ES2291855T3 - Productos de reaccion de tipo sales de derivados de hals y acidos organicos que contienen fosforo para la estabilizacion de materiales polimericos. - Google Patents
Productos de reaccion de tipo sales de derivados de hals y acidos organicos que contienen fosforo para la estabilizacion de materiales polimericos. Download PDFInfo
- Publication number
- ES2291855T3 ES2291855T3 ES04712633T ES04712633T ES2291855T3 ES 2291855 T3 ES2291855 T3 ES 2291855T3 ES 04712633 T ES04712633 T ES 04712633T ES 04712633 T ES04712633 T ES 04712633T ES 2291855 T3 ES2291855 T3 ES 2291855T3
- Authority
- ES
- Spain
- Prior art keywords
- reaction products
- alkyl
- image
- cycloaliphatic
- aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007795 chemical reaction product Substances 0.000 title claims abstract description 10
- 230000006641 stabilisation Effects 0.000 title claims description 5
- 238000011105 stabilization Methods 0.000 title claims description 5
- 150000007524 organic acids Chemical class 0.000 title abstract description 4
- 235000005985 organic acids Nutrition 0.000 title abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title description 4
- 229910052698 phosphorus Inorganic materials 0.000 title description 4
- 239000011574 phosphorus Substances 0.000 title description 4
- 239000002861 polymer material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 20
- -1 cycloaliphatic Chemical group 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 238000005469 granulation Methods 0.000 claims description 11
- 230000003179 granulation Effects 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000005056 compaction Methods 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- TYFJTEPDESMEHE-UHFFFAOYSA-N 6,8-dihydroxy-3-[2-(4-methoxyphenyl)ethyl]-3,4-dihydroisochromen-1-one Chemical compound C1=CC(OC)=CC=C1CCC1OC(=O)C2=C(O)C=C(O)C=C2C1 TYFJTEPDESMEHE-UHFFFAOYSA-N 0.000 claims description 2
- MLCHBQKMVKNBOV-UHFFFAOYSA-N phenylphosphinic acid Chemical compound OP(=O)C1=CC=CC=C1 MLCHBQKMVKNBOV-UHFFFAOYSA-N 0.000 claims description 2
- 230000015556 catabolic process Effects 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- KTLIMPGQZDZPSB-UHFFFAOYSA-N diethylphosphinic acid Chemical compound CCP(O)(=O)CC KTLIMPGQZDZPSB-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 abstract description 9
- 150000001412 amines Chemical class 0.000 abstract description 4
- 125000000217 alkyl group Chemical group 0.000 abstract 9
- 125000001931 aliphatic group Chemical group 0.000 abstract 8
- 125000001072 heteroaryl group Chemical group 0.000 abstract 8
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000004611 light stabiliser Substances 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 239000000047 product Substances 0.000 description 21
- 239000004952 Polyamide Substances 0.000 description 16
- 229920002647 polyamide Polymers 0.000 description 16
- 230000015572 biosynthetic process Effects 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 210000000056 organ Anatomy 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 238000006068 polycondensation reaction Methods 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 3
- BEQVQKJCLJBTKZ-UHFFFAOYSA-N diphenylphosphinic acid Chemical compound C=1C=CC=CC=1P(=O)(O)C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920000571 Nylon 11 Polymers 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- VZZJVOCVAZHETD-UHFFFAOYSA-N diethylphosphane Chemical compound CCPCC VZZJVOCVAZHETD-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000176 photostabilization Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
- C08K5/353—Five-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polyamides (AREA)
- Hydrogenated Pyridines (AREA)
- Luminescent Compositions (AREA)
