ES2342106T3 - Composicion catalitica para polimerizacion de olefinas. - Google Patents

Composicion catalitica para polimerizacion de olefinas. Download PDF

Info

Publication number
ES2342106T3
ES2342106T3 ES06758705T ES06758705T ES2342106T3 ES 2342106 T3 ES2342106 T3 ES 2342106T3 ES 06758705 T ES06758705 T ES 06758705T ES 06758705 T ES06758705 T ES 06758705T ES 2342106 T3 ES2342106 T3 ES 2342106T3
Authority
ES
Spain
Prior art keywords
group
carbon atoms
atoms
phenyl
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES06758705T
Other languages
English (en)
Spanish (es)
Inventor
Thorsten c/o Lummus Novolen Technology GmbH SELL
Joerg Schottek
Nicola Stefanie Paczkowski
Andreas Winter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novolen Technology Holdings CV
Original Assignee
Novolen Technology Holdings CV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novolen Technology Holdings CV filed Critical Novolen Technology Holdings CV
Application granted granted Critical
Publication of ES2342106T3 publication Critical patent/ES2342106T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
ES06758705T 2005-05-17 2006-04-27 Composicion catalitica para polimerizacion de olefinas. Active ES2342106T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US130925 1993-10-04
US11/130,925 US7232869B2 (en) 2005-05-17 2005-05-17 Catalyst composition for olefin polymerization

Publications (1)

Publication Number Publication Date
ES2342106T3 true ES2342106T3 (es) 2010-07-01

Family

ID=36829739

Family Applications (1)

Application Number Title Priority Date Filing Date
ES06758705T Active ES2342106T3 (es) 2005-05-17 2006-04-27 Composicion catalitica para polimerizacion de olefinas.

Country Status (11)

Country Link
US (2) US7232869B2 (US07468416-20081223-C00005.png)
EP (1) EP1882000B1 (US07468416-20081223-C00005.png)
JP (1) JP2008545821A (US07468416-20081223-C00005.png)
KR (1) KR101190758B1 (US07468416-20081223-C00005.png)
CN (1) CN101384624B (US07468416-20081223-C00005.png)
AT (1) ATE462731T1 (US07468416-20081223-C00005.png)
BR (1) BRPI0610163A2 (US07468416-20081223-C00005.png)
DE (1) DE602006013300D1 (US07468416-20081223-C00005.png)
ES (1) ES2342106T3 (US07468416-20081223-C00005.png)
TW (1) TW200710110A (US07468416-20081223-C00005.png)
WO (1) WO2006124231A1 (US07468416-20081223-C00005.png)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
PT2099832T (pt) 2006-12-14 2019-06-27 Grace W R & Co Ativadores de catalisador, processos para preparação dos mesmos, e sua utilização em catalisadores e polimerização de olefinas
KR101278336B1 (ko) * 2007-10-25 2013-06-25 루머스 노보렌 테크놀로지 게엠베하 안사-메탈로센 화합물의 라세모선택적 합성, 안사-메탈로센 화합물, 이를 포함하는 촉매, 그 촉매를 이용한 올레핀 폴리머 제조 공정, 그리고 올레핀 호모- 및 코폴리머
WO2010077230A1 (en) * 2008-12-31 2010-07-08 Lummus Novolen Technology Gmbh New metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
US8299287B2 (en) * 2007-10-25 2012-10-30 Lammus Novolen Technology GmbH Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
EP2172493A1 (en) 2008-10-02 2010-04-07 Total Petrochemicals Research Feluy Activating supports based on perfluorinated boronic acids
EP2633104A1 (en) 2010-10-28 2013-09-04 Lummus Novolen Technology Gmbh Nonwoven and yarn polypropylene with additivation
WO2012071205A2 (en) * 2010-11-22 2012-05-31 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
WO2013118140A2 (en) * 2012-02-08 2013-08-15 Reliance Industries Ltd Immobilization of single site catalyst on inorganic oxide support for preparation of uhmwpe
US9284386B2 (en) 2012-05-08 2016-03-15 Lg Chem, Ltd. Ansa-metallocene compound and method for preparing supported catalyst using the same
KR101584350B1 (ko) * 2013-04-08 2016-01-13 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
FR3039431B1 (fr) * 2015-07-29 2019-05-31 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines
FR3042989A1 (fr) * 2015-10-30 2017-05-05 Ifp Energies Now Nouvelle composition catalytique a base de nickel en presence d'un activateur specifique et son utilisation dans un procede d'oligomerisation des olefines
FR3045414B1 (fr) * 2015-12-18 2019-12-27 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
CN108786918B (zh) * 2017-05-05 2020-07-24 中国石油化工股份有限公司 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法
CN108786919B (zh) * 2017-05-05 2020-07-21 中国石油化工股份有限公司 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
SG11202001743RA (en) 2017-10-31 2020-05-28 Exxonmobil Chemical Patents Inc Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
KR102301666B1 (ko) * 2017-12-22 2021-09-14 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조 방법, 상기 제조 방법으로 제조된 혼성 담지 메탈로센 촉매, 및 이를 이용하는 폴리올레핀의 제조 방법
KR102431269B1 (ko) 2018-11-02 2022-08-10 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
US11866522B2 (en) 2018-12-28 2024-01-09 Braskem S.A. Process for introducing catalyst in a polymerization process
US11352375B2 (en) 2018-12-28 2022-06-07 Braskem S.A. Auxiliaries for olefin polymerization process
CN115368490B (zh) * 2021-05-20 2023-11-28 中国科学技术大学 硼烷助催化剂、合成方法及其应用

