ES2320365T3 - Mezclas de copolimeros bloque de estireno-butadieno para laminas retractiles. - Google Patents
Mezclas de copolimeros bloque de estireno-butadieno para laminas retractiles. Download PDFInfo
- Publication number
- ES2320365T3 ES2320365T3 ES05849213T ES05849213T ES2320365T3 ES 2320365 T3 ES2320365 T3 ES 2320365T3 ES 05849213 T ES05849213 T ES 05849213T ES 05849213 T ES05849213 T ES 05849213T ES 2320365 T3 ES2320365 T3 ES 2320365T3
- Authority
- ES
- Spain
- Prior art keywords
- block
- copolymer
- weight
- blocks
- mixture according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 50
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 229920003048 styrene butadiene rubber Polymers 0.000 title description 8
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 title description 7
- 239000002174 Styrene-butadiene Substances 0.000 title description 6
- 239000011115 styrene butadiene Substances 0.000 title description 6
- 229920001400 block copolymer Polymers 0.000 claims abstract description 32
- 239000000178 monomer Substances 0.000 claims abstract description 26
- 150000001993 dienes Chemical class 0.000 claims abstract description 14
- 239000004793 Polystyrene Substances 0.000 claims abstract description 9
- 230000009477 glass transition Effects 0.000 claims abstract description 9
- 229920002223 polystyrene Polymers 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000004014 plasticizer Substances 0.000 abstract description 2
- 229920006300 shrink film Polymers 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 13
- 230000008602 contraction Effects 0.000 description 9
- 239000003999 initiator Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 3
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 3
- 238000004455 differential thermal analysis Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MJYQFWSXKFLTAY-OVEQLNGDSA-N (2r,3r)-2,3-bis[(4-hydroxy-3-methoxyphenyl)methyl]butane-1,4-diol;(2r,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O.C1=C(O)C(OC)=CC(C[C@@H](CO)[C@H](CO)CC=2C=C(OC)C(O)=CC=2)=C1 MJYQFWSXKFLTAY-OVEQLNGDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 235000004426 flaxseed Nutrition 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005001637 | 2005-01-12 | ||
| DE102005001637A DE102005001637A1 (de) | 2005-01-12 | 2005-01-12 | Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2320365T3 true ES2320365T3 (es) | 2009-05-21 |
Family
ID=36035706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES05849213T Active ES2320365T3 (es) | 2005-01-12 | 2005-12-31 | Mezclas de copolimeros bloque de estireno-butadieno para laminas retractiles. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9090768B2 (enExample) |
| EP (1) | EP1838781B1 (enExample) |
| JP (1) | JP4959581B2 (enExample) |
| KR (1) | KR101235976B1 (enExample) |
| CN (1) | CN101098929B (enExample) |
| AT (1) | ATE423168T1 (enExample) |
| BR (1) | BRPI0519833A2 (enExample) |
| CA (1) | CA2591623C (enExample) |
| DE (2) | DE102005001637A1 (enExample) |
| ES (1) | ES2320365T3 (enExample) |
| MX (1) | MX2007008271A (enExample) |
| PL (1) | PL1838781T3 (enExample) |
| WO (1) | WO2006074819A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4911913B2 (ja) * | 2005-04-14 | 2012-04-04 | 旭化成ケミカルズ株式会社 | 共重合体組成物及びそのフィルム |
| US8545953B2 (en) * | 2007-02-28 | 2013-10-01 | Styrolution GmbH | Hollow polystyrene body obtained by injection stretch blow moulding |
| KR101442292B1 (ko) * | 2007-03-28 | 2014-09-19 | 덴끼 가가꾸 고교 가부시키가이샤 | Ｍｄ 슈링크용 성형 재료 및 ｍｄ 슈링크 필름 |
| DK2152770T3 (da) * | 2007-05-23 | 2011-02-07 | Basf Se | Isotactic polystyrene having reactive groups |
| WO2009007358A1 (en) | 2007-07-10 | 2009-01-15 | Basf Se | Flame retardant thermoplastic molding compositions |
| CN101855291B (zh) * | 2007-09-14 | 2012-09-19 | 巴斯夫欧洲公司 | 模塑组合物、其用途及由其制造的集成电路管状包装 |
| US7923391B2 (en) | 2007-10-16 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Nonwoven web material containing crosslinked elastic component formed from a pentablock copolymer |
