ES2358322T5 - Catalizador de óxido de etileno - Google Patents
Catalizador de óxido de etileno Download PDFInfo
- Publication number
- ES2358322T5 ES2358322T5 ES03718116.1T ES03718116T ES2358322T5 ES 2358322 T5 ES2358322 T5 ES 2358322T5 ES 03718116 T ES03718116 T ES 03718116T ES 2358322 T5 ES2358322 T5 ES 2358322T5
- Authority
- ES
- Spain
- Prior art keywords
- vehicle
- solution
- catalyst
- silver
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/118,192 US6750173B2 (en) | 2002-04-08 | 2002-04-08 | Ethylene oxide catalyst |
| US118192 | 2002-04-08 | ||
| PCT/US2003/009794 WO2003086624A1 (en) | 2002-04-08 | 2003-04-01 | Ethylene oxide catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2358322T3 ES2358322T3 (es) | 2011-05-09 |
| ES2358322T5 true ES2358322T5 (es) | 2018-04-18 |
Family
ID=28674376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03718116.1T Expired - Lifetime ES2358322T5 (es) | 2002-04-08 | 2003-04-01 | Catalizador de óxido de etileno |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6750173B2 (https=) |
| EP (1) | EP1492619B2 (https=) |
| JP (1) | JP5089013B2 (https=) |
| KR (1) | KR100826146B1 (https=) |
| CN (1) | CN1329119C (https=) |
| AT (1) | ATE496692T1 (https=) |
| AU (1) | AU2003222129B2 (https=) |
| BR (1) | BR0309052B1 (https=) |
| CA (1) | CA2479237C (https=) |
| DE (1) | DE60335866D1 (https=) |
| ES (1) | ES2358322T5 (https=) |
| MX (1) | MXPA04009854A (https=) |
| RU (1) | RU2311958C2 (https=) |
| TW (1) | TWI323259B (https=) |
| WO (1) | WO2003086624A1 (https=) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100980123B1 (ko) * | 2002-06-28 | 2010-09-03 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 촉매 선택성을 향상시키는 방법 및 올레핀 에폭시화 방법 |
| RU2005102097A (ru) | 2002-06-28 | 2005-08-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина |
| US7348444B2 (en) * | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US6846774B2 (en) * | 2003-04-23 | 2005-01-25 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
| US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| US7250126B2 (en) * | 2004-08-11 | 2007-07-31 | Fleetguard, Inc. | Acid-neutralizing filter media |
| US7507844B2 (en) * | 2005-05-09 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides |
| US7759284B2 (en) * | 2005-05-09 | 2010-07-20 | Scientific Design Company, Inc. | Calcination in an inert gas in the presence of a small concentration of an oxidizing component |
| BRPI0611817A2 (pt) * | 2005-06-07 | 2011-12-20 | Saint Gobain Ceramics | veìculo catalisador e um processo para preparação do veìculo catalisador |
| KR101369619B1 (ko) * | 2005-06-07 | 2014-03-05 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법 |
| JP2009525848A (ja) * | 2006-02-03 | 2009-07-16 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒の処理方法、触媒、および触媒の使用 |
| WO2007123932A2 (en) * | 2006-04-18 | 2007-11-01 | Dow Global Technologies Inc. | Alkylene oxide catalyst and use thereof |
| US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| RU2009120540A (ru) * | 2006-11-01 | 2010-12-10 | Дау Глобал Текнолоджиз Инк. (Us) | Формованные пористые элементы из альфа-оксида алюминия и способы их получения |
| EP2125202A2 (en) * | 2006-11-20 | 2009-12-02 | Shell Internationale Research Maatschappij B.V. | A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst |
| AR066468A1 (es) | 2007-05-09 | 2009-08-19 | Shell Int Research | Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina |
| KR101629037B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| KR101629038B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| US7820840B2 (en) * | 2008-07-09 | 2010-10-26 | The Regents Of The University Of Michigan | Epoxidation catalyst and process |
| US8629079B2 (en) | 2011-04-14 | 2014-01-14 | Basf Se | Process for producing a catalyst for the oxidation of ethylene to ethylene oxide |
| JP5984593B2 (ja) * | 2011-09-30 | 2016-09-06 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびそれを用いたエチレンオキシドの製造方法 |
| WO2013102177A1 (en) | 2011-12-30 | 2013-07-04 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particle and method of forming same |
| EP2802436B1 (en) | 2012-01-10 | 2019-09-25 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive particles having complex shapes |
| EP2852473B1 (en) | 2012-05-23 | 2020-12-23 | Saint-Gobain Ceramics & Plastics Inc. | Shaped abrasive particles and methods of forming same |
| CN108015685B (zh) | 2012-10-15 | 2020-07-14 | 圣戈班磨料磨具有限公司 | 具有特定形状的磨粒 |
| PL2978566T3 (pl) | 2013-03-29 | 2024-07-15 | Saint-Gobain Abrasives, Inc. | Cząstki ścierne o określonych kształtach i sposoby formowania takich cząstek |
| TWI632138B (zh) | 2013-05-16 | 2018-08-11 | 科學設計股份有限公司 | 具有降低鈉含量之建基於銀之環氧乙烷觸媒 |
| TWI632954B (zh) | 2013-05-16 | 2018-08-21 | 科學設計股份有限公司 | 改善環氧乙烷觸媒的催化效能之載體處理 |
| CN104437664B (zh) * | 2013-09-16 | 2016-09-21 | 中国石油化工股份有限公司 | 一种制备α-氧化铝载体的方法 |
| KR101889698B1 (ko) | 2013-09-30 | 2018-08-21 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 형상화 연마입자 및 이의 형성 방법 |
| MX380754B (es) | 2013-12-31 | 2025-03-12 | Saint Gobain Abrasives Inc | Artículo abrasivo que incluye partículas abrasivas perfiladas. |
| US9771507B2 (en) | 2014-01-31 | 2017-09-26 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particle including dopant material and method of forming same |
| EP4306610A3 (en) | 2014-04-14 | 2024-04-03 | Saint-Gobain Ceramics and Plastics, Inc. | Abrasive article including shaped abrasive particles |
| US9914864B2 (en) | 2014-12-23 | 2018-03-13 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particles and method of forming same |
| TWI634200B (zh) | 2015-03-31 | 2018-09-01 | 聖高拜磨料有限公司 | 固定磨料物品及其形成方法 |
| CN116967949A (zh) | 2015-03-31 | 2023-10-31 | 圣戈班磨料磨具有限公司 | 固定磨料制品和其形成方法 |
| WO2016201104A1 (en) | 2015-06-11 | 2016-12-15 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
| KR102313436B1 (ko) | 2016-05-10 | 2021-10-19 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 연마 입자들 및 그 형성 방법 |
| WO2017197006A1 (en) | 2016-05-10 | 2017-11-16 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive particles and methods of forming same |
| US11123712B2 (en) | 2016-07-26 | 2021-09-21 | Research Triangle Institute | Catalysts utilizing carbon dioxide for the epoxidation of olefins |
| EP4349896A3 (en) | 2016-09-29 | 2024-06-12 | Saint-Gobain Abrasives, Inc. | Fixed abrasive articles and methods of forming same |
| BR112019011162B1 (pt) | 2016-12-02 | 2022-08-16 | Shell Internationale Research Maatschappij B.V. | Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno |
| US10563105B2 (en) | 2017-01-31 | 2020-02-18 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
| US10865148B2 (en) | 2017-06-21 | 2020-12-15 | Saint-Gobain Ceramics & Plastics, Inc. | Particulate materials and methods of forming same |
| EP4081370A4 (en) | 2019-12-27 | 2024-04-24 | Saint-Gobain Ceramics & Plastics Inc. | ABRASIVE ARTICLES AND THEIR FORMATION PROCESSES |
