ES2175845T3 - Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia. - Google Patents

Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia.

Info

Publication number
ES2175845T3
ES2175845T3 ES98965218T ES98965218T ES2175845T3 ES 2175845 T3 ES2175845 T3 ES 2175845T3 ES 98965218 T ES98965218 T ES 98965218T ES 98965218 T ES98965218 T ES 98965218T ES 2175845 T3 ES2175845 T3 ES 2175845T3
Authority
ES
Spain
Prior art keywords
copolymers
tubular reactor
reactorestubulars
fluence
improvers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98965218T
Other languages
English (en)
Inventor
Andreas Deckers
Bernd Wenderoth
Peter Wedel
Wilhelm Weber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2175845T3 publication Critical patent/ES2175845T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
    • C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Detergent Compositions (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Procedimiento para la obtención de copolímeros de etileno/acetato de vinilo, en el cual se polimeriza de forma continua una mezcla, constituida por etileno y acetato de vinilo en presencia de iniciadores de polimerización radicales y, en caso dado, reguladores del peso molecular en un reactor tubular refrigerado a una presión en el intervalo de 1000 hasta 3500 bar, caracterizado porque se agrega el iniciador de polimerización al principio y en varios lugares a lo largo del reactor tubular por dosificación y situándose las alteraciones de temperatura en la mezcla de reacción a lo largo del reactor tubular entre el primer máximo de temperatura y la última dosificación del iniciador de polimerización en un intervalo de un máximo de 20 C.
ES98965218T 1997-12-05 1998-12-01 Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia. Expired - Lifetime ES2175845T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19754039A DE19754039A1 (de) 1997-12-05 1997-12-05 Verfahren zur Herstellung von Ethylencopolymeren in segmentierten Rohrreaktoren und Verwendung der Copolymere als Fließverbesserer

Publications (1)

Publication Number Publication Date
ES2175845T3 true ES2175845T3 (es) 2002-11-16

Family

ID=7850888

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98965218T Expired - Lifetime ES2175845T3 (es) 1997-12-05 1998-12-01 Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia.

Country Status (12)

Country Link
US (1) US6610797B1 (es)
EP (1) EP1036100B1 (es)
JP (1) JP4488463B2 (es)
KR (1) KR100567636B1 (es)
AT (1) ATE215570T1 (es)
CA (1) CA2311413C (es)
DE (2) DE19754039A1 (es)
DK (1) DK1036100T3 (es)
ES (1) ES2175845T3 (es)
NO (1) NO324462B1 (es)
PT (1) PT1036100E (es)
WO (1) WO1999029748A1 (es)

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US7745550B2 (en) 2001-12-19 2010-06-29 Exxonmobil Chemical Patents Inc. Tubular polymerization reactors and polymers made therein
DE102010001408A1 (de) 2009-02-06 2010-08-12 Basf Se Verwendung von Ketonen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauches von Dieselmotoren
DE102010039039A1 (de) 2009-08-24 2011-03-03 Basf Se Verwendung von organischen Verbindungen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauchs von Dieselmotoren
US8790426B2 (en) 2010-04-27 2014-07-29 Basf Se Quaternized terpolymer
CN102858811B (zh) 2010-04-27 2015-01-28 巴斯夫欧洲公司 季铵化三元共聚物
WO2011161149A1 (de) 2010-06-25 2011-12-29 Basf Se Quaternisiertes copolymerisat
US8911516B2 (en) 2010-06-25 2014-12-16 Basf Se Quaternized copolymer
PL2808350T3 (pl) 2010-07-06 2018-04-30 Basf Se Kwaternizowane związki azotu niezawierające kwasów i ich zastosowanie jako dodatku do paliw silnikowych i smarów
BR112013016031B1 (pt) † 2010-12-22 2020-04-07 Basell Polyolefine Gmbh processo para preparar copolímero de etileno na presença de iniciador da polimerização por radicais livres por copolimerização de etileno, copolímero de etileno obtido por tal processo e seu uso, bem como processo para revestimento por extrusão de um substrato
EP2540808A1 (de) 2011-06-28 2013-01-02 Basf Se Quaternisierte Stickstoffverbindungen und deren Verwendung als Additive in Kraft- und Schmierstoffen
US20130133243A1 (en) 2011-06-28 2013-05-30 Basf Se Quaternized nitrogen compounds and use thereof as additives in fuels and lubricants
EP2589647A1 (de) 2011-11-04 2013-05-08 Basf Se Quaternisierte Polyetheramine und deren Verwendung als Additive in Kraft- und Schmierstoffen
EP2604674A1 (de) 2011-12-12 2013-06-19 Basf Se Verwendung quaternisierter Alkylamine als Additive in Kraft- und Schmierstoffen
ES2711361T3 (es) 2012-02-10 2019-05-03 Basf Se Sales de imidazolio como aditivos para carburantes y combustibles
US9062266B2 (en) 2012-02-10 2015-06-23 Basf Se Imidazolium salts as additives for fuels
CA2866557A1 (en) 2012-03-07 2013-09-12 Basf Se Use of substituted ureas or urethanes for further improvement of the cold flow properties of mineral oils and crude oils
CN104159999B (zh) 2012-03-07 2016-03-23 巴斯夫欧洲公司 取代的脲或氨基甲酸酯用于改善矿物的和合成的非水工业液体、特别是燃料或润滑剂的使用特性的用途
US9458401B2 (en) 2012-03-07 2016-10-04 Basf Se Use of substituted ureas or urethanes for improvement of the use properties of mineral and synthetic nonaqueous industrial fluids
KR20150079782A (ko) 2012-10-23 2015-07-08 바스프 에스이 히드로카르빌 에폭시드의 4차화 암모늄 염 및 연료 및 윤활제 내의 첨가제로서의 이의 용도
CN105849238B (zh) 2013-06-07 2017-08-15 巴斯夫欧洲公司 用环氧烷烃和烃基取代的多羧酸季铵化的氮化合物作为燃料和润滑剂中的添加剂的用途
EP2811007A1 (de) 2013-06-07 2014-12-10 Basf Se Verwendung mit Alkylenoxid und Hydrocarbyl-substituierter Polycarbonsäure quaternisierter Alkylamine als Additive in Kraft- und Schmierstoffen
PL3483234T3 (pl) 2013-09-20 2021-12-13 Basf Se Zastosowanie specjalnych pochodnych czwartorzędowanych związków azotowych jako dodatków do paliw silnikowych
EP3099720B1 (de) 2014-01-29 2018-07-04 Basf Se Verwendung von polycarbonsäure-basierten additiven für kraftstoffe
CN106459811B (zh) 2014-01-29 2020-02-18 巴斯夫欧洲公司 用于燃料和润滑剂的缓蚀剂
DE212015000271U1 (de) 2014-11-25 2017-09-06 Basf Se Korrosionsinhibitoren für Kraft- und Schmierstoffe
US10557096B2 (en) 2014-11-27 2020-02-11 Basf Se Copolymer and use thereof for reducing crystallization of paraffin crystals in fuels
