BR0309052A - Catalisador para óxido de etileno - Google Patents
Catalisador para óxido de etilenoInfo
- Publication number
- BR0309052A BR0309052A BR0309052-3A BR0309052A BR0309052A BR 0309052 A BR0309052 A BR 0309052A BR 0309052 A BR0309052 A BR 0309052A BR 0309052 A BR0309052 A BR 0309052A
- Authority
- BR
- Brazil
- Prior art keywords
- ethylene oxide
- catalyst
- sodium ions
- ions
- ppm
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"CATALISADOR PARA óXIDO DE ETILENO". A presente invenção refere-se a um catalisador para óxido de etileno composto de prata depositada em um suporte de alumina que foi tratado para remover pelo menos 25% dos íons de sódio da superfície e substituir os íons de sódio removidos com até 10 ppm de íons lítio, e à preparação do mesmo.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/118,192 US6750173B2 (en) | 2002-04-08 | 2002-04-08 | Ethylene oxide catalyst |
PCT/US2003/009794 WO2003086624A1 (en) | 2002-04-08 | 2003-04-01 | Ethylene oxide catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0309052A true BR0309052A (pt) | 2005-03-29 |
BR0309052B1 BR0309052B1 (pt) | 2013-05-07 |
Family
ID=28674376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0309052-3A BR0309052B1 (pt) | 2002-04-08 | 2003-04-01 | processo para preparaÇço de um catalisador para produÇço de àxido de etileno. |
Country Status (15)
Country | Link |
---|---|
US (1) | US6750173B2 (pt) |
EP (1) | EP1492619B2 (pt) |
JP (1) | JP5089013B2 (pt) |
KR (1) | KR100826146B1 (pt) |
CN (1) | CN1329119C (pt) |
AT (1) | ATE496692T1 (pt) |
AU (1) | AU2003222129B2 (pt) |
BR (1) | BR0309052B1 (pt) |
CA (1) | CA2479237C (pt) |
DE (1) | DE60335866D1 (pt) |
ES (1) | ES2358322T5 (pt) |
MX (1) | MXPA04009854A (pt) |
RU (1) | RU2311958C2 (pt) |
TW (1) | TWI323259B (pt) |
WO (1) | WO2003086624A1 (pt) |
Families Citing this family (48)
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CN1665797B (zh) | 2002-06-28 | 2011-09-14 | 国际壳牌研究有限公司 | 环氧化方法的开车方法和烯烃环氧化方法 |
MX256050B (es) * | 2002-06-28 | 2008-04-07 | Shell Int Research | Metodo para mejorar la selectividad de un catalizador y un proceso de epoxidacion de una olefina. |
US7348444B2 (en) * | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
US6846774B2 (en) * | 2003-04-23 | 2005-01-25 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
US7250126B2 (en) * | 2004-08-11 | 2007-07-31 | Fleetguard, Inc. | Acid-neutralizing filter media |
US7759284B2 (en) * | 2005-05-09 | 2010-07-20 | Scientific Design Company, Inc. | Calcination in an inert gas in the presence of a small concentration of an oxidizing component |
US7507844B2 (en) * | 2005-05-09 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides |
EP1890807B1 (en) | 2005-06-07 | 2019-04-03 | Shell International Research Maatschappij B.V. | A catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
EP1901842B8 (en) * | 2005-06-07 | 2019-10-30 | Saint-Gobain Ceramics & Plastics, Inc. | A catalyst carrier |
CN101410178A (zh) * | 2006-02-03 | 2009-04-15 | 国际壳牌研究有限公司 | 催化剂的处理方法,催化剂和催化剂的用途 |
TWI466718B (zh) * | 2006-04-18 | 2015-01-01 | Dow Global Technologies Llc | 環氧烷催化劑及其用途 |
US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
TWI454427B (zh) * | 2006-11-01 | 2014-10-01 | Dow Global Technologies Llc | α-氧化鋁之成形多孔體及其製備方法 |
