2018-11-21 | Solvay Specialty Polymers Italy S.p.A. | Vinylidene fluoride polymers |
| EP3059265B1 (en) | 2015-02-23 | 2020-10-07 | 3M Innovative Properties Company | Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers |
| EP3436524B1 (en) | 2016-04-01 | 2022-06-15 | Arkema Inc. | 3-d printed fluoropolymer structures |
| US11629249B2 (en) * | 2016-10-05 | 2023-04-18 | Solvay Specialty Polymers Italy S.P.A. | Vinylidene fluoride and trifluoroethylene containing polymers latexes |
| FR3067032B1 (fr) * | 2017-06-06 | 2021-10-01 | Arkema France | Elastomere de fluoropolymere thermoplastique |
| FR3071500B1 (fr) * | 2017-09-27 | 2020-05-15 | Arkema France | Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft |
| KR102120447B1 (ko) * | 2017-11-22 | 2020-06-09 | 한국화학연구원 | 폴리에틸렌글리콜을 이용한 폴리비닐리덴 플루오라이드 나노 입자의 제조방법 및 이에 따라 제조되는 폴리비닐리덴 플루오라이드 나노 입자 |
| US20210070897A1 (en) * | 2018-03-16 | 2021-03-11 | Arkema Inc. | High solids, surfactant-free fluoropolymer |
| EP3806190B1 (en) | 2018-05-31 | 2022-08-24 | Kureha Corporation | Resin composition for nonaqueous electrolyte secondary battery, separator for nonaqueous electrolyte secondary battery using same, resin composition for electrode mixture layer, electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery |
| CN113227167A (zh) | 2018-11-12 | 2021-08-06 | 阿科玛股份有限公司 | 用于制造含氟聚合物分散体的方法 |
| US12060479B2 (en) | 2018-12-06 | 2024-08-13 | Arkema Inc. | Fluoro-thermoplastic elastomer blends |
| US12054605B2 (en) | 2019-03-29 | 2024-08-06 | Kureha Corporation | Vinylidene fluoride-based polymer composition obtained using non-fluorinated surfactant and production method therefor |
| JP2023536649A (ja) | 2020-08-06 | 2023-08-28 | アーケマ・インコーポレイテッド | 加工可能なテトラフルオロエチレンコポリマー |
| JPWO2022071232A1 (enExample) * | 2020-09-30 | 2022-04-07 | ||
| JP2023543807A (ja) | 2020-10-01 | 2023-10-18 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロポリマーの水性重合における低反応性炭化水素分散剤 |
| CN115466343B (zh) | 2021-06-11 | 2023-10-27 | 中昊晨光化工研究院有限公司 | 一种聚醚二酸或其盐类表面活性剂及其应用 |
| EP4438632A1 (en) | 2023-03-29 | 2024-10-02 | Arkema France | Polyvinylidene fluoride for high purity water supply applications |
| EP4458869A1 (en) | 2023-05-03 | 2024-11-06 | Arkema, Inc. | Process for the production of polyvinylidene fluoride copolymers |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3037953A (en) * | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3301807A (en) | 1963-04-11 | 1967-01-31 | Thiokol Chemical Corp | Stabilized, concentrated polytetrafluoroethylene dispersions containing non-ionic surfactants |
| US3704272A (en) * | 1970-09-15 | 1972-11-28 | Du Pont | Concentration of polytetrafluoroethylene aqueous dispersion |
| US3817951A (en) * | 1972-11-20 | 1974-06-18 | Pennwalt Corp | Low-modulus thermoplastic ethylene-tetrafluoroethylene-hexafluoropropene terpolymers |
| US4342675A (en) * | 1978-06-16 | 1982-08-03 | E. I. Du Pont De Nemours And Company | Process for preparing aqueous dispersion of polytetrafluoroethylene |
| US4569978A (en) * | 1984-07-25 | 1986-02-11 | Pennwalt Corporation | Emulsion polymerization of vinylidene fluoride polymers in the presence of trichlorofluoromethane as chain transfer agent |