Family Cites Families (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
DE3508887A1 (de) 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
EP0284708B1 (en) 1987-04-03 1996-01-31 Fina Technology, Inc. Metallocene catalyst systems for olefin polymerization having a silicon hydrocarbyl bridge.
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3808268A1 (de) 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3907964A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
EP0485823B1 (de) 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
US5243001A (en) 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
US5239022A (en) 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
EP0485821B1 (de) 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
TW300901B (US07468416-20081223-C00005.png) 1991-08-26 1997-03-21 Hoechst Ag
DE59210001D1 (de) 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
TW309523B (US07468416-20081223-C00005.png) 1991-11-30 1997-07-01 Hoechst Ag
DE59206948D1 (de) 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
TW318184B (US07468416-20081223-C00005.png) 1991-11-30 1997-10-21 Hoechst Ag
US5932669A (en) 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
ATE162529T1 (de) 1992-06-13 1998-02-15 Hoechst Ag Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl
TW294669B (US07468416-20081223-C00005.png) 1992-06-27 1997-01-01 Hoechst Ag
ES2128371T3 (es) 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
JP3307704B2 (ja) 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
DE69431222T2 (de) 1993-06-07 2003-04-17 Mitsui Chemicals Inc Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
CA2125247C (en) 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
JP3423378B2 (ja) 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
DE4344689A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
PL182074B1 (en) 1994-06-24 2001-11-30 Exxon Chemical Patents Inc Catalytic systems for polymerisation processes, their production and application
US6140432A (en) 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6124230A (en) 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US5635437A (en) 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US5678812A (en) * 1996-02-14 1997-10-21 R. R. Donnelley & Sons Company Bindery apparatus with gathering conveyors and a method of make-ready
WO1997048735A1 (en) 1996-06-17 1997-12-24 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
DE69738304T2 (de) 1996-12-09 2008-09-18 Mitsubishi Chemical Corp. Katalysator zur Alpha-Olefinpolymerisation
US6255515B1 (en) 1997-01-21 2001-07-03 Mitsubishi Chemical Corporation Processes for producing silicon- or germanium-containing organic compound, transition metal complex, catalyst for polymerization of α-olefin and α-olefin polymer
DE19757563A1 (de) 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
KR100532265B1 (ko) 1997-06-05 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 중합체 지지 촉매
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
JP4116148B2 (ja) 1998-06-08 2008-07-09 三菱化学株式会社 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法
DE19903306A1 (de) 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
DE19962814A1 (de) * 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
PL199958B1 (pl) 1999-12-23 2008-11-28 Basell Polyolefine Gmbh Metalocen, układ katalityczny zawierający co najmniej jeden matalocen, zastosowanie układu katalicznego oraz homo- lub kopolimery propylenu
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
SG96700A1 (en) * 2001-09-27 2003-06-16 Sumitomo Chemical Co Catalyst component for addition polymerization, process for producing catalyst for addition polymerization and process for producing addition polymer
BR0312643A (pt) * 2002-07-15 2005-04-19 Basell Polyolefine Gmbh Processo para preparar um catalisador para a polimerização de olefina, uso de um catalisador, catalisador, e, processo para a polimerização de olefinas
WO2004007570A2 (en) * 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of supported catalyst systems
SG130016A1 (en) * 2002-09-24 2007-03-20 Sumitomo Chemical Co Modified particle, catalyst component for addition polymerization, catalyst for addition polymerization and process for producing addition polymer
US7592402B2 (en) 2004-04-30 2009-09-22 Sumitomo Chemical Company, Limited Process for producing modified particle; carrier; catalyst component for addition polymerization; process for producing catalyst for addition polymerization; and process for producing addition polymer

