ES2331235T3 - Empleo de un silano con funcionalidad de isocianato como aditivo promotor de la adherencia en pegamentos termofusibles de poliuretano. - Google Patents
Empleo de un silano con funcionalidad de isocianato como aditivo promotor de la adherencia en pegamentos termofusibles de poliuretano. Download PDFInfo
- Publication number
- ES2331235T3 ES2331235T3 ES02787933T ES02787933T ES2331235T3 ES 2331235 T3 ES2331235 T3 ES 2331235T3 ES 02787933 T ES02787933 T ES 02787933T ES 02787933 T ES02787933 T ES 02787933T ES 2331235 T3 ES2331235 T3 ES 2331235T3
- Authority
- ES
- Spain
- Prior art keywords
- functionality
- silane
- polyurethane
- isocyanate
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004814 polyurethane Substances 0.000 title claims abstract description 23
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 23
- 239000000654 additive Substances 0.000 title claims description 7
- 230000000996 additive effect Effects 0.000 title claims description 4
- 230000001737 promoting effect Effects 0.000 title description 5
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 17
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 17
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 7
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 7
- 229910000077 silane Inorganic materials 0.000 claims description 23
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 19
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 17
- 239000012948 isocyanate Substances 0.000 claims description 14
- 150000002513 isocyanates Chemical class 0.000 claims description 14
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 13
- 125000005442 diisocyanate group Chemical group 0.000 claims description 10
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 10
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 5
- 239000004831 Hot glue Substances 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 4
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 150000004072 triols Chemical class 0.000 claims description 2
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 claims 2
- 150000004756 silanes Chemical class 0.000 abstract description 17
- 239000013466 adhesive and sealant Substances 0.000 abstract 1
- 239000003292 glue Substances 0.000 description 25
- 239000000203 mixture Substances 0.000 description 21
- 239000012943 hotmelt Substances 0.000 description 17
- 239000005058 Isophorone diisocyanate Substances 0.000 description 11
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- -1 alkoxy silanes Chemical class 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- 230000004927 fusion Effects 0.000 description 5
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- RWLDCNACDPTRMY-UHFFFAOYSA-N 3-triethoxysilyl-n-(3-triethoxysilylpropyl)propan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCNCCC[Si](OCC)(OCC)OCC RWLDCNACDPTRMY-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical group [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- XCOASYLMDUQBHW-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)butan-1-amine Chemical compound CCCCNCCC[Si](OC)(OC)OC XCOASYLMDUQBHW-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000004588 polyurethane sealant Substances 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- QKOWXXDOHMJOMQ-UHFFFAOYSA-N 1,3,5-tris(6-isocyanatohexyl)biuret Chemical compound O=C=NCCCCCCNC(=O)N(CCCCCCN=C=O)C(=O)NCCCCCCN=C=O QKOWXXDOHMJOMQ-UHFFFAOYSA-N 0.000 description 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- FMGBDYLOANULLW-UHFFFAOYSA-N 3-isocyanatopropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCN=C=O FMGBDYLOANULLW-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004823 Reactive adhesive Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 208000030603 inherited susceptibility to asthma Diseases 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 125000003588 lysine group Chemical group [H]N([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- KFOZMMAXUUCIKU-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)butan-1-amine Chemical compound CCCCNCCC[Si](OCC)(OCC)OCC KFOZMMAXUUCIKU-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/809—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/20—Compositions for hot melt adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2190/00—Compositions for sealing or packing joints