| US5349003A (en) * | 1988-09-20 | 1994-09-20 | Japan Synthetic Rubber Co., Ltd. | Aqueous fluorine-containing polymer dispersion and aqueous dispersion containing fluorine-containing polymer and water-soluble resin and/or water dispersible resin |
| JP3307663B2 (ja) * | 1990-10-30 | 2002-07-24 | 大日本インキ化学工業株式会社 | ゲル化微粒子状フッ素樹脂水性分散体及びその製造方法 |
| JP3172983B2 (ja) * | 1993-09-20 | 2001-06-04 | ダイキン工業株式会社 | ビニリデンフルオライド系重合体の水性分散液およびその製法 |
| JP3346090B2 (ja) * | 1995-03-31 | 2002-11-18 | ダイキン工業株式会社 | ポリテトラフルオロエチレン水性分散液組成物及びその用途 |
| US5955556A (en) * | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| US5859123A (en) * | 1995-11-15 | 1999-01-12 | Central Glass Company, Limited | Water-based fluorine-containing emulsion |
| EP1359194B1 (en) * | 1998-02-24 | 2006-10-11 | Asahi Glass Company, Limited | Polytetrafluoroethylene aqueous dispersion composition |
| JP2000128935A (ja) * | 1998-08-20 | 2000-05-09 | Asahi Glass Co Ltd | フッ素系共重合体の水性分散液 |
| US6720360B1 (en) * | 2000-02-01 | 2004-04-13 | 3M Innovative Properties Company | Ultra-clean fluoropolymers |
| US6593416B2 (en) * | 2000-02-01 | 2003-07-15 | 3M Innovative Properties Company | Fluoropolymers |
| DE10018853C2 (de) | 2000-04-14 | 2002-07-18 | Dyneon Gmbh | Herstellung wässriger Dispersionen von Fluorpolymeren |
| US6794550B2 (en) * | 2000-04-14 | 2004-09-21 | 3M Innovative Properties Company | Method of making an aqueous dispersion of fluoropolymers |
| US6512063B2 (en) * | 2000-10-04 | 2003-01-28 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers |
| EP1383811B1 (en) * | 2001-05-02 | 2009-11-25 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| US6956078B2 (en) * | 2002-01-04 | 2005-10-18 | E.I. Du Pont De Nemours And Company | Concentrated fluoropolymer dispersions |
| WO2003106556A1 (ja) * | 2002-05-20 | 2003-12-24 | ダイキン工業株式会社 | 含フッ素樹脂水性分散体組成物及び含フッ素水性塗料組成物 |
| US6734264B1 (en) * | 2002-12-16 | 2004-05-11 | Atofina Chemicals, Inc. | Chain transfer agent |
| US6841616B2 (en) * | 2003-03-28 | 2005-01-11 | Arkema Inc. | Polymerization of halogen-containing monomers using siloxane surfactant |
| EP1533325B1 (en) * | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
| US20060135716A1 (en) * | 2004-12-20 | 2006-06-22 | Ming-Hong Hung | Fluoroelastomers having low glass transition temperature |
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- 2006-05-23 JP JP2008515733A patent/JP5112303B2/ja active Active
- 2006-05-23 EP EP06770939A patent/EP1891153B1/en active Active
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| Publication number | Publication date |
|---|---|
| EP1891153A4 (en) | 2010-01-27 |
| CN101223228A (zh) | 2008-07-16 |
| US20060281845A1 (en) | 2006-12-14 |
| US8158734B2 (en) | 2012-04-17 |
| ATE535553T1 (de) | 2011-12-15 |
| CN101223228B (zh) | 2013-06-19 |
| JP2008543988A (ja) | 2008-12-04 |
| KR20080017467A (ko) | 2008-02-26 |
| WO2006135543A2 (en) | 2006-12-21 |
| KR101298055B1 (ko) | 2013-08-20 |
| EP1891153A2 (en) | 2008-02-27 |
| JP5112303B2 (ja) | 2013-01-09 |
| WO2006135543A3 (en) | 2008-01-24 |
| EP1891153B1 (en) | 2011-11-30 |
| US20070270534A1 (en) | 2007-11-22 |
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