| KR102877276B1 (ko) | 2019-12-27 | 2025-10-28 | 세인트-고바인 세라믹스 앤드 플라스틱스, 인크. | 연마 물품 및 이의 형성 방법 |
| CN114867582B (zh) | 2019-12-27 | 2024-10-18 | 圣戈本陶瓷及塑料股份有限公司 | 磨料制品及其形成方法 |
| WO2021260138A1 (en) | 2020-06-26 | 2021-12-30 | Basf Se | Shaped catalyst body for the production of ethylene oxide |
| WO2021260140A1 (en) | 2020-06-26 | 2021-12-30 | Basf Se | Production of porous alpha-alumina supports from boehmitic derived aluminas |
| EP4171802A1 (de) | 2020-06-26 | 2023-05-03 | Basf Se | Poröser katalysatorträger-formkörper |
| CN117545552A (zh) | 2021-06-25 | 2024-02-09 | 巴斯夫欧洲公司 | 高纯度压片阿尔法氧化铝催化剂载体 |
| EP4457055A4 (en) | 2021-12-30 | 2025-12-24 | Saint Gobain Abrasives Inc | ABRASIVE ARTICLES AND THEIR FORMATION PROCESSES |
| EP4457054A4 (en) | 2021-12-30 | 2026-01-14 | Saint Gobain Abrasives Inc | ABRASIVE ARTICLES AND THEIR FORMATION PROCESSES |
| CA3241421A1 (en) | 2021-12-30 | 2023-07-06 | Anthony MARTONE | Abrasive articles and methods of forming same |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2709173A (en) * | 1950-01-09 | 1955-05-24 | California Research Corp | Oxidation of olefins and catalyst therefor |
| US2765283A (en) * | 1951-10-01 | 1956-10-02 | Jefferson Chem Co Inc | Supported silver surface catalyst and process of producing same |
| GB1170663A (en) | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
| US3563913A (en) | 1967-10-30 | 1971-02-16 | Shell Oil Co | Silver catalyst production |
| US4010115A (en) | 1972-01-07 | 1977-03-01 | Shell Oil Company | Catalyst for the oxidation of ethylene to ethylene oxide |
| US3962136A (en) | 1972-01-07 | 1976-06-08 | Shell Oil Company | Catalyst for production of ethylene oxide |
| GB1491447A (en) | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
| US4212772A (en) | 1976-05-19 | 1980-07-15 | Basf Aktiengesellschaft | Catalyst for the manufacture of ethylene oxide |
| DE2861030D1 (en) | 1977-11-19 | 1981-11-26 | Basf Ag | Process for preparing an ethylene oxide catalyst |
| DE2844402A1 (de) | 1978-10-12 | 1980-04-30 | Basf Ag | Silber enthaltende traegerkatalysatoren, verfahren zu ihrer herstellung und verfahren zur herstellung von aethylenoxid mittels dieser katalysatoren |
| DE2933950A1 (de) * | 1979-08-22 | 1981-03-12 | Basf Ag | Traegerkatalysatoren fuer die herstellung von aethylenoxid. |
| US4368144A (en) | 1980-12-22 | 1983-01-11 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Silver catalyst for production of ethylene oxide |
| JPS57180434A (en) | 1981-04-30 | 1982-11-06 | Mitsubishi Petrochem Co Ltd | Silver catalyst for production of ethylene oxide |
| DE3528313A1 (de) | 1985-08-07 | 1987-02-12 | Basf Ag | Silberkatalysator, seine herstellung und verwendung |
| JPH084745B2 (ja) | 1986-05-09 | 1996-01-24 | 三菱化学株式会社 | エチレンオキシド製造用銀触媒 |
| IL84232A (en) | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
| US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| EP0357293B1 (en) | 1988-08-30 | 1996-02-28 | Union Carbide Corporation | Catalysts for the production of ethylene oxide and their preparation processes |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5051395A (en) | 1989-09-25 | 1991-09-24 | Union Carbide Chemicals And Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or efficiency |
| US5187140A (en) † | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
| US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US6184175B1 (en) * | 1993-03-01 | 2001-02-06 | Scientic Design Company, Inc. | Process for preparing silver catalyst |