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
- Sealing Material Composition (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10162642A DE10162642A1 (de) | 2001-12-20 | 2001-12-20 | Haftvermittler für reaktive Polyurethane |
| DE10162642 | 2001-12-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2331235T3 true ES2331235T3 (es) | 2009-12-28 |
Family
ID=7709954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02787933T Expired - Lifetime ES2331235T3 (es) | 2001-12-20 | 2002-12-11 | Empleo de un silano con funcionalidad de isocianato como aditivo promotor de la adherencia en pegamentos termofusibles de poliuretano. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20050032974A1 (https=) |
| EP (1) | EP1456274B1 (https=) |
| JP (1) | JP4159472B2 (https=) |
| AT (1) | ATE444322T1 (https=) |
| AU (1) | AU2002352240A1 (https=) |
| DE (2) | DE10162642A1 (https=) |
| ES (1) | ES2331235T3 (https=) |
| WO (1) | WO2003054049A1 (https=) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10229519A1 (de) * | 2001-07-10 | 2003-01-30 | Henkel Kgaa | Reaktive Polyurethane mit einem geringen Gehalt an monomeren Diisocyanaten |
| EP1502927A1 (de) * | 2003-07-31 | 2005-02-02 | Sika Technology AG | Isocyanatfreie Primerzusammensetzung für Glas und Glaskeramiken |
| DE102004038274A1 (de) * | 2004-08-06 | 2006-03-16 | Henkel Kgaa | Bindemittel mit Barriere-Eigenschaften II |
| EP1801138A1 (de) * | 2005-12-23 | 2007-06-27 | Sika Technology AG | Feuchtigkeitshärtende Heissschmelzklebstoffe umfassend mindestens ein silanfunktionelles Polyurethanprepolymer |
| WO2007088126A2 (de) * | 2006-02-03 | 2007-08-09 | Basf Se | Durch energieeintrag reparable beschichtungen |
| US7989528B2 (en) | 2007-02-23 | 2011-08-02 | Nv Bekaert Sa | Coupling agent to provide the coupling of a metal element to a material to be reinforced |
| DE102007032666A1 (de) | 2007-07-13 | 2009-01-22 | Bayer Materialscience Ag | Allophanat- und Silangruppen enthaltende Polyisocyanate |
| EP2254959B1 (en) * | 2008-02-21 | 2016-02-10 | SABMiller International Brands Limited | A coating composition for strengthening glass |
| DE102009016173A1 (de) | 2009-04-03 | 2010-10-14 | Bayer Materialscience Ag | Schutzlack |
| DE102009019899A1 (de) | 2009-05-04 | 2010-11-11 | Fischerwerke Gmbh & Co. Kg | Klebstoffe auf Basis silanterminierter Isocyanate |
| DE102009047964A1 (de) | 2009-10-01 | 2011-04-21 | Bayer Materialscience Ag | Hochfunktionelle Allophanat- und Silangruppen enthaltende Polyisocyanate |
| DE102010060443A1 (de) | 2010-11-09 | 2012-05-10 | Fischerwerke Gmbh & Co. Kg | Harz für Kleb- und Beschichtungsstoffe auf Basis silanterminierter Harze mit mindestens zwei Edukten |
| WO2012064971A1 (en) * | 2010-11-11 | 2012-05-18 | Dow Global Technologies Llc | Polyurethane based insulated glass sealant |
| EP3119827B1 (de) * | 2014-03-17 | 2020-05-06 | Henkel AG & Co. KGaA | Polyurethan-klebstoff mit epoxidgruppen |
| US10179830B2 (en) | 2014-06-13 | 2019-01-15 | Covestro Deutschland Ag | Thioallophanate polyisocyanates containing silane groups |
| CN107406572B (zh) | 2015-03-17 | 2020-06-30 | 科思创德国股份有限公司 | 含有硅烷基团并且基于1,5-二异氰酸根合戊烷的多异氰酸酯 |
| JP7372263B2 (ja) * | 2018-04-30 | 2023-10-31 | ダウ グローバル テクノロジーズ エルエルシー | イソシアネート末端シランに基づく二成分接着剤組成物、およびそれを作製するための方法 |
| KR101932244B1 (ko) * | 2018-08-03 | 2019-03-20 | 성호정 | 폴리우레탄 도막 방수제, 그 제조방법 및 이를 이용한 방수공법 |
| WO2020225310A1 (en) | 2019-05-06 | 2020-11-12 | Basf Coatings Gmbh | Silane-based coating composition |
| WO2021094130A1 (en) | 2019-11-15 | 2021-05-20 | Basf Coatings Gmbh | Silane-based coating compositions comprising a metal alkoxide catalyst |
| AU2021246184A1 (en) | 2020-04-02 | 2022-10-20 | Basf Coatings Gmbh | Silane-based coating compositions comprising a metal alkoxide catalyst and an acid-functional polymer |
| CA3216610A1 (en) | 2021-04-28 | 2022-11-03 | Jonas DEMPFLE | Isocyanate-functionalized organosilanes as adhesion promoters in sealant and primer compositions |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1088696A (en) * | 1974-09-17 | 1980-10-28 | Nicholas J. Gervase | Isocyanto-functional organo silanes and adhesives therefrom |
| US4031120A (en) * | 1974-09-17 | 1977-06-21 | Lord Corporation | Isocyanatosilane adducts |
| US4052943A (en) * | 1976-09-16 | 1977-10-11 | The United States Of America As Represented By The Secretary Of The Navy | Coating composition and method for improving propellant tear strength |
| DE3220865C2 (de) * | 1982-06-03 | 1984-08-02 | Dynamit Nobel Ag, 5210 Troisdorf | Haftkleber auf der Basis von hydroxylgruppenhaltigen Polymermischungen |
| US4539345A (en) * | 1985-02-04 | 1985-09-03 | Minnesota Mining And Manufacturing Company | Moisture-curable polyurethane composition |
| US4625012A (en) * | 1985-08-26 | 1986-11-25 | Essex Specialty Products, Inc. | Moisture curable polyurethane polymers |
| US4687533A (en) * | 1985-08-26 | 1987-08-18 | Essex Specialty Products, Inc. | Bonding method employing moisture curable polyurethane polymers |
| DE3633777C2 (de) * | 1985-10-03 | 1996-08-22 | Mitsubishi Gas Chemical Co | Hot-melt-Kleberzusammensetzung |
| US4640868A (en) * | 1986-02-10 | 1987-02-03 | Morton Thiokol Inc. | Clear, weather resistant adherent coating |
| JP2772002B2 (ja) * | 1988-11-28 | 1998-07-02 | サンスター技研株式会社 | プライマー組成物 |
| US5155201A (en) * | 1989-07-13 | 1992-10-13 | Akzo N.V. | Polyurethane polyols and high solids coatings therefrom |
| DE4114220A1 (de) * | 1991-05-01 | 1992-11-05 | Bayer Ag | Durch feuchtigkeit haertbare, nco-polyurethan-schmelzklebstoff-zusammensetzung |
| CA2144530C (en) * | 1992-10-13 | 2005-07-26 | Wen Bin Chiao | Polyurethane sealant compositions |
| JPH10114813A (ja) * | 1997-09-01 | 1998-05-06 | Mitsui Chem Inc | 一液型ウレタン樹脂組成物 |
| JP3263034B2 (ja) * | 1997-11-12 | 2002-03-04 | 横浜ゴム株式会社 | ポリウレタン組成物 |
| DE19855999A1 (de) * | 1998-12-04 | 2000-06-15 | Bayer Ag | Alkoxysilanhaltige Lackzubereitung |
| DE10013628A1 (de) * | 2000-03-18 | 2001-09-20 | Degussa | Stabile 1:1-Monoaddukte aus sekundären Aminoalkylalkoxysilanen und Diisocyanaten sowie ein Verfahren zu ihrer Herstellung |
| DE10048615A1 (de) * | 2000-09-30 | 2002-04-11 | Degussa | Nichtwäßriges, wärmehärtendes Zweikomponenten-Beschichtungsmittel |
-
2001
- 2001-12-20 DE DE10162642A patent/DE10162642A1/de not_active Ceased
-
2002
- 2002-12-11 WO PCT/EP2002/014057 patent/WO2003054049A1/de not_active Ceased
- 2002-12-11 AT AT02787933T patent/ATE444322T1/de not_active IP Right Cessation
- 2002-12-11 ES ES02787933T patent/ES2331235T3/es not_active Expired - Lifetime
- 2002-12-11 DE DE50213893T patent/DE50213893D1/de not_active Expired - Lifetime
- 2002-12-11 AU AU2002352240A patent/AU2002352240A1/en not_active Abandoned
- 2002-12-11 EP EP02787933A patent/EP1456274B1/de not_active Expired - Lifetime
- 2002-12-11 JP JP2003554762A patent/JP4159472B2/ja not_active Expired - Fee Related
-
2004
- 2004-06-17 US US10/870,344 patent/US20050032974A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP4159472B2 (ja) | 2008-10-01 |
| AU2002352240A1 (en) | 2003-07-09 |
| ATE444322T1 (de) | 2009-10-15 |
| JP2005513217A (ja) | 2005-05-12 |
| WO2003054049A1 (de) | 2003-07-03 |
| DE50213893D1 (de) | 2009-11-12 |
| EP1456274B1 (de) | 2009-09-30 |
| EP1456274A1 (de) | 2004-09-15 |
| DE10162642A1 (de) | 2003-07-10 |
| US20050032974A1 (en) | 2005-02-10 |
Similar Documents
| Publication | Publication Date | Title |
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