ES2266899T3 - Catalizador ziegler modificado, proceso para prepararlo y proceso para preparar poli-1-olefinas en su presencia. - Google Patents
Catalizador ziegler modificado, proceso para prepararlo y proceso para preparar poli-1-olefinas en su presencia. Download PDFInfo
- Publication number
- ES2266899T3 ES2266899T3 ES03792238T ES03792238T ES2266899T3 ES 2266899 T3 ES2266899 T3 ES 2266899T3 ES 03792238 T ES03792238 T ES 03792238T ES 03792238 T ES03792238 T ES 03792238T ES 2266899 T3 ES2266899 T3 ES 2266899T3
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- Spain
- Prior art keywords
- component
- polymerization
- catalyst
- mol
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000003054 catalyst Substances 0.000 title claims abstract description 89
- 238000000034 method Methods 0.000 title claims description 44
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 116
- 239000011777 magnesium Substances 0.000 claims abstract description 84
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 39
- -1 magnesium alkoxide Chemical class 0.000 claims abstract description 39
- 239000000725 suspension Substances 0.000 claims abstract description 37
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 239000007789 gas Substances 0.000 claims abstract description 12
- 230000000737 periodic effect Effects 0.000 claims abstract description 11
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- 150000002902 organometallic compounds Chemical class 0.000 claims abstract description 8
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 5
- 229920001577 copolymer Polymers 0.000 claims abstract description 4
- 229920001519 homopolymer Polymers 0.000 claims abstract description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 43
- 239000005977 Ethylene Substances 0.000 claims description 43
- 239000010936 titanium Substances 0.000 claims description 32
- 239000000460 chlorine Substances 0.000 claims description 30
- 239000002283 diesel fuel Substances 0.000 claims description 24
- 239000003208 petroleum Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 238000002360 preparation method Methods 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 14
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 9
- 150000002367 halogens Chemical group 0.000 claims description 8
- 230000035484 reaction time Effects 0.000 claims description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052801 chlorine Chemical group 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 239000002612 dispersion medium Substances 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 claims description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 150000003464 sulfur compounds Chemical class 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 125000001246 bromo group Chemical group Br* 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 abstract description 8
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 34
- 230000000052 comparative effect Effects 0.000 description 30
- 238000009835 boiling Methods 0.000 description 19
- 239000006185 dispersion Substances 0.000 description 16
- 229910000077 silane Inorganic materials 0.000 description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 12
- 238000009826 distribution Methods 0.000 description 12
- 229910052719 titanium Inorganic materials 0.000 description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 11