| US5447897A (en) | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
| DE69520409T3 (de) * | 1994-12-15 | 2010-02-18 | Shell Internationale Research Maatschappij B.V. | Verfahren zur Herstellung von Äthylenoxid-Katalysatoren |
| US5705661A (en) | 1995-09-25 | 1998-01-06 | Mitsubishi Chemical Corporation | Catalyst for production of ethylene oxide |
| US5801259A (en) * | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5733842A (en) † | 1996-04-30 | 1998-03-31 | Norton Checmical Process Products Corporation | Method of making porous catalyst carrier without the addition of pore forming agents |
| DE69919425T2 (de) | 1998-02-20 | 2005-09-08 | Nippon Shokubai Co. Ltd. | Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid |
| CA2343836C (en) | 1998-09-14 | 2007-12-04 | Shell Internationale Research Maatschappij B.V. | Epoxidation catalyst carrier, preparation and use thereof |
| RU2232049C2 (ru) * | 1998-09-14 | 2004-07-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ удаления ионизируемых частиц с поверхности катализатора для улучшения каталитических свойств |
| ATE391552T1 (de) | 1998-09-14 | 2008-04-15 | Shell Int Research | Verfahren zur herstellung von katalysatoren mit verbesserten katalytischen eigenschaften |
-
2002
- 2002-04-08 US US10/118,192 patent/US6750173B2/en not_active Expired - Lifetime
-
2003
- 2003-04-01 ES ES03718116.1T patent/ES2358322T5/es not_active Expired - Lifetime
- 2003-04-01 RU RU2004130467/04A patent/RU2311958C2/ru active
- 2003-04-01 CA CA2479237A patent/CA2479237C/en not_active Expired - Lifetime
- 2003-04-01 AU AU2003222129A patent/AU2003222129B2/en not_active Expired
- 2003-04-01 BR BRPI0309052-3A patent/BR0309052B1/pt active IP Right Grant
- 2003-04-01 JP JP2003583626A patent/JP5089013B2/ja not_active Expired - Fee Related
- 2003-04-01 KR KR1020047015965A patent/KR100826146B1/ko not_active Expired - Lifetime
- 2003-04-01 WO PCT/US2003/009794 patent/WO2003086624A1/en not_active Ceased
- 2003-04-01 AT AT03718116T patent/ATE496692T1/de not_active IP Right Cessation
- 2003-04-01 DE DE60335866T patent/DE60335866D1/de not_active Expired - Lifetime
- 2003-04-01 EP EP03718116.1A patent/EP1492619B2/en not_active Expired - Lifetime
- 2003-04-01 CN CNB038095629A patent/CN1329119C/zh not_active Expired - Lifetime
- 2003-04-01 MX MXPA04009854A patent/MXPA04009854A/es active IP Right Grant
- 2003-04-08 TW TW092108010A patent/TWI323259B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2479237C (en) | 2012-01-24 |
| EP1492619A4 (en) | 2009-05-27 |
| DE60335866D1 (de) | 2011-03-10 |
| RU2311958C2 (ru) | 2007-12-10 |
| TW200306309A (https=) | 2003-11-16 |
| TWI323259B (en) | 2010-04-11 |
| BR0309052B1 (pt) | 2013-05-07 |
| ES2358322T3 (es) | 2011-05-09 |
| US6750173B2 (en) | 2004-06-15 |
| US20030191019A1 (en) | 2003-10-09 |
| WO2003086624A1 (en) | 2003-10-23 |
| MXPA04009854A (es) | 2005-02-14 |
| JP5089013B2 (ja) | 2012-12-05 |
| CA2479237A1 (en) | 2003-10-23 |
| RU2004130467A (ru) | 2005-08-10 |
| EP1492619B1 (en) | 2011-01-26 |
| ATE496692T1 (de) | 2011-02-15 |
| AU2003222129A2 (en) | 2003-10-27 |
| JP2005526600A (ja) | 2005-09-08 |
| CN1649671A (zh) | 2005-08-03 |
| EP1492619A1 (en) | 2005-01-05 |
| CN1329119C (zh) | 2007-08-01 |
| EP1492619B2 (en) | 2018-02-14 |
| KR100826146B1 (ko) | 2008-04-30 |
| BR0309052A (pt) | 2005-03-29 |
| KR20040097306A (ko) | 2004-11-17 |
| AU2003222129A1 (en) | 2003-10-27 |
| AU2003222129B2 (en) | 2006-10-12 |
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