| US8399368B2 (en) | 2007-10-16 | 2013-03-19 | Kimberly-Clark Worldwide, Inc. | Nonwoven web material containing a crosslinked elastic component formed from a linear block copolymer |
| US8349963B2 (en) | 2007-10-16 | 2013-01-08 | Kimberly-Clark Worldwide, Inc. | Crosslinked elastic material formed from a linear block copolymer |
| US7923392B2 (en) | 2007-10-16 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Crosslinked elastic material formed from a branched block copolymer |
| CA2727152C (en) * | 2008-06-27 | 2016-05-17 | Basf Se | Styrene butadiene block copolymer mixtures for shrink-wrap films |
| JP5684141B2 (ja) * | 2008-12-23 | 2015-03-11 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 非親和性の硬質ブロック及び高い剛性を有する成形組成物を含む相分離ブロック又はグラフトコポリマー |
| US20110226723A1 (en) * | 2010-03-17 | 2011-09-22 | Basf Se | Hollow body with improved barrier action |
| WO2011113781A1 (de) | 2010-03-17 | 2011-09-22 | Basf Se | Hohlkörper mit verbesserter barrierewirkung |
| CN106604817B (zh) * | 2014-08-29 | 2020-03-03 | 郡是株式会社 | 热收缩性多层膜和热收缩性标签 |
| MX2019006344A (es) * | 2016-12-23 | 2019-11-07 | Ineos Styrolution Group Gmbh | Composiciones de polimeros para peliculas de envoltura retractil. |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG55445A1 (en) * | 1997-01-07 | 1998-12-21 | Denki Kagaku Kogyo Kabushili K | Block copolymer block copolymer compostion and heat shrinkable films made thereof |
| DE19810141A1 (de) * | 1998-03-10 | 1999-09-16 | Basf Ag | Polymermischungen aus Styrolpolymeren |
| DE19914075A1 (de) * | 1999-03-27 | 2000-09-28 | Basf Ag | Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren |
| DE10158500A1 (de) * | 2001-11-28 | 2003-06-12 | Basf Ag | Transparente Styrol-Butadien-Blockcopolymermischungen |
| ATE478902T1 (de) * | 2002-04-25 | 2010-09-15 | Asahi Kasei Chemicals Corp | Blockcopolymer und zusammensetzung davon |
| JP2004018800A (ja) | 2002-06-20 | 2004-01-22 | Denki Kagaku Kogyo Kk | 熱可塑性樹脂シート |
| TWI287031B (en) | 2003-05-28 | 2007-09-21 | Nippon Catalytic Chem Ind | Aqueous resin composition and its uses |
-
2005
- 2005-01-12 DE DE102005001637A patent/DE102005001637A1/de not_active Withdrawn
- 2005-12-31 US US11/813,742 patent/US9090768B2/en not_active Expired - Fee Related
- 2005-12-31 EP EP05849213A patent/EP1838781B1/de not_active Not-in-force
- 2005-12-31 BR BRPI0519833-0A patent/BRPI0519833A2/pt active Search and Examination
- 2005-12-31 CA CA2591623A patent/CA2591623C/en not_active Expired - Fee Related
- 2005-12-31 ES ES05849213T patent/ES2320365T3/es active Active
- 2005-12-31 DE DE502005006672T patent/DE502005006672D1/de active Active
- 2005-12-31 WO PCT/EP2005/014166 patent/WO2006074819A1/de not_active Ceased
- 2005-12-31 AT AT05849213T patent/ATE423168T1/de not_active IP Right Cessation
- 2005-12-31 MX MX2007008271A patent/MX2007008271A/es active IP Right Grant
- 2005-12-31 PL PL05849213T patent/PL1838781T3/pl unknown
- 2005-12-31 KR KR1020077018356A patent/KR101235976B1/ko not_active Expired - Fee Related
- 2005-12-31 JP JP2007550717A patent/JP4959581B2/ja not_active Expired - Fee Related
- 2005-12-31 CN CN2005800465239A patent/CN101098929B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US9090768B2 (en) | 2015-07-28 |
| WO2006074819A1 (de) | 2006-07-20 |
| US20080269414A1 (en) | 2008-10-30 |
| CN101098929B (zh) | 2011-01-19 |
| JP4959581B2 (ja) | 2012-06-27 |
| BRPI0519833A2 (pt) | 2009-03-17 |
| CA2591623C (en) | 2013-05-07 |
| KR20070114125A (ko) | 2007-11-29 |
| DE102005001637A1 (de) | 2006-07-20 |
| CN101098929A (zh) | 2008-01-02 |
| PL1838781T3 (pl) | 2009-07-31 |
| ATE423168T1 (de) | 2009-03-15 |
| KR101235976B1 (ko) | 2013-02-21 |
| EP1838781B1 (de) | 2009-02-18 |
| DE502005006672D1 (de) | 2009-04-02 |
| JP2008527123A (ja) | 2008-07-24 |
| MX2007008271A (es) | 2007-09-07 |
| EP1838781A1 (de) | 2007-10-03 |
| CA2591623A1 (en) | 2006-07-20 |
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