- 150000004703 alkoxides Chemical class 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 8
- 229910003074 TiCl4 Inorganic materials 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- ZMAPKOCENOWQRE-UHFFFAOYSA-N diethoxy(diethyl)silane Chemical compound CCO[Si](CC)(CC)OCC ZMAPKOCENOWQRE-UHFFFAOYSA-N 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910003902 SiCl 4 Inorganic materials 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- ZJJUBGNGLAAGQS-UHFFFAOYSA-N cyclopentyl(dimethoxy)silane Chemical compound CO[SiH](OC)C1CCCC1 ZJJUBGNGLAAGQS-UHFFFAOYSA-N 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 2
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 206010011416 Croup infectious Diseases 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910003910 SiCl4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10236647 | 2002-08-09 | ||
| DE10236647A DE10236647A1 (de) | 2002-08-09 | 2002-08-09 | Modifizierter Ziegler Katalysator, Verfahren zu seiner Herstellung und Verfahren zum Herstellen eines Poly-1-olefins in seiner Gegenwart |
| US40819902P | 2002-09-04 | 2002-09-04 | |
| US408199P | 2002-09-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2266899T3 true ES2266899T3 (es) | 2007-03-01 |
Family
ID=31947603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03792238T Expired - Lifetime ES2266899T3 (es) | 2002-08-09 | 2003-07-31 | Catalizador ziegler modificado, proceso para prepararlo y proceso para preparar poli-1-olefinas en su presencia. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7196152B2 (https=) |
| EP (1) | EP1539836B1 (https=) |
| JP (1) | JP4558487B2 (https=) |
| KR (1) | KR20050075329A (https=) |
| CN (1) | CN1307214C (https=) |
| AU (1) | AU2003258552A1 (https=) |
| DE (1) | DE60306397T2 (https=) |
| ES (1) | ES2266899T3 (https=) |
| WO (1) | WO2004018529A2 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005102973A1 (ja) * | 2004-04-23 | 2005-11-03 | Idemitsu Kosan Co., Ltd. | マグネシウム化合物、オレフィン重合用触媒及びオレフィン重合体の製造方法 |
| DE102004037229A1 (de) * | 2004-07-29 | 2006-02-16 | Basell Polyolefine Gmbh | Verfahren zum Herstellen eines Poly-1-olefins in Gegenwart eines Ziegler Katalysators |
| KR20070045280A (ko) | 2004-08-24 | 2007-05-02 | 이데미쓰 고산 가부시키가이샤 | 마그네슘 화합물, 고체 촉매 성분, 올레핀 중합 촉매 및폴리올레핀의 제조 방법 |
| KR101930976B1 (ko) | 2011-06-01 | 2018-12-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중금속 지글러-나타 전촉매 및 그로부터 제조된 올레핀 중합용 촉매 |
| CN102408504B (zh) * | 2011-11-14 | 2013-02-13 | 中国石油大庆化工研究中心 | 钒系催化剂作用下的乙烯均聚方法及乙烯与丁烯-1共聚方法 |
| CN103130932B (zh) * | 2011-11-30 | 2015-05-27 | 中国石油天然气股份有限公司 | 一种烯烃聚合的方法 |
| CN103130940A (zh) * | 2011-11-30 | 2013-06-05 | 中国石油天然气股份有限公司 | 一种双峰或宽分子量分布聚乙烯的制备方法 |
| EP2938642A4 (en) | 2012-12-31 | 2016-09-14 | Reliance Ind Ltd | ZIEGLER-NATTA HETEROGENEOUS CATALYST SYSTEM AND OLEFIN POLYMERIZATION METHOD USING THE SAME |
| US9962251B2 (en) | 2013-10-17 | 2018-05-08 | Boston Scientific Scimed, Inc. | Devices and methods for delivering implants |
| EA034591B1 (ru) * | 2014-10-16 | 2020-02-25 | Сабик Глоубл Текнолоджиз Б.В. | Каталитическая композиция для полимеризации олефинов |
| KR20230005245A (ko) | 2020-04-30 | 2023-01-09 | 다우 글로벌 테크놀로지스 엘엘씨 | (다중-알콕시)실란 화합물로 제조된 지글러-나타 (전)촉매계 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3644318A (en) | 1968-08-21 | 1972-02-22 | Hoechst Ag | Process for the polymerization of olefins |
| JPS55149307A (en) | 1979-04-09 | 1980-11-20 | Idemitsu Kosan Co Ltd | Ethylene polymerizing method |
| JPS58222104A (ja) * | 1982-06-21 | 1983-12-23 | Toa Nenryo Kogyo Kk | オレフイン重合用触媒成分 |
| JPH0617402B2 (ja) * | 1985-03-14 | 1994-03-09 | チッソ株式会社 | ポリオレフインの製造法 |
| DE3538099A1 (de) | 1985-10-26 | 1987-04-30 | Ruhrchemie Ag | Verfahren zur homo- und mischpolymerisation von olefinen |
| US5034365A (en) * | 1990-05-09 | 1991-07-23 | Quantum Chemical Corporation | Silica supported polymerization catalyst |
| FR2623812B1 (fr) | 1987-11-30 | 1992-02-21 | Bp Chimie Sa | Catalyseur de polymerisation d'olefines de type ziegler natta et procede de preparation a partir de dialcoxyde de magnesium |
| US5354820A (en) | 1987-12-07 | 1994-10-11 | Idemitsu Petrochemical Company Limited | Process for the preparation of olefin polymer |
| DE4017661A1 (de) | 1990-06-01 | 1991-12-05 | Hoechst Ag | Verfahren zur herstellung eines poly-1-olefins |
| JP3110058B2 (ja) * | 1991-03-18 | 2000-11-20 | 東燃化学株式会社 | α−オレフィンの重合方法 |
| JP3044262B2 (ja) | 1991-07-02 | 2000-05-22 | 東ソー株式会社 | ポリオレフィンの製造方法 |
| EP0522424B1 (en) | 1991-07-03 | 1996-12-18 | Tosoh Corporation | Method for producing a polyolefin |
| JP3167418B2 (ja) * | 1992-04-27 | 2001-05-21 | 東邦チタニウム株式会社 | 超高分子量ポリエチレン製造用固体触媒成分 |
| JP3355657B2 (ja) | 1992-08-10 | 2002-12-09 | 東ソー株式会社 | ポリオレフィンの製造方法 |
| TW304958B (https=) | 1993-01-07 | 1997-05-11 | Hoechst Ag | |
| ES2136212T3 (es) | 1994-01-31 | 1999-11-16 | Toho Titanium Co Ltd | Catalizador para la polimerizacion de olefinas y procedimiento de polimerizacion que utiliza este. |
| US5968865A (en) * | 1997-12-10 | 1999-10-19 | Union Carbide Chemicals & Plastics Technology Corporation | Electron donor containing compositions |
| ATE234310T1 (de) * | 1997-12-23 | 2003-03-15 | Borealis Tech Oy | Magnesium-,halogen- und alkoxy-enthaldendes produkt |
| DE10003872A1 (de) * | 1999-11-26 | 2001-08-16 | Basell Polyolefine Gmbh | Verfahren zum Herstellen eines Poly-l-olefins in Gegenwart eines Ziegler Katalysators |
-
2003
- 2003-07-31 DE DE60306397T patent/DE60306397T2/de not_active Expired - Lifetime
- 2003-07-31 ES ES03792238T patent/ES2266899T3/es not_active Expired - Lifetime
- 2003-07-31 CN CNB038190761A patent/CN1307214C/zh not_active Expired - Fee Related
- 2003-07-31 EP EP03792238A patent/EP1539836B1/en not_active Expired - Lifetime
- 2003-07-31 US US10/523,775 patent/US7196152B2/en not_active Expired - Fee Related
- 2003-07-31 AU AU2003258552A patent/AU2003258552A1/en not_active Abandoned
- 2003-07-31 JP JP2004530064A patent/JP4558487B2/ja not_active Expired - Fee Related
- 2003-07-31 KR KR1020057002146A patent/KR20050075329A/ko not_active Ceased
- 2003-07-31 WO PCT/EP2003/008472 patent/WO2004018529A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005535771A (ja) | 2005-11-24 |
| EP1539836B1 (en) | 2006-06-21 |
| US20050261123A1 (en) | 2005-11-24 |
| WO2004018529A3 (en) | 2004-05-13 |
| AU2003258552A1 (en) | 2004-03-11 |
| CN1675261A (zh) | 2005-09-28 |
| JP4558487B2 (ja) | 2010-10-06 |
| KR20050075329A (ko) | 2005-07-20 |
| DE60306397T2 (de) | 2007-08-23 |
| WO2004018529A2 (en) | 2004-03-04 |
| CN1307214C (zh) | 2007-03-28 |
| US7196152B2 (en) | 2007-03-27 |
| EP1539836A2 (en) | 2005-06-15 |
| DE60306397D1 (de) | 2006-08-03 |
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