EP2125202A2 (en) * | 2006-11-20 | 2009-12-02 | Shell Internationale Research Maatschappij B.V. | A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst |
KR20100017689A (ko) | 2007-05-09 | 2010-02-16 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 촉매, 이 촉매의 제조방법, 및 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산 방법 |
JP5868703B2 (ja) * | 2008-05-07 | 2016-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法 |
EP2297124B1 (en) * | 2008-05-07 | 2013-08-21 | Shell Internationale Research Maatschappij B.V. | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
WO2010005971A2 (en) * | 2008-07-09 | 2010-01-14 | The Regents Of The University Of Michigan | Epoxidation catalyst and process |
US8629079B2 (en) | 2011-04-14 | 2014-01-14 | Basf Se | Process for producing a catalyst for the oxidation of ethylene to ethylene oxide |
JP5984593B2 (ja) * | 2011-09-30 | 2016-09-06 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびそれを用いたエチレンオキシドの製造方法 |
EP2797715A4 (en) | 2011-12-30 | 2016-04-20 | Saint Gobain Ceramics | SHAPED ABRASIVE PARTICLE AND METHOD OF FORMING THE SAME |
JP5966019B2 (ja) | 2012-01-10 | 2016-08-10 | サン−ゴバン セラミックス アンド プラスティクス,インコーポレイティド | 複雑形状を有する研磨粒子およびその形成方法 |
CN110013795A (zh) | 2012-05-23 | 2019-07-16 | 圣戈本陶瓷及塑料股份有限公司 | 成形磨粒及其形成方法 |
US9440332B2 (en) | 2012-10-15 | 2016-09-13 | Saint-Gobain Abrasives, Inc. | Abrasive particles having particular shapes and methods of forming such particles |
CA2907372C (en) | 2013-03-29 | 2017-12-12 | Saint-Gobain Abrasives, Inc. | Abrasive particles having particular shapes and methods of forming such particles |
TWI632138B (zh) | 2013-05-16 | 2018-08-11 | 科學設計股份有限公司 | 具有降低鈉含量之建基於銀之環氧乙烷觸媒 |
TWI632954B (zh) | 2013-05-16 | 2018-08-21 | 科學設計股份有限公司 | 改善環氧乙烷觸媒的催化效能之載體處理 |
CN104437664B (zh) * | 2013-09-16 | 2016-09-21 | 中国石油化工股份有限公司 | 一种制备α-氧化铝载体的方法 |
BR112016015029B1 (pt) | 2013-12-31 | 2021-12-14 | Saint-Gobain Abrasifs | Artigo abrasivo incluindo partículas abrasivas moldadas |
US9771507B2 (en) | 2014-01-31 | 2017-09-26 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particle including dopant material and method of forming same |
MX2016013465A (es) | 2014-04-14 | 2017-02-15 | Saint-Gobain Ceram & Plastics Inc | Articulo abrasivo que incluye particulas abrasivas conformadas. |
US9914864B2 (en) | 2014-12-23 | 2018-03-13 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particles and method of forming same |
TWI634200B (zh) | 2015-03-31 | 2018-09-01 | 聖高拜磨料有限公司 | 固定磨料物品及其形成方法 |
CN107636109A (zh) | 2015-03-31 | 2018-01-26 | 圣戈班磨料磨具有限公司 | 固定磨料制品和其形成方法 |
EP3307483B1 (en) | 2015-06-11 | 2020-06-17 | Saint-Gobain Ceramics&Plastics, Inc. | Abrasive article including shaped abrasive particles |
CN109415615A (zh) | 2016-05-10 | 2019-03-01 | 圣戈本陶瓷及塑料股份有限公司 | 磨料颗粒及其形成方法 |
WO2017197002A1 (en) | 2016-05-10 | 2017-11-16 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive particles and methods of forming same |
US11123712B2 (en) | 2016-07-26 | 2021-09-21 | Research Triangle Institute | Catalysts utilizing carbon dioxide for the epoxidation of olefins |
EP4349896A3 (en) | 2016-09-29 | 2024-06-12 | Saint-Gobain Abrasives, Inc. | Fixed abrasive articles and methods of forming same |
US11801493B2 (en) | 2016-12-02 | 2023-10-31 | Shell Usa, Inc. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