KR20160080453A (ko) * 2014-12-29 2016-07-08 한화토탈 주식회사 태양전지 봉지재 시트용 에틸렌비닐아세테이트 공중합체 수지의 제조방법 및 그 수지
JP6547371B2 (ja) * 2015-03-30 2019-07-24 大日本印刷株式会社 積層シート、発泡積層シート及びそれらの製造方法
US11085001B2 (en) 2015-07-16 2021-08-10 Basf Se Copolymers as additives for fuels and lubricants
DE212016000150U1 (de) 2015-07-24 2018-03-16 Basf Se Korrosionsinhibitoren für Kraft- und Schmierstoffe
EP3375793B1 (en) * 2015-12-22 2023-09-06 Braskem S.A. Device for injecting a polymerization initiator in a tubular reactor, tubular reactor for continuous polymerization of olefins, and process for producing ethylene copolymers and polymers
WO2017202642A1 (de) 2016-05-24 2017-11-30 Basf Se Copolymerisat und seine verwendung zur verminderung der kristallisation von paraffinkristallen in kraftstoffen
US11078418B2 (en) 2016-07-05 2021-08-03 Basf Se Corrosion inhibitors for fuels and lubricants
WO2018007192A1 (de) 2016-07-05 2018-01-11 Basf Se Korrosionsinhibitoren für kraft- und schmierstoffe
US20190249099A1 (en) 2016-07-07 2019-08-15 Basf Se Copolymers as additives for fuels and lubricants
WO2018007486A1 (de) 2016-07-07 2018-01-11 Basf Se Polymere als additive für kraft und schmierstoffe
WO2018007445A1 (de) 2016-07-07 2018-01-11 Basf Se Korrosionsinhibitoren für kraft- und schmierstoffe
EP3555244B1 (de) 2016-12-15 2023-05-31 Basf Se Polymere als dieselkraftstoffadditive für direkteinspritzende dieselmotoren
EP3555242B1 (de) 2016-12-19 2020-11-25 Basf Se Additive zur verbesserung der thermischen stabilität von kraftstoffen
WO2018188986A1 (de) 2017-04-13 2018-10-18 Basf Se Polymere als additive für kraft und schmierstoffe
CN110177814A (zh) * 2017-12-18 2019-08-27 Lg化学株式会社 乙烯乙酸乙烯酯共聚物及其制备方法
EP3990585A1 (en) 2019-06-26 2022-05-04 Basf Se New additive packages for gasoline fuels
KR20220097917A (ko) 2019-10-31 2022-07-08 엑손모빌 케미칼 패턴츠 인코포레이티드 고분자량 에틸렌계 중합체의 제조를 위한 방법 및 시스템
EP3913035A1 (en) 2020-05-20 2021-11-24 Basf Se Novel compositions for reducing crystallization of paraffin crystals in fuels
ES2964845T3 (es) 2020-07-14 2024-04-09 Basf Se Inhibidores de corrosión para combustibles y lubricantes
RS65269B1 (sr) 2021-04-15 2024-03-29 Basf Se Nove kompozicije za smanjenje kristalizacije kristala parafina u gorivima
KR102540867B1 (ko) 2021-04-29 2023-06-07 한화토탈에너지스 주식회사 개시제 투입구 위치 선정을 통한 높은 생산성으로 제품을 생산하기 위한 에틸렌 중합방법
WO2023025636A1 (en) 2021-08-27 2023-03-02 Basf Se Aqueous dispersions of paraffin inhibitors
CA3237233A1 (en) 2021-11-16 2023-05-25 Richard HEDIGER Method for producing of a fuel additive
WO2024056479A1 (en) 2022-09-12 2024-03-21 Basf Se New compositions for reducing crystallization of paraffin crystals in fuels

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Also Published As

Publication number Publication date
KR100567636B1 (ko) 2006-04-05
JP2001525462A (ja) 2001-12-11
NO20002778D0 (no) 2000-05-30
EP1036100A1 (de) 2000-09-20
DE59803667D1 (de) 2002-05-08
EP1036100B1 (de) 2002-04-03
ATE215570T1 (de) 2002-04-15
CA2311413C (en) 2008-02-05
PT1036100E (pt) 2002-09-30
US6610797B1 (en) 2003-08-26
WO1999029748A1 (de) 1999-06-17
CA2311413A1 (en) 1999-06-17
JP4488463B2 (ja) 2010-06-23
NO20002778L (no) 2000-07-31
KR20010032707A (ko) 2001-04-25
DK1036100T3 (da) 2002-07-08
NO324462B1 (no) 2007-10-22
DE19754039A1 (de) 1999-06-24

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