ES2115152T3 - Procedimiento para la polimerizacion por radicales del cloruro de vinilo, a ph acido, en dispersion acuosa. - Google Patents
Procedimiento para la polimerizacion por radicales del cloruro de vinilo, a ph acido, en dispersion acuosa.Info
- Publication number
- ES2115152T3 ES2115152T3 ES94202958T ES94202958T ES2115152T3 ES 2115152 T3 ES2115152 T3 ES 2115152T3 ES 94202958 T ES94202958 T ES 94202958T ES 94202958 T ES94202958 T ES 94202958T ES 2115152 T3 ES2115152 T3 ES 2115152T3
- Authority
- ES
- Spain
- Prior art keywords
- vinyl chloride
- procedure
- acid
- aqueous dispersion
- radical polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 239000006185 dispersion Substances 0.000 title 1
- 238000010526 radical polymerization reaction Methods 0.000 title 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 4
- IFFPICMESYHZPQ-UHFFFAOYSA-N Prenylamine Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)CCNC(C)CC1=CC=CC=C1 IFFPICMESYHZPQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Abstract
LA TEMPERATURA DEL MEDIO DE POLIMERIZACION DEL CLORURO DE VINILO EN LA INTERVENCION DE INICIADORES OLEOSOLUBLES SE REGULA ESENCIALMENTE POR INYECCION DIRECTA Y SE MODULA POR UNA CANTIDAD EFICAZ DE UN INHIBIDOR INORGANICO FUERTE DE LA POLIMERIZACION RADICAL O DE UN PRECURSOR, ELEGIDOS VENTAJOSAMENTE ENTRE EL YODO Y EL MONOXIDO DE NITROGENO, ASI COMO ENTRE LOS YODUROS Y LOS NITRILOS DE LOS METALES ALCALINOS, PRECURSORES RESPECTIVOS DEL YODO Y DEL MONOXIDO DE NITROGENO. EL PROCESO CONDUCE A UNA MEJORA SIGNIFICATIVA DE LA PRODUCTIVIDAD DE LOS REACTORES.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9301120A BE1007648A3 (fr) | 1993-10-21 | 1993-10-21 | Procede pour la polymerisation radicalaire du chlorure de vinyle a ph acide en dispersion aqueuse. |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2115152T3 true ES2115152T3 (es) | 1998-06-16 |
Family
ID=3887451
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94202958T Expired - Lifetime ES2115152T3 (es) | 1993-10-21 | 1994-10-12 | Procedimiento para la polimerizacion por radicales del cloruro de vinilo, a ph acido, en dispersion acuosa. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5459211A (es) |
EP (1) | EP0649862B1 (es) |
JP (1) | JP3573804B2 (es) |
KR (1) | KR100349492B1 (es) |
BE (1) | BE1007648A3 (es) |
BR (1) | BR9404159A (es) |
CA (1) | CA2133914C (es) |
DE (1) | DE69408621T2 (es) |
ES (1) | ES2115152T3 (es) |
FI (1) | FI111374B (es) |
TW (1) | TW282474B (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000061648A1 (en) * | 1999-04-09 | 2000-10-19 | Polymer Systems As | Preparation of polymer particles |
EP1236742A1 (en) * | 2001-02-28 | 2002-09-04 | Bayer Ag | Controlled free-radical polymerization products using new control agents |
EP1622853A1 (en) * | 2003-04-22 | 2006-02-08 | SOLVAY (Société Anonyme) | Iodinated organic substances of low molecular mass and process for preparing them |
FR2903409A1 (fr) * | 2006-07-04 | 2008-01-11 | Solvay | Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres |
JP2013018953A (ja) * | 2011-06-15 | 2013-01-31 | Canon Inc | 高分子粒子の製造方法 |
CN106573995B (zh) | 2014-08-14 | 2019-07-09 | 罗门哈斯公司 | 聚合方法 |
EP3180366B1 (en) | 2014-08-14 | 2018-09-26 | Rohm and Haas Company | Polymer with releasable gas |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3642756A (en) * | 1969-08-22 | 1972-02-15 | Dow Chemical Co | Method for increasing the capacity of a polymerization vessel during polymerization of vinyl chloride monomer in aqueous suspension |
BE756503A (fr) * | 1969-09-24 | 1971-03-23 | Wacker Chemie Gmbh | Procede de polymerisation du chlorure de vinyle |
US3790542A (en) * | 1970-09-15 | 1974-02-05 | Shinetsu Chemical Co | Method for polymerizing vinyl chloride |
BE837070A (fr) * | 1974-12-27 | 1976-06-24 | Procede de polymerisation en suspension de chlorure de vinyle | |
US4180634A (en) * | 1975-07-18 | 1979-12-25 | Shin-Etsu Chemical Co., Ltd. | Polymerizing vinyl chloride with lowering of scale formation |
-
1993
- 1993-10-21 BE BE9301120A patent/BE1007648A3/fr not_active IP Right Cessation
-
1994
- 1994-10-12 EP EP94202958A patent/EP0649862B1/fr not_active Expired - Lifetime
- 1994-10-12 DE DE69408621T patent/DE69408621T2/de not_active Expired - Lifetime
- 1994-10-12 ES ES94202958T patent/ES2115152T3/es not_active Expired - Lifetime
- 1994-10-13 US US08/322,765 patent/US5459211A/en not_active Expired - Lifetime
- 1994-10-17 TW TW083109610A patent/TW282474B/zh not_active IP Right Cessation
- 1994-10-18 JP JP25184194A patent/JP3573804B2/ja not_active Expired - Fee Related
- 1994-10-19 BR BR9404159A patent/BR9404159A/pt not_active IP Right Cessation
- 1994-10-20 KR KR1019940026825A patent/KR100349492B1/ko not_active IP Right Cessation
- 1994-10-20 FI FI944927A patent/FI111374B/fi not_active IP Right Cessation
- 1994-10-20 CA CA002133914A patent/CA2133914C/fr not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69408621D1 (de) | 1998-04-02 |
BE1007648A3 (fr) | 1995-09-05 |
KR950011477A (ko) | 1995-05-15 |
DE69408621T2 (de) | 1998-09-10 |
EP0649862A1 (fr) | 1995-04-26 |
FI944927A0 (fi) | 1994-10-20 |
KR100349492B1 (ko) | 2002-11-11 |
FI944927A (fi) | 1995-04-22 |
BR9404159A (pt) | 1995-06-27 |
CA2133914C (fr) | 2006-11-28 |
US5459211A (en) | 1995-10-17 |
JPH07157505A (ja) | 1995-06-20 |
TW282474B (es) | 1996-08-01 |
JP3573804B2 (ja) | 2004-10-06 |
CA2133914A1 (fr) | 1995-04-22 |
EP0649862B1 (fr) | 1998-02-25 |
FI111374B (fi) | 2003-07-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EC2A | Search report published |
Date of ref document: 19980316 Kind code of ref document: A1 Effective date: 19980316 |
|
FG2A | Definitive protection |
Ref document number: 649862 Country of ref document: ES |
|
FA2A | Application withdrawn |
Effective date: 20000710 |