US10563105B2 (en) | 2017-01-31 | 2020-02-18 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
EP3642293A4 (en) | 2017-06-21 | 2021-03-17 | Saint-Gobain Ceramics&Plastics, Inc. | PARTICULATE MATERIALS AND METHOD FOR MANUFACTURING THEREOF |
CN114867582B (zh) | 2019-12-27 | 2024-10-18 | 圣戈本陶瓷及塑料股份有限公司 | 磨料制品及其形成方法 |
WO2021260140A1 (en) | 2020-06-26 | 2021-12-30 | Basf Se | Production of porous alpha-alumina supports from boehmitic derived aluminas |
US20230256420A1 (en) | 2020-06-26 | 2023-08-17 | Basf Se | Shaped catalyst body for the production of ethylene oxide |
WO2021260185A1 (en) | 2020-06-26 | 2021-12-30 | Basf Se | Tableted alpha-alumina catalyst support |
CN117545552A (zh) | 2021-06-25 | 2024-02-09 | 巴斯夫欧洲公司 | 高纯度压片阿尔法氧化铝催化剂载体 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2709173A (en) * | 1950-01-09 | 1955-05-24 | California Research Corp | Oxidation of olefins and catalyst therefor |
US2765283A (en) * | 1951-10-01 | 1956-10-02 | Jefferson Chem Co Inc | Supported silver surface catalyst and process of producing same |
GB1170663A (en) | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
US3563913A (en) | 1967-10-30 | 1971-02-16 | Shell Oil Co | Silver catalyst production |
US4010115A (en) | 1972-01-07 | 1977-03-01 | Shell Oil Company | Catalyst for the oxidation of ethylene to ethylene oxide |
US4012425A (en) | 1972-01-07 | 1977-03-15 | Shell Oil Company | Ethylene oxide process |
GB1491447A (en) | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
US4212772A (en) | 1976-05-19 | 1980-07-15 | Basf Aktiengesellschaft | Catalyst for the manufacture of ethylene oxide |
EP0002045B1 (de) | 1977-11-19 | 1981-09-02 | BASF Aktiengesellschaft | Verfahren zur Herstellung eines Äthylenoxydkatalysators |
DE2844402A1 (de) | 1978-10-12 | 1980-04-30 | Basf Ag | Silber enthaltende traegerkatalysatoren, verfahren zu ihrer herstellung und verfahren zur herstellung von aethylenoxid mittels dieser katalysatoren |
DE2933950A1 (de) * | 1979-08-22 | 1981-03-12 | Basf Ag | Traegerkatalysatoren fuer die herstellung von aethylenoxid. |
US4368144A (en) | 1980-12-22 | 1983-01-11 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Silver catalyst for production of ethylene oxide |
JPS57180434A (en) | 1981-04-30 | 1982-11-06 | Mitsubishi Petrochem Co Ltd | Silver catalyst for production of ethylene oxide |
DE3528313A1 (de) | 1985-08-07 | 1987-02-12 | Basf Ag | Silberkatalysator, seine herstellung und verwendung |
JPH084745B2 (ja) | 1986-05-09 | 1996-01-24 | 三菱化学株式会社 | エチレンオキシド製造用銀触媒 |
IL84232A (en) | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
EP0357292A1 (en) | 1988-08-30 | 1990-03-07 | Imperial Chemical Industries Plc | Production of ethylene oxide and catalysts therefor |
US5051395A (en) | 1989-09-25 | 1991-09-24 | Union Carbide Chemicals And Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or efficiency |
US5187140A (en) † | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US6184175B1 (en) * | 1993-03-01 | 2001-02-06 | Scientic Design Company, Inc. | Process for preparing silver catalyst |
US5447897A (en) | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
DE69520409T3 (de) * | 1994-12-15 | 2010-02-18 | Shell Internationale Research Maatschappij B.V. | Verfahren zur Herstellung von Äthylenoxid-Katalysatoren |
