ES2093874T3 - Catalizador con soporte, procedimiento para su produccion asi como su utilizacion para la preparacion de acetato de vinilo. - Google Patents

Catalizador con soporte, procedimiento para su produccion asi como su utilizacion para la preparacion de acetato de vinilo.

Info

Publication number
ES2093874T3
ES2093874T3 ES93105335T ES93105335T ES2093874T3 ES 2093874 T3 ES2093874 T3 ES 2093874T3 ES 93105335 T ES93105335 T ES 93105335T ES 93105335 T ES93105335 T ES 93105335T ES 2093874 T3 ES2093874 T3 ES 2093874T3
Authority
ES
Spain
Prior art keywords
preparation
vinyl acetate
support
catalyst
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93105335T
Other languages
English (en)
Inventor
Peter Dr Wirtz
Friedrich Dr Wunder
Karl-Fred Dr Worner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Application granted granted Critical
Publication of ES2093874T3 publication Critical patent/ES2093874T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/343—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of ultrasonic wave energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C07C69/01—Vinyl esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Health & Medical Sciences (AREA)
  • Optics & Photonics (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Measuring Pulse, Heart Rate, Blood Pressure Or Blood Flow (AREA)

Abstract

LA INVENCION SE REFIERE A CATALIZADORES RADOS: SON DEL TIPO PD/K/AU, PD/K/BA Y PD/K/CD, MEJORADOS, SU PRODUCCION Y SU APLICACION PARA LA OBTENCION DE ACETATO DE VINILO A PARTIR DE ETILENO, ACIDO ACETICO Y OXIGENO EN FASE GASEOSA. LOS CATALIZADORES MENCIONADOS SE PRODUCEN MEDIANTE PULVERIZACION POR ULTRASONIDO Y EN CANTIDADES PEQUEÑAS, DE UNