ES2202031T3 - Concentrados de biocida-poliester y composiciones biocidas preparadas de estos. - Google Patents
Concentrados de biocida-poliester y composiciones biocidas preparadas de estos.Info
- Publication number
- ES2202031T3 ES2202031T3 ES00811173T ES00811173T ES2202031T3 ES 2202031 T3 ES2202031 T3 ES 2202031T3 ES 00811173 T ES00811173 T ES 00811173T ES 00811173 T ES00811173 T ES 00811173T ES 2202031 T3 ES2202031 T3 ES 2202031T3
- Authority
- ES
- Spain
- Prior art keywords
- biocide
- polyester
- concentrate
- accordance
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 44
- 239000012141 concentrate Substances 0.000 title claims abstract description 38
- 239000003139 biocide Substances 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 title claims description 28
- 230000003115 biocidal effect Effects 0.000 claims abstract description 52
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- -1 polypropylene Polymers 0.000 claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 238000002845 discoloration Methods 0.000 claims abstract description 11
- 229920000098 polyolefin Polymers 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 12
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 9
- 229920000307 polymer substrate Polymers 0.000 claims description 8
- 150000002009 diols Chemical class 0.000 claims description 7
- 229920001634 Copolyester Polymers 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 238000005562 fading Methods 0.000 claims description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 5
- 229920006324 polyoxymethylene Polymers 0.000 claims description 4
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 3
- VKONPUDBRVKQLM-UHFFFAOYSA-N cyclohexane-1,4-diol Chemical compound OC1CCC(O)CC1 VKONPUDBRVKQLM-UHFFFAOYSA-N 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 229940044120 2-n-octyl-4-isothiazolin-3-one Drugs 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 2
- 229930182556 Polyacetal Natural products 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 239000004305 biphenyl Substances 0.000 claims description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- JWZXKXIUSSIAMR-UHFFFAOYSA-N methylene bis(thiocyanate) Chemical compound N#CSCSC#N JWZXKXIUSSIAMR-UHFFFAOYSA-N 0.000 claims description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- 238000004383 yellowing Methods 0.000 abstract description 10
- 239000004698 Polyethylene Substances 0.000 abstract description 8
- 229920000573 polyethylene Polymers 0.000 abstract description 8
- 239000000843 powder Substances 0.000 abstract description 7
- 239000004743 Polypropylene Substances 0.000 abstract description 2
- 229920001155 polypropylene Polymers 0.000 abstract description 2
- 239000003981 vehicle Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 238000010348 incorporation Methods 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920003232 aliphatic polyester Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000003090 pesticide formulation Substances 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 2
- 229920005629 polypropylene homopolymer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- QBTHTNCUNBHSHN-UHFFFAOYSA-N 2-[3,5-bis(2-hydroxyphenyl)phenyl]phenol Chemical compound OC1=CC=CC=C1C1=CC(C=2C(=CC=CC=2)O)=CC(C=2C(=CC=CC=2)O)=C1 QBTHTNCUNBHSHN-UHFFFAOYSA-N 0.000 description 1
- ICPXIRMAMWRMAD-UHFFFAOYSA-N 2-[3-[2-[3-(2-hydroxyethoxy)phenyl]propan-2-yl]phenoxy]ethanol Chemical compound C=1C=CC(OCCO)=CC=1C(C)(C)C1=CC=CC(OCCO)=C1 ICPXIRMAMWRMAD-UHFFFAOYSA-N 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- PNJNLCNHYSWUPT-UHFFFAOYSA-N 2-methylpentane-1,4-diol Chemical compound CC(O)CC(C)CO PNJNLCNHYSWUPT-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- RBQLGIKHSXQZTB-UHFFFAOYSA-N 3-methylpentane-2,4-diol Chemical compound CC(O)C(C)C(C)O RBQLGIKHSXQZTB-UHFFFAOYSA-N 0.000 description 1
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- SQJQLYOMPSJVQS-UHFFFAOYSA-N 4-(4-carboxyphenyl)sulfonylbenzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1S(=O)(=O)C1=CC=C(C(O)=O)C=C1 SQJQLYOMPSJVQS-UHFFFAOYSA-N 0.000 description 1
- VTDMBRAUHKUOON-UHFFFAOYSA-N 4-[(4-carboxyphenyl)methyl]benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1CC1=CC=C(C(O)=O)C=C1 VTDMBRAUHKUOON-UHFFFAOYSA-N 0.000 description 1
- OLZBOWFKDWDPKA-UHFFFAOYSA-N 4-[1-(4-carboxyphenyl)ethyl]benzoic acid Chemical compound C=1C=C(C(O)=O)C=CC=1C(C)C1=CC=C(C(O)=O)C=C1 OLZBOWFKDWDPKA-UHFFFAOYSA-N 0.000 description 1
- VFGBGCDMQOVGIU-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)propan-2-yl]benzene-1,3-diol Chemical compound C=1C=C(O)C=C(O)C=1C(C)CC1=CC=C(O)C=C1 VFGBGCDMQOVGIU-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BWVAOONFBYYRHY-UHFFFAOYSA-N [4-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=C(CO)C=C1 BWVAOONFBYYRHY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- WYHYNUWZLKTEEY-UHFFFAOYSA-N cyclobutane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CC(C(O)=O)C1 WYHYNUWZLKTEEY-UHFFFAOYSA-N 0.000 description 1
- LNGJOYPCXLOTKL-UHFFFAOYSA-N cyclopentane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C1 LNGJOYPCXLOTKL-UHFFFAOYSA-N 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- HDHLIWCXDDZUFH-UHFFFAOYSA-N irgarol 1051 Chemical compound CC(C)(C)NC1=NC(SC)=NC(NC2CC2)=N1 HDHLIWCXDDZUFH-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/467,809 US6475505B1 (en) | 1999-12-20 | 1999-12-20 | Biocide-polyester concentrates and biocidal compositions prepared therefrom |
| US467809 | 1999-12-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2202031T3 true ES2202031T3 (es) | 2004-04-01 |
Family
ID=23857274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00811173T Expired - Lifetime ES2202031T3 (es) | 1999-12-20 | 2000-12-12 | Concentrados de biocida-poliester y composiciones biocidas preparadas de estos. |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US6475505B1 (https=) |
| EP (1) | EP1114583B1 (https=) |
| JP (1) | JP2001172106A (https=) |
| KR (1) | KR100691538B1 (https=) |
| CN (1) | CN1190131C (https=) |
| AT (1) | ATE245348T1 (https=) |
| BR (1) | BR0005939A (https=) |
| CA (1) | CA2329023C (https=) |
| DE (1) | DE60004004T2 (https=) |
| DK (1) | DK1114583T3 (https=) |
| ES (1) | ES2202031T3 (https=) |
| PT (1) | PT1114583E (https=) |
| RU (1) | RU2258723C2 (https=) |
| TW (1) | TWI260969B (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AUPQ841900A0 (en) * | 2000-06-28 | 2000-07-20 | Unisearch Limited | Synthesis of cyclic compounds |
| WO2002055301A1 (de) * | 2001-01-10 | 2002-07-18 | Mitsubishi Polyester Film Gmbh | Antimikrobiell ausgerüstete, mehrschichtige polyesterfolie mit matter oberfläche |
| DE10258551A1 (de) * | 2001-12-22 | 2003-07-03 | Phoenix Ag | Klärbeckenmembran |
| US7166671B2 (en) | 2002-12-10 | 2007-01-23 | Cellresin Technologies, Llc | Grafted cyclodextrin |
| US8129450B2 (en) | 2002-12-10 | 2012-03-06 | Cellresin Technologies, Llc | Articles having a polymer grafted cyclodextrin |
| US7385004B2 (en) | 2002-12-10 | 2008-06-10 | Cellresin Technologies, Llc | Enhanced lubrication in polyolefin closure with polyolefin grafted cyclodextrin |
| US20050106192A1 (en) * | 2003-11-13 | 2005-05-19 | Parekh Prabodh P. | Synergistically-effective composition of zinc ricinoleate and one or more substituted monocyclic organic compounds and use thereof for preventing and/or suppressing malodors |
| ATE480592T1 (de) | 2004-05-24 | 2010-09-15 | Cellresin Tech Llc | Amphotere gepfropfte barrierematerialien |
| US20060093572A1 (en) * | 2004-11-03 | 2006-05-04 | Bordoloi Binoy K | Cyanoacrylate monomer formulation containing diiodomethyl-p-tolylsulfone and 2,4,4'-trichloro-2' -hydroxydiphenyl ether |
| CA2638768A1 (en) * | 2006-02-28 | 2007-09-07 | Tyco Healthcare Group Lp | Antimicrobial releasing polymers |
| US20070207189A1 (en) * | 2006-02-28 | 2007-09-06 | Nadya Belcheva | Antimicrobial medical devices |
| DE102006029829A1 (de) * | 2006-06-27 | 2008-01-03 | St. Antoniusheim Ggmbh | Konstruktionswerkstoff, insbesondere zur Herstellung von Bienenwabenrahmen, Bienenwabenmittelwände und/oder Zargen für Bienenbeuten |
| MX2009011902A (es) * | 2007-05-01 | 2010-04-30 | Oplon Bv | Empaquetamiento biocidico para cosmeticos y productos alimenticios. |
| CA2693944C (en) * | 2007-07-20 | 2015-11-17 | Ralf Dujardin | Polymer composite material with biocide functionality |
| US8012554B2 (en) * | 2007-09-12 | 2011-09-06 | Pactiv Corporation | Bags having odor management capabilities |
| US7901780B2 (en) * | 2008-06-25 | 2011-03-08 | Solutia Inc. | Polymer interlayers comprising blends of plasticized poly(vinyl butyral) and poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester |
| US20120152149A1 (en) * | 2009-08-26 | 2012-06-21 | Basf Se | Use of 1,3-diols as biocides |
| AU2012374106B8 (en) * | 2012-03-22 | 2016-11-03 | Irpc Public Company Limited | Boring bivalve resistant polymer composition |
| WO2015044785A2 (en) | 2013-09-27 | 2015-04-02 | Basf Se | Polyolefin compositions for building materials |
| CN109052592A (zh) * | 2018-09-12 | 2018-12-21 | 武汉中新化工有限公司 | 一种聚酯切片生产过程中加药抑制微生物的方法 |
| CN112471145A (zh) * | 2020-12-04 | 2021-03-12 | 王立强 | 一种超高分子固体缓释消毒抑菌剂及其制备方法 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3567724A (en) * | 1968-10-31 | 1971-03-02 | Goodrich Co B F | Hexahydro-1,3,5-tris-(4-hydroxyaryl)-s-triazines |
| AR204937A1 (es) * | 1973-12-12 | 1976-03-19 | Ciba Geigy Ag | Procedimiento para aprestar y proveer cuero con un acabado antimicrobiano y preparaciones para ilevarlo a cabo |
| SU530047A1 (ru) * | 1974-07-05 | 1976-09-30 | Казанский Филиал Всесоюзного Ордена Трудового Красного Знамени Научно-Исследовательского Института Синтетического Каучука Им. Академика С.В.Лебедева | Полиэфирна композици |
| US4086297A (en) * | 1975-11-28 | 1978-04-25 | Ventron Corporation | Method of making polymeric compositions and compositions therefor |
| SU657041A1 (ru) * | 1976-09-14 | 1979-04-15 | Предприятие П/Я В-2913 | Способ стабилизации гомо-или сополимеров этилена |
| US4629621A (en) * | 1984-07-23 | 1986-12-16 | Zetachron, Inc. | Erodible matrix for sustained release bioactive composition |
| NZ215076A (en) | 1985-03-04 | 1988-09-29 | Thiokol Morton Inc | Non-foamed porous thermoplastic resin and microbiocide masterbatch and method of making same |
| JPS62544A (ja) * | 1985-06-26 | 1987-01-06 | Teisan Seiyaku Kk | ポリエステル系組成物の成型品及びその製造方法 |
| US4686239A (en) | 1986-04-17 | 1987-08-11 | Morton Thiokol, Inc. | Solid biocide dry blend |
| JPH0781233B2 (ja) * | 1988-08-10 | 1995-08-30 | 帝人株式会社 | 防ダニ性詰綿用繊維の製造方法 |
| US5229124A (en) * | 1990-04-02 | 1993-07-20 | Morton International, Inc. | Microbicides immobilized in water soluble thermoplastic resins and aqueous dispersions of microbicides prepared therefrom |
| US5639803A (en) | 1990-10-19 | 1997-06-17 | Olin Corporation | Process for incorporating biocides into a liquid dispersion |
| US5358979A (en) * | 1990-12-13 | 1994-10-25 | Akzo Nobel Nv | Primarily solid concentrate which contains a biocide |
| GB2262468A (en) | 1991-12-19 | 1993-06-23 | Yad Hygiene Products Limited | Moulding polymeric articles having a biocidally active surface |
| US5929132A (en) | 1992-11-19 | 1999-07-27 | Arch Chemicals, Inc. | Process for incorporating biocides into a liquid dispersion |
| US5702754A (en) * | 1995-02-22 | 1997-12-30 | Meadox Medicals, Inc. | Method of providing a substrate with a hydrophilic coating and substrates, particularly medical devices, provided with such coatings |
| JPH08239507A (ja) * | 1995-03-07 | 1996-09-17 | Toppan Printing Co Ltd | 抗菌性樹脂組成物 |
| JP3479150B2 (ja) * | 1995-03-14 | 2003-12-15 | アキレス株式会社 | 抗菌、防黴性インテグラルポリウレタンフォーム |
| JPH0977907A (ja) * | 1995-09-14 | 1997-03-25 | Wataboshi Sangyo Kk | 合成樹脂組成物 |
| GB9600661D0 (en) * | 1996-01-12 | 1996-03-13 | Woolard Trevor | Bactericidal compostions and articles containing them |
| EP0846418B1 (en) * | 1996-05-10 | 2006-08-16 | Toyo Boseki Kabushiki Kaisha | Antimicrobial composition and antimicrobial laminate |
| JPH1013929A (ja) * | 1996-06-20 | 1998-01-16 | Nippon Denki Ido Tsushin Kk | 自動車電話装置 |
| KR100279081B1 (ko) | 1996-11-26 | 2001-01-15 | 조민호 | 방출조절형농약제제 |
| JPH1112107A (ja) * | 1997-06-19 | 1999-01-19 | Suzuki Yushi Kogyo Kk | 水処理用除菌剤および除菌剤入り浴用剤 |
| AUPP060597A0 (en) * | 1997-11-27 | 1998-01-08 | Novapharm Research (Australia) Pty Ltd | Improved biocide and biocidal cloth |
| US5919554A (en) | 1998-01-30 | 1999-07-06 | Microban Products Company | Antimicrobial fiberglass reinforced plastic composite |
| JPH11263705A (ja) * | 1998-03-17 | 1999-09-28 | Nisshin Steel Co Ltd | 抗菌剤及び抗菌性樹脂組成物 |
| JPH11335206A (ja) * | 1998-05-22 | 1999-12-07 | Sanyo Chem Ind Ltd | 耐熱性に優れる樹脂用抗菌剤および抗菌性樹脂組成物 |
| WO2000053413A1 (en) | 1999-03-06 | 2000-09-14 | Icet, Inc. | Antimicrobial plastics |
-
1999
- 1999-12-20 US US09/467,809 patent/US6475505B1/en not_active Expired - Fee Related
-
2000
- 2000-12-12 DE DE60004004T patent/DE60004004T2/de not_active Expired - Lifetime
- 2000-12-12 ES ES00811173T patent/ES2202031T3/es not_active Expired - Lifetime
- 2000-12-12 EP EP00811173A patent/EP1114583B1/en not_active Expired - Lifetime
- 2000-12-12 PT PT00811173T patent/PT1114583E/pt unknown
- 2000-12-12 DK DK00811173T patent/DK1114583T3/da active
- 2000-12-12 AT AT00811173T patent/ATE245348T1/de active
- 2000-12-13 RU RU2000130944/04A patent/RU2258723C2/ru not_active IP Right Cessation
- 2000-12-16 KR KR1020000077395A patent/KR100691538B1/ko not_active Expired - Fee Related
- 2000-12-18 TW TW089127054A patent/TWI260969B/zh active
- 2000-12-18 CA CA002329023A patent/CA2329023C/en not_active Expired - Fee Related
- 2000-12-19 CN CNB001359592A patent/CN1190131C/zh not_active Expired - Fee Related
- 2000-12-19 JP JP2000385240A patent/JP2001172106A/ja active Pending
- 2000-12-20 BR BR0005939-0A patent/BR0005939A/pt not_active Application Discontinuation
-
2002
- 2002-07-22 US US10/199,268 patent/US7041307B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2001172106A (ja) | 2001-06-26 |
| BR0005939A (pt) | 2001-11-27 |
| DE60004004T2 (de) | 2004-04-15 |
| KR100691538B1 (ko) | 2007-03-09 |
| ATE245348T1 (de) | 2003-08-15 |
| TWI260969B (en) | 2006-09-01 |
| PT1114583E (pt) | 2003-12-31 |
| US20030027890A1 (en) | 2003-02-06 |
| US7041307B2 (en) | 2006-05-09 |
| CN1190131C (zh) | 2005-02-23 |
| DE60004004D1 (de) | 2003-08-28 |
| RU2258723C2 (ru) | 2005-08-20 |
| EP1114583A2 (en) | 2001-07-11 |
| EP1114583A3 (en) | 2001-09-19 |
| CN1300541A (zh) | 2001-06-27 |
| US6475505B1 (en) | 2002-11-05 |
| CA2329023C (en) | 2008-07-29 |
| KR20010070305A (ko) | 2001-07-25 |
| DK1114583T3 (da) | 2003-11-17 |
| EP1114583B1 (en) | 2003-07-23 |
| CA2329023A1 (en) | 2001-06-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2202031T3 (es) | Concentrados de biocida-poliester y composiciones biocidas preparadas de estos. | |
| EP1838784B1 (de) | Biologisch abbaubare polyestermischung | |
| US20060276617A1 (en) | Aliphatic polyester resin composition, preparation method therefor, and molded article and foamed article produced from the resin composition | |
| JP3535258B2 (ja) | 持続性を有するオレフィン系防虫樹脂組成物およびその成形体 | |
| JP6972032B2 (ja) | 生物活性を有するポリエステルおよびポリオレフィン成形化合物ならびにそれから製造される成形体 | |
| WO2006052579A2 (en) | Polymeric compositions for sustained release of volatile materials | |
| EP2933294B9 (en) | Polylactic acid resin composition and resin molded article thereof | |
| KR100431360B1 (ko) | 서방성 방향 수지 조성물 | |
| JPH09202852A (ja) | 熱可塑性樹脂組成物 | |
| RU2738477C1 (ru) | Противомикробная полимерная композиция | |
| US6284814B1 (en) | Method of making masterbatches of liquid additives and, in particular, antimicrobial masterbatches | |
| KR20230152284A (ko) | 폴리유산 항균 조성물 | |
| JP2012177045A (ja) | ポリ乳酸系フィルム | |
| KR20000024493A (ko) | 옻 성분을 혼합한 기능성 합성수지 및 그 제조 방법 | |
| JPS5847420B2 (ja) | ナンネンセイポリエステルジユシソセイブツ | |
| MXPA00012421A (en) | Biocide-polyester concentrates and biocidal compositions prepared therefrom | |
| CA2080185A1 (en) | Composition | |
| JP3399130B2 (ja) | 可塑化されたポリ乳酸及びその成型品 | |
| JP7170304B2 (ja) | 小動物防除組成物 | |
| JP2000212005A (ja) | 小動物防除性樹脂組成物及び該樹脂組成物を成形してなる小動物防除性部材 | |
| JP2004123593A (ja) | 屋内性ダニ防除剤、屋内性ダニ防除組成物及び屋内性ダニ防除樹脂組成物 | |
| JP7151122B2 (ja) | ポリエステル系樹脂組成物の製造方法及びポリエステル系樹脂組成物並びに成形体 | |
| JPH10110061A (ja) | 害虫防除成型品 | |
| KR20220125057A (ko) | 항균능 및 대전방지능을 갖는 수지 조성물, 이의 제조방법 및 이를 포함하는 제품 | |
| US20040031861A1 (en) | Essential oils in additive concentrates |