ES2177905T3 - Modificacion de la conductividad electrica de una pelicula de oxido para mantener un bajo potencial de corrosion en agua a alta temperatura. - Google Patents

Modificacion de la conductividad electrica de una pelicula de oxido para mantener un bajo potencial de corrosion en agua a alta temperatura.

Info

Publication number
ES2177905T3
ES2177905T3 ES97306213T ES97306213T ES2177905T3 ES 2177905 T3 ES2177905 T3 ES 2177905T3 ES 97306213 T ES97306213 T ES 97306213T ES 97306213 T ES97306213 T ES 97306213T ES 2177905 T3 ES2177905 T3 ES 2177905T3
Authority
ES
Spain
Prior art keywords
water
zircony
modification
high temperature
oxide film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97306213T
Other languages
English (en)
Inventor
Samson Hettiarachchi
Young Jin Kim
Peter Louis Andresen
Thomas Pompilio Diaz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Application granted granted Critical
Publication of ES2177905T3 publication Critical patent/ES2177905T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C17/00—Monitoring; Testing ; Maintaining
    • G21C17/02—Devices or arrangements for monitoring coolant or moderator
    • G21C17/022—Devices or arrangements for monitoring coolant or moderator for monitoring liquid coolants or moderators
    • G21C17/0225—Chemical surface treatment, e.g. corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C12/00—Solid state diffusion of at least one non-metal element other than silicon and at least one metal element or silicon into metallic material surfaces
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/80—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/18—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using inorganic inhibitors
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N17/00—Investigating resistance of materials to the weather, to corrosion, or to light
    • G01N17/02—Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C17/00—Monitoring; Testing ; Maintaining
    • G21C17/02—Devices or arrangements for monitoring coolant or moderator
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/28—Arrangements for introducing fluent material into the reactor core; Arrangements for removing fluent material from the reactor core
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/28—Arrangements for introducing fluent material into the reactor core; Arrangements for removing fluent material from the reactor core
    • G21C19/30—Arrangements for introducing fluent material into the reactor core; Arrangements for removing fluent material from the reactor core with continuous purification of circulating fluent material, e.g. by extraction of fission products deterioration or corrosion products, impurities, e.g. by cold traps
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/28—Arrangements for introducing fluent material into the reactor core; Arrangements for removing fluent material from the reactor core
    • G21C19/30—Arrangements for introducing fluent material into the reactor core; Arrangements for removing fluent material from the reactor core with continuous purification of circulating fluent material, e.g. by extraction of fission products deterioration or corrosion products, impurities, e.g. by cold traps
    • G21C19/307—Arrangements for introducing fluent material into the reactor core; Arrangements for removing fluent material from the reactor core with continuous purification of circulating fluent material, e.g. by extraction of fission products deterioration or corrosion products, impurities, e.g. by cold traps specially adapted for liquids
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C17/00—Monitoring; Testing ; Maintaining
    • G21C17/02—Devices or arrangements for monitoring coolant or moderator
    • G21C17/022—Devices or arrangements for monitoring coolant or moderator for monitoring liquid coolants or moderators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ecology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

UN METODO PARA MITIGAR LA CORROSION GENERAL Y LA INICIACION Y EL CRECIMIENTO DE FISURAS SOBRE LA SUPERFICIE DE COMPONENTES METALICOS EN UN REACTOR NUCLEAR ENFRIADO CON AGUA. UN COMPUESTO FORMADO POR UN METAL NO NOBLE, COMO EL ZIRCONIO O EL TITANIO, SE INYECTA EN EL AGUA DEL REACTOR EN FORMA DE SOLUCION O DE SUSPENSION. ESTE COMPUESTO SE DESCOMPONE EN LAS CONDICIONES TERMICAS DEL REACTOR PARA LIBERAR IONES O ATOMOS DEL METAL NO NOBLE, QUE SE INCORPORAN A LAS SUPERFICIES DE LOS COMPONENTES, INCLUSO EN LAS SUPERFICIES INTERNAS DE LAS FISURAS QUE SE HAN FORMADO. LOS PREFERIDOS SON LOS COMPUESTOS DE ZIRCONIO COMO EL ACETILACETONATO DE ZIRCONIO, NITRATO DE ZIRCONIO Y NITRATO DE ZIRCONILO. EL ZIRCONIO INCORPORADO A LA SUPERFICIE OXIDADA DE UN COMPONENTE METALICO REDUCIRA EL POTENCIAL DE CORROSION ELECTROQUIMICA EN LA SUPERFICIE A UN NIVEL INFERIOR AL POTENCIAL CRITICO PARA PROTEGER FRENTE A LA RUPTURA POR CORROSION INTERGRANULAR SIN LA ADICION DE HIDROGENO.
ES97306213T 1996-08-15 1997-08-15 Modificacion de la conductividad electrica de una pelicula de oxido para mantener un bajo potencial de corrosion en agua a alta temperatura. Expired - Lifetime ES2177905T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/698,178 US5774516A (en) 1993-10-29 1996-08-15 Modification of oxide film electrical conductivity to maintain low corrosion potential in high-temperature water

Publications (1)

Publication Number Publication Date
ES2177905T3 true ES2177905T3 (es) 2002-12-16

Family

ID=24804223

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97306213T Expired - Lifetime ES2177905T3 (es) 1996-08-15 1997-08-15 Modificacion de la conductividad electrica de una pelicula de oxido para mantener un bajo potencial de corrosion en agua a alta temperatura.

Country Status (6)

Country Link
US (1) US5774516A (es)
EP (1) EP0826789B1 (es)
JP (1) JPH10197684A (es)
DE (1) DE69713227T2 (es)
ES (1) ES2177905T3 (es)
TW (1) TW381270B (es)

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US6024805A (en) * 1997-11-12 2000-02-15 General Electric Company Metal hydride addition for reducing corrosion potential of structural steel
US6714618B1 (en) * 1997-11-28 2004-03-30 General Electric Company Temperature-based method for controlling the amount of metal applied to metal oxide surfaces to reduce corrosion and stress corrosion cracking
US6259758B1 (en) * 1999-02-26 2001-07-10 General Electric Company Catalytic hydrogen peroxide decomposer in water-cooled reactors
JP4043647B2 (ja) * 1999-06-23 2008-02-06 株式会社東芝 原子炉構造材及び原子炉構造材の腐食低減方法
US6328911B1 (en) 2000-02-15 2001-12-11 The Regents Of The University Of California Method for the prevention of high temperature corrosion due to alkali sulfates and chlorides and composition for use in the same
DE10013865A1 (de) 2000-03-21 2001-10-04 Siemens Ag Verfahren zur Verminderung der Korrosion eines Bauteils einer kerntechnischen Anlage und Bauteil einer kerntechnischen Anlage
JP3923705B2 (ja) 2000-04-24 2007-06-06 株式会社日立製作所 原子力プラントの運転方法および原子力プラント並びに原子力プラントの水質制御方法
JP4042362B2 (ja) * 2000-08-11 2008-02-06 住友金属工業株式会社 Ｎｉ基合金製品とその製造方法
US6488782B2 (en) * 2001-01-29 2002-12-03 General Electric Company Method of reducing corrosion potential and stress corrosion cracking susceptibility in nickel-based alloys
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Also Published As

Publication number Publication date
US5774516A (en) 1998-06-30
DE69713227T2 (de) 2003-01-02
EP0826789A1 (en) 1998-03-04
JPH10197684A (ja) 1998-07-31
EP0826789B1 (en) 2002-06-12
TW381270B (en) 2000-02-01
DE69713227D1 (de) 2002-07-18

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