US5705661A (en) | 1995-09-25 | 1998-01-06 | Mitsubishi Chemical Corporation | Catalyst for production of ethylene oxide |
US5733842A (en) † | 1996-04-30 | 1998-03-31 | Norton Checmical Process Products Corporation | Method of making porous catalyst carrier without the addition of pore forming agents |
US5801259A (en) * | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
DE69919425T2 (de) | 1998-02-20 | 2005-09-08 | Nippon Shokubai Co. Ltd. | Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid |
CA2343783C (en) * | 1998-09-14 | 2008-02-12 | Shell Internationale Research Maatschappij B.V. | Process for removing ionizable species from catalyst surface to improve catalytic properties |
CA2343836C (en) | 1998-09-14 | 2007-12-04 | Shell Internationale Research Maatschappij B.V. | Epoxidation catalyst carrier, preparation and use thereof |
RU2234370C2 (ru) | 1998-09-14 | 2004-08-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения катализаторов с улучшенными каталитическими свойствами |
-
2002
- 2002-04-08 US US10/118,192 patent/US6750173B2/en not_active Expired - Lifetime
-
2003
- 2003-04-01 RU RU2004130467/04A patent/RU2311958C2/ru active
- 2003-04-01 WO PCT/US2003/009794 patent/WO2003086624A1/en active Application Filing
- 2003-04-01 ES ES03718116.1T patent/ES2358322T5/es not_active Expired - Lifetime
- 2003-04-01 MX MXPA04009854A patent/MXPA04009854A/es active IP Right Grant
- 2003-04-01 DE DE60335866T patent/DE60335866D1/de not_active Expired - Lifetime
- 2003-04-01 KR KR1020047015965A patent/KR100826146B1/ko active IP Right Grant
- 2003-04-01 JP JP2003583626A patent/JP5089013B2/ja not_active Expired - Fee Related
- 2003-04-01 EP EP03718116.1A patent/EP1492619B2/en not_active Expired - Lifetime
- 2003-04-01 CN CNB038095629A patent/CN1329119C/zh not_active Expired - Lifetime
- 2003-04-01 BR BRPI0309052-3A patent/BR0309052B1/pt active IP Right Grant
- 2003-04-01 CA CA2479237A patent/CA2479237C/en not_active Expired - Lifetime
- 2003-04-01 AU AU2003222129A patent/AU2003222129B2/en not_active Expired
- 2003-04-01 AT AT03718116T patent/ATE496692T1/de not_active IP Right Cessation
- 2003-04-08 TW TW092108010A patent/TWI323259B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1492619A1 (en) | 2005-01-05 |
CN1649671A (zh) | 2005-08-03 |
EP1492619B2 (en) | 2018-02-14 |
TWI323259B (en) | 2010-04-11 |
KR100826146B1 (ko) | 2008-04-30 |
RU2311958C2 (ru) | 2007-12-10 |
TW200306309A (pt) | 2003-11-16 |
AU2003222129B2 (en) | 2006-10-12 |
DE60335866D1 (de) | 2011-03-10 |
RU2004130467A (ru) | 2005-08-10 |
KR20040097306A (ko) | 2004-11-17 |
AU2003222129A1 (en) | 2003-10-27 |
JP5089013B2 (ja) | 2012-12-05 |
ATE496692T1 (de) | 2011-02-15 |
EP1492619A4 (en) | 2009-05-27 |
JP2005526600A (ja) | 2005-09-08 |
AU2003222129A2 (en) | 2003-10-27 |
US6750173B2 (en) | 2004-06-15 |
CN1329119C (zh) | 2007-08-01 |
US20030191019A1 (en) | 2003-10-09 |
MXPA04009854A (es) | 2005-02-14 |
ES2358322T5 (es) | 2018-04-18 |
CA2479237C (en) | 2012-01-24 |
WO2003086624A1 (en) | 2003-10-23 |
BR0309052B1 (pt) | 2013-05-07 |
ES2358322T3 (es) | 2011-05-09 |
CA2479237A1 (en) | 2003-10-23 |
EP1492619B1 (en) | 2011-01-26 |
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