Also Published As

Publication number Publication date
JP2008545821A (ja) 2008-12-18
US20060264587A1 (en) 2006-11-23
CN101384624B (zh) 2012-07-04
KR101190758B1 (ko) 2012-10-12
BRPI0610163A2 (pt) 2010-06-01
EP1882000B1 (en) 2010-03-31
WO2006124231A1 (en) 2006-11-23
KR20080033906A (ko) 2008-04-17
US20070249799A1 (en) 2007-10-25
ATE462731T1 (de) 2010-04-15
DE602006013300D1 (de) 2010-05-12
EP1882000A1 (en) 2008-01-30
US7468416B2 (en) 2008-12-23
TW200710110A (en) 2007-03-16
US7232869B2 (en) 2007-06-19
CN101384624A (zh) 2009-03-11

Similar Documents

Publication Publication Date Title
ES2342106T3 (es) Composicion catalitica para polimerizacion de olefinas.
ES2225280T3 (es) Sistema catalizador nuevo y su empleo.
US7169864B2 (en) Metallocene catalysts, their synthesis and their use for the polymerization of olefins
JP4465107B2 (ja) 触媒組成物
JP4105783B2 (ja) 担持された触媒システム、その調製方法、及びオレフィンを重合させるための前記触媒システムの使用
US6444606B1 (en) Supported catalyst system, method for the production and use thereof in olefin polymerization
JP4239136B2 (ja) メタロセン触媒の調製法
ES2203714T3 (es) Sistema de catalizador soportado, procedimiento para su produccion y su utilizacion para la polimerizacion de olefinas.
JP3582181B2 (ja) オレフィン重合触媒用担体、オレフィン重合触媒及びオレフィン重合体の製造方法
ES2289755T3 (es) Compuesto quimico, constituido de manera neutra o ionica, adecuado como componente de catalizador para la polimerizacion de olefinas.
KR20070012412A (ko) 메탈로센 리간드, 메탈로센 화합물 및 메탈로센 촉매,그들의 합성 방법 및 올레핀 중합을 위한 용도
JPH09502222A (ja) エチレンコポリマー、エチレンベースポリマーの製造法及びそれに使用される触媒系
US5780562A (en) Olefin polymerization catalyst and polyolefin
CA2206971A1 (en) Supported catalyst system, process for its preparation and its use for the polymerization of olefins
EP0694563B1 (en) Olefin polymerization catalyst and process for preparing polyolefins
JP2005008711A (ja) 超高分子量オレフィン系重合体の製造方法
ES2197933T3 (es) Sistema catalizador soportado, procedimiento para su fabricacion y su utilizacion para la polimerizacion de olefinas.
KR20100006307A (ko) 올레핀 중합 촉매 및 이를 이용한 폴리올레핀 중합체의중합방법
JPH0912622A (ja) オレフィン重合体製造用触媒およびオレフィン重合体の製造方法
JPH08291202A (ja) オレフィン重合体製造用触媒およびオレフィン重合体の製造方法