- Pyridine Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03003939A EP1449872A1 (de) | 2003-02-21 | 2003-02-21 | Stabilisierung polymerer Materialien |
| EP03003939 | 2003-02-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2291855T3 true ES2291855T3 (es) | 2008-03-01 |
Family
ID=32731562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES04712633T Expired - Lifetime ES2291855T3 (es) | 2003-02-21 | 2004-02-19 | Productos de reaccion de tipo sales de derivados de hals y acidos organicos que contienen fosforo para la estabilizacion de materiales polimericos. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20060079610A1 (enExample) |
| EP (3) | EP1449872A1 (enExample) |
| JP (2) | JP2006518407A (enExample) |
| KR (2) | KR20050109487A (enExample) |
| CN (2) | CN1751088A (enExample) |
| AT (1) | ATE370190T1 (enExample) |
| DE (1) | DE602004008228T2 (enExample) |
| ES (1) | ES2291855T3 (enExample) |
| TW (2) | TW200420643A (enExample) |
| WO (2) | WO2004074365A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1449872A1 (de) * | 2003-02-21 | 2004-08-25 | Clariant International Ltd. | Stabilisierung polymerer Materialien |
| JP4788865B2 (ja) * | 2004-10-04 | 2011-10-05 | 東洋紡績株式会社 | マスターバッチ用熱可塑性樹脂組成物およびその成形材料の製造方法およびそれらを用いた熱可塑性樹脂組成物およびその製造方法 |
| EP1773932B1 (en) * | 2004-06-22 | 2010-04-14 | INVISTA Technologies S.à.r.l. | Solubilized additive composition comprising acidic and basic constituents |
| US8557950B2 (en) | 2005-06-16 | 2013-10-15 | Grupo Petrotemex, S.A. De C.V. | High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates |
| US9267007B2 (en) | 2005-09-16 | 2016-02-23 | Grupo Petrotemex, S.A. De C.V. | Method for addition of additives into a polymer melt |
| US7838596B2 (en) | 2005-09-16 | 2010-11-23 | Eastman Chemical Company | Late addition to effect compositional modifications in condensation polymers |
| DE102008026075B4 (de) * | 2008-05-30 | 2015-04-30 | Lurgi Zimmer Gmbh | Verfahren zur Herstellung von Polyamiden unter Verwendung von Carbonsäuren und Amiden |
| JP6107559B2 (ja) * | 2012-11-09 | 2017-04-05 | 豊田合成株式会社 | 発光装置 |
| TWI513762B (zh) * | 2014-04-09 | 2015-12-21 | Fdc Lees Chemical Industry Co | 雙官能型安定劑及其組成物 |
| KR102402244B1 (ko) * | 2014-05-21 | 2022-05-26 | 솔베이 스페셜티 폴리머즈 유에스에이, 엘.엘.씨. | 안정화제 화합물 |
| TWI671121B (zh) * | 2014-07-29 | 2019-09-11 | 荷蘭商帝斯曼知識產權資產管理有限公司 | 用於製備聚醯胺的方法、用於該方法中的耐綸鹽及用於製造該鹽的方法 |
| US10889704B2 (en) | 2017-05-22 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with Mooney viscosity stability and method for preparing same |
| WO2018217294A1 (en) * | 2017-05-22 | 2018-11-29 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with mooney viscosity stability and method for preparing same |
| CN110650979B (zh) * | 2017-05-22 | 2022-06-14 | 埃克森美孚化学专利公司 | 具有门尼粘度稳定性的卤化弹性体及其制备方法 |
| CN112521659A (zh) * | 2020-12-07 | 2021-03-19 | 上海大学 | 一种改性紫外光稳定剂、制备方法及其应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5976417A (en) * | 1909-01-07 | 1999-11-02 | Clariant Finance (Bvi) Limited | Mixtures of HALS compounds |
| JPS5263183A (en) * | 1975-11-19 | 1977-05-25 | Adeka Argus Chem Co Ltd | Stabilizer for organic materials |
| DE2862332D1 (en) * | 1977-12-30 | 1983-11-10 | Ciba Geigy Ag | Stabilisation of heat-curable metallic enamel paints against the action of light, humidity and oxygen by the addition of polyalkylpiperidine derivatives |
| EP0017617A3 (de) * | 1979-03-27 | 1980-10-29 | Ciba-Geigy Ag | Polyalkylpiperidin-spirooxazolone, ihre Verwendung als Lichtschutzmittel und mit diesen Verbindungen stabilisierter Kunststoff |
| JPS5962651A (ja) * | 1982-10-02 | 1984-04-10 | Adeka Argus Chem Co Ltd | 高分子材料用光安定剤 |
| US4619956A (en) * | 1985-05-03 | 1986-10-28 | American Cyanamid Co. | Stabilization of high solids coatings with synergistic combinations |
