ES2142506T3 - Fotoiniciadores funcionalizados, derivados y macromeros de los mismos y su uso. - Google Patents

Fotoiniciadores funcionalizados, derivados y macromeros de los mismos y su uso.

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Publication number
ES2142506T3
ES2142506T3 ES95942692T ES95942692T ES2142506T3 ES 2142506 T3 ES2142506 T3 ES 2142506T3 ES 95942692 T ES95942692 T ES 95942692T ES 95942692 T ES95942692 T ES 95942692T ES 2142506 T3 ES2142506 T3 ES 2142506T3
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ES
Spain
Prior art keywords
functionalized
aminoacetophenones
macromeros
derivatives
photoinitiators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95942692T
Other languages
English (en)
Inventor
Peter Chabrecek
Kurt Dietliker
Dieter Lohmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Novartis AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application granted granted Critical
Publication of ES2142506T3 publication Critical patent/ES2142506T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • G—PHYSICS
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    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/075—Silicon-containing compounds
    • G03F7/0757—Macromolecular compounds containing Si-O, Si-C or Si-N bonds
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/20—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C271/28—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
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    • C07C2601/14—The ring being saturated

Abstract

LA PRESENTE INVENCION SE REFIERE A AL - AMINOACETOFENONAS FUNCIONALIZADAS CON DIISOCIANATOS ORGANICOS QUE TIENEN LA ESTRUCTURA GENERAL (I) Y QUE PUEDEN SER UTILIZADOS COMO FOTOINICIADORES REACTIVOS; A OLIGOMEROS Y POLIMEROS A LOS CUALES ESTAN UNIDAS DICHAS {AL} - AMINOACETOFENONAS FUNCIONALIZADAS; A {AL} - AMINOACETOFENONAS QUE PRESENTAN UNA CADENA LATERAL INSATURADA POLIMERIZABLE; A FOTOINICIADORES DIMEROS Y TRIMEROS; A LA UTILIZACION DE DICHOS FOTOINICIADORES; A MATERIALES REVESTIDOS CON DICHOS FOTOINICIADORES; Y A LA UTILIZACION DE {AL} - AMINOAETOFENONAS FUNCIONALIZADAS PARA MODIFICAR SUPERFICIES. EN LA CITADA ESTRUCTURA (I) X ES - O - BIVALENTE, - NH -, - S -, ALQUILENO INFERIOR O (A); Y ES UN ENLACE DIRECTO O - O (CH{SUB,2}){SUB,N}, DONDE N ES UN ENTERO ENTRE 1 Y 6 Y CUYO GRUPO TERMINAL CH{SUB,2} ESTA UNIDO AL GRUPO X ADYACENTE EN LA FORMULA (I); R ES H, C{SUB,1} - C{SUB,12} ALQUILO, C{SUB,1} - C{SUB,12} ALCOXI, C{SUB,1} - C{SUB,12} ALQUILNH O - NR{SUB,1A}R{SUB,1B}, DONDE R{SUB,1A} ESALQUILO INFERIOR Y R{SUB,1B} ES H O ALQUILO INFERIOR; R{SUB,1} ES ALQUILO INFERIOR LINEAL O RAMIFICADO, ALQUENILO INFERIOR O ARIL - ALQUILO INFERIOR; R{SUB,2}, INDEPENDIENTEMENTE DE R{SUB,1}, TIENE EL MISMO SIGNIFICADO QUE R{SUB,1} O ES ARILO, O R{SUB,1} Y R{SUB,2} JUNTOS SON (CH{SUB,2}){SUB,M} -, DONDE M ES UN ENTERO ENTRE 2 Y 6; R{SUB,3} Y R{SUB,4} SON, INDEPENDIENTEMENTE, ALQUILO INFERIOR LINEAL O RAMIFICADO QUE PUEDE ESTAR SUSTITUIDO CON C{SUB,1} - C{SUB,4} ALCOXI O ARIL - ALQUILO INFERIOR O ALQUENILO INFERIOR; O R{SUB,3} Y R{SUB,4} JUNTOS SON - (CH{SUB,2}){SUB,Z} - Y{SUB,1} (CH{SUB,2}){SUB,Z} -, DONDE Y{SUB,1} ES UN ENLACE DIRECTO, - O , - S - O - NR{SUB,1B} - Y R{SUB,1B} ES H O ALQUILO INFERIOR Y Z ES, INDEPENDIENTEMENTE, UN ENTERO ENTRE 2 Y 4; R{SUB,5} ES C{SUB,3} - C{SUB,18} ALQUILENO LINEAL O RAMIFICADO, C{SUB,6} C{SUB,10} ARILENO SIN SUSTITUIR O SUSTITUIDO CON C{SUB,1} C{SUB,4} ALQUILO O C{SUB,1} - C{SUB,4} ALCOXI, O C{SUB,7} C{SUB,18} ARALQUILENO SUSTITUIDO CON C{SUB,1} - C{SUB,4} ALQUILO, CON C{SUB,1} - C{SUB,4} ALCOXI O SIN SUSTITUIR, C{SUB,13} C{SUB,24} ARILENALQUILENARILENO SUSTITUIDO CON C{SUB,1} C{SUB,4} ALQUILO, CON C{SUB,1} - C{SUB,4} ALCOXI O SIN SUSTITUIR, C{SUB,3} - C{SUB,8} CICLOALQUILENO SUSTITUIDO CON C{SUB,1} C{SUB,4} ALQUILO, C{SUB,1} - C{SUB,4} ALCOXI O SIN SUSTITUIR, C{SUB,3} - C{SUB,8} CICLOALQUILEN - C{SUB,Y}H{SUB,2Y} SUSTITUIDO CON C{SUB,1} - C{SUB,4} ALQUILO, CON C{SUB,1} C{SUB,4} ALCOXI O SIN SUSTITUIR O -C{SUB,Y}H{SUB,2Y} C{SUB,Y}H{SUB,2Y} - SUSTITUIDO CON C{SUB,1} - C{SUB,4} ALQUILO, CON C{SUB,1} - C{SUB,4} ALCOXI O SIN SUSTITUIR, DONDE Y ES UN ENTERO ENTRE 1 Y 6; Y D ES UN GRUPO ISOCIANATO.
ES95942692T 1994-12-30 1995-12-18 Fotoiniciadores funcionalizados, derivados y macromeros de los mismos y su uso. Expired - Lifetime ES2142506T3 (es)

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TW434456B (en) 2001-05-16
NO973021L (no) 1997-09-01
JPH10512856A (ja) 1998-12-08
US6204306B1 (en) 2001-03-20
ZA9511002B (en) 1996-07-01
MX9704918A (es) 1997-10-31
PT800511E (pt) 2000-07-31
DK0800511T3 (da) 2000-06-19
EP0800511A1 (en) 1997-10-15
CA2208664A1 (en) 1996-07-11
GR3032930T3 (en) 2000-07-31
FI972698A (fi) 1997-08-25
BR9510177A (pt) 1997-12-23
FI972698A0 (fi) 1997-06-23
ATE189210T1 (de) 2000-02-15
WO1996020919A1 (en) 1996-07-11
DE69514835D1 (de) 2000-03-02
CN1174547A (zh) 1998-02-25
AU700575B2 (en) 1999-01-07
NO973021D0 (no) 1997-06-27
IL116488A0 (en) 1996-03-31
EP0800511B1 (en) 2000-01-26
DE69514835T2 (de) 2000-08-17
AU4387396A (en) 1996-07-24
KR980700964A (ko) 1998-04-30

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