ES2272786T3 - Procedimiento para la sintesis selectiva de trietilendiamina. - Google Patents
Procedimiento para la sintesis selectiva de trietilendiamina. Download PDFInfo
- Publication number
- ES2272786T3 ES2272786T3 ES02782456T ES02782456T ES2272786T3 ES 2272786 T3 ES2272786 T3 ES 2272786T3 ES 02782456 T ES02782456 T ES 02782456T ES 02782456 T ES02782456 T ES 02782456T ES 2272786 T3 ES2272786 T3 ES 2272786T3
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- Spain
- Prior art keywords
- catalyst
- teda
- zeolite
- weight
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 238000000034 method Methods 0.000 title claims abstract description 64
- 230000015572 biosynthetic process Effects 0.000 title description 18
- 238000003786 synthesis reaction Methods 0.000 title description 13
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims abstract description 115
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000010457 zeolite Substances 0.000 claims abstract description 61
- 239000003054 catalyst Substances 0.000 claims abstract description 60
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000006243 chemical reaction Methods 0.000 claims abstract description 39
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 claims abstract description 32
- 239000002184 metal Substances 0.000 claims abstract description 32
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- 229910052681 coesite Inorganic materials 0.000 claims abstract description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 7
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 7
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 7
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 18
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- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/08—Bridged systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10132499 | 2001-07-05 | ||
| DE10132499A DE10132499A1 (de) | 2001-07-05 | 2001-07-05 | Verfahren zur selektiven Synthese von Triethylendiamin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2272786T3 true ES2272786T3 (es) | 2007-05-01 |
Family
ID=7690641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02782456T Expired - Lifetime ES2272786T3 (es) | 2001-07-05 | 2002-07-04 | Procedimiento para la sintesis selectiva de trietilendiamina. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6958397B2 (enExample) |
| EP (1) | EP1406904B1 (enExample) |
| JP (1) | JP5073914B2 (enExample) |
| KR (1) | KR20040023639A (enExample) |
| CN (1) | CN1228339C (enExample) |
| AT (1) | ATE341551T1 (enExample) |
| DE (2) | DE10132499A1 (enExample) |
| ES (1) | ES2272786T3 (enExample) |
| WO (1) | WO2003004499A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10326137A1 (de) | 2003-06-06 | 2004-12-23 | Basf Ag | Verfahren zur Erhöhung der Schneidhärte eines Formkörpers enthaltend ein kristallines Alumosilikat und Verwendung dieser Formkörper mit erhöhter Schneidhärte in chemischen Syntheseverfahren, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) durch Umsetzung von Ethylendiamin (EDA) und/oder Piperazin (PIP) |
| DE10356184A1 (de) | 2003-12-02 | 2005-07-07 | Basf Ag | Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung |
| DE102004013588A1 (de) * | 2004-03-19 | 2005-10-06 | Basf Ag | Verfahren zur Herstellung von Triethylendiamin aus Monoethanolamin |
| DE102004024274A1 (de) * | 2004-05-15 | 2005-12-01 | Basf Ag | Verfahren zur Herstellung einer Lösung von reinem Triethylendiamin (TEDA) |
| DE102004029544A1 (de) * | 2004-06-18 | 2006-01-05 | Basf Ag | Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) |
| WO2009030649A2 (de) * | 2007-09-03 | 2009-03-12 | Basf Se | Verfahren zur herstellung von teda-derivaten |
| DE102009027791B4 (de) | 2009-07-17 | 2013-02-21 | Basf Se | Zusammensetzung enthaltend Triethylendiamin, Monethylenglykol und Borhydrid |
| US8440586B2 (en) * | 2010-02-26 | 2013-05-14 | Corning Incorporated | Low pressure drop extruded catalyst filter |
| CN108906116B (zh) * | 2018-07-18 | 2021-01-29 | 西安近代化学研究所 | 一种用于合成2-甲基三乙烯二胺的催化剂和制备方法及应用 |
| CN115920589B (zh) * | 2022-12-21 | 2023-08-11 | 可迪尔空气技术（北京）有限公司 | 一种低浓度污水池废气的处理方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5337876B2 (enExample) * | 1973-07-19 | 1978-10-12 | ||
| EP0158319A3 (en) * | 1984-04-10 | 1988-05-25 | Union Carbide Corporation | Synthesis of 1-azabicyclo(2.2.2) octanes or 1,4-diazabicyclo(2-2.2)octanes |
| US4804758A (en) * | 1986-10-08 | 1989-02-14 | Basf Aktiengesellschaft | Preparation of 1,4-diazabicyclo[2.2.2]octanes |
| DE3735214A1 (de) * | 1987-10-17 | 1989-04-27 | Huels Chemische Werke Ag | Verfahren zur herstellung von 1,4-diazabicyclo(2.2.2)-octan aus piperazin |
| US5731449A (en) * | 1996-09-23 | 1998-03-24 | Air Products And Chemicals, Inc. | Triethylendiamine synthesis with base-treated zeolites as catalysts |
| US5741906A (en) * | 1996-11-15 | 1998-04-21 | Air Products And Chemicals, Inc. | Production of triethylenediamine using surface acidity deactivated zeolite catalysts |
| US6084096A (en) * | 1998-04-09 | 2000-07-04 | Air Products And Chemicals, Inc. | Triethylenediamine and piperazine synthesis using zeolite catalysts modified with a silicon-containing compound |
-
2001
- 2001-07-05 DE DE10132499A patent/DE10132499A1/de not_active Withdrawn
-
2002
- 2002-07-04 US US10/482,644 patent/US6958397B2/en not_active Expired - Fee Related
- 2002-07-04 DE DE50208348T patent/DE50208348D1/de not_active Expired - Lifetime
- 2002-07-04 EP EP02782456A patent/EP1406904B1/de not_active Expired - Lifetime
- 2002-07-04 ES ES02782456T patent/ES2272786T3/es not_active Expired - Lifetime
- 2002-07-04 CN CNB028135210A patent/CN1228339C/zh not_active Expired - Lifetime
- 2002-07-04 KR KR10-2004-7000036A patent/KR20040023639A/ko not_active Withdrawn
- 2002-07-04 AT AT02782456T patent/ATE341551T1/de not_active IP Right Cessation
- 2002-07-04 WO PCT/EP2002/007430 patent/WO2003004499A1/de not_active Ceased
- 2002-07-04 JP JP2003510666A patent/JP5073914B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATE341551T1 (de) | 2006-10-15 |
| US20040236106A1 (en) | 2004-11-25 |
| CN1228339C (zh) | 2005-11-23 |
| US6958397B2 (en) | 2005-10-25 |
| DE50208348D1 (de) | 2006-11-16 |
| EP1406904A1 (de) | 2004-04-14 |
| CN1524083A (zh) | 2004-08-25 |
| KR20040023639A (ko) | 2004-03-18 |
| DE10132499A1 (de) | 2003-01-23 |
| EP1406904B1 (de) | 2006-10-04 |
| WO2003004499A1 (de) | 2003-01-16 |
| JP2005500324A (ja) | 2005-01-06 |
| JP5073914B2 (ja) | 2012-11-14 |
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