| US5795499A (en) * | 1989-12-26 | 1998-08-18 | Cytec Technology Corp. | Stabilization of high solids coatings with liquid compositions of triazine UV absorbers |
| IT1251687B (it) * | 1991-10-11 | 1995-05-19 | Mini Ricerca Scient Tecnolog | Sali di composti triazinici con acidi ossigenati del fosforo, e loro impiego in composizioni polimeriche autoestinguenti. |
| EP0559613B1 (de) * | 1992-03-05 | 1999-12-15 | Ciba SC Holding AG | Stabilisierung von organischen Pigmenten |
| US5616636A (en) * | 1992-03-11 | 1997-04-01 | Sandoz Ltd. | Phosphonite-hals and phosphite-hals compounds as stabilizers |
| FR2694761B1 (fr) * | 1992-08-17 | 1996-06-14 | Sandoz Sa | Amines steriquement encombrees, leur preparation et leur utilisation comme stabilisants des matieres polymeres. |
| TW237471B (enExample) * | 1992-09-03 | 1995-01-01 | Ciba Geigy | |
| GB9609742D0 (en) * | 1996-05-10 | 1996-07-17 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| GB9615943D0 (en) * | 1996-07-30 | 1996-09-11 | Sandoz Ltd | Improvements in or relating to organic processes |
| US5969014A (en) * | 1997-09-23 | 1999-10-19 | Clariant Finance (Bvi) Limited | Synergistic polyamide stabilization method |
| DE19745099B4 (de) * | 1997-10-11 | 2014-11-06 | Lurgi Zimmer Gmbh | Verwendung eines Additivs mit kettenregelnden und stabilisierenden Eigenschaften bei der Herstellung von Polycaprolactam |
| US5965261A (en) * | 1998-11-16 | 1999-10-12 | Clariant Finance (Bvi) Limited | Polyester |
| FR2818985B1 (fr) * | 2000-12-29 | 2004-02-20 | Nylstar Sa | Procede de fabrication de compositions stabilisees a base de polyamide |
| EP1449872A1 (de) * | 2003-02-21 | 2004-08-25 | Clariant International Ltd. | Stabilisierung polymerer Materialien |
-
2003
- 2003-02-21 EP EP03003939A patent/EP1449872A1/de not_active Withdrawn
-
2004
- 2004-02-19 DE DE602004008228T patent/DE602004008228T2/de not_active Expired - Fee Related
- 2004-02-19 AT AT04712633T patent/ATE370190T1/de not_active IP Right Cessation
- 2004-02-19 EP EP04712630A patent/EP1597309A1/en not_active Withdrawn
- 2004-02-19 TW TW093104032A patent/TW200420643A/zh unknown
- 2004-02-19 WO PCT/IB2004/000508 patent/WO2004074365A1/en not_active Ceased
- 2004-02-19 KR KR1020057014897A patent/KR20050109487A/ko not_active Withdrawn
- 2004-02-19 JP JP2006502477A patent/JP2006518407A/ja not_active Withdrawn
- 2004-02-19 CN CNA2004800046033A patent/CN1751088A/zh active Pending
- 2004-02-19 EP EP04712633A patent/EP1597311B1/en not_active Expired - Lifetime
- 2004-02-19 ES ES04712633T patent/ES2291855T3/es not_active Expired - Lifetime
- 2004-02-19 WO PCT/IB2004/000509 patent/WO2004074364A1/en not_active Ceased
- 2004-02-19 US US10/546,503 patent/US20060079610A1/en not_active Abandoned
- 2004-02-19 CN CNA2004800046654A patent/CN1751087A/zh active Pending
- 2004-02-19 US US10/546,501 patent/US20060217467A1/en not_active Abandoned
- 2004-02-19 TW TW093104031A patent/TW200427752A/zh unknown
- 2004-02-19 JP JP2006502478A patent/JP2006518371A/ja not_active Withdrawn
- 2004-02-19 KR KR1020057014908A patent/KR20050101550A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP1449872A1 (de) | 2004-08-25 |
| WO2004074365A1 (en) | 2004-09-02 |
| CN1751087A (zh) | 2006-03-22 |
| CN1751088A (zh) | 2006-03-22 |
| DE602004008228D1 (de) | 2007-09-27 |
| TW200420643A (en) | 2004-10-16 |
| EP1597309A1 (en) | 2005-11-23 |
| KR20050101550A (ko) | 2005-10-24 |
| ATE370190T1 (de) | 2007-09-15 |
| EP1597311B1 (en) | 2007-08-15 |
| US20060079610A1 (en) | 2006-04-13 |
| KR20050109487A (ko) | 2005-11-21 |
| EP1597311A1 (en) | 2005-11-23 |
| TW200427752A (en) | 2004-12-16 |
| US20060217467A1 (en) | 2006-09-28 |
| JP2006518371A (ja) | 2006-08-10 |
| JP2006518407A (ja) | 2006-08-10 |
| WO2004074364A1 (en) | 2004-09-02 |
| DE602004008228T2 (de) | 2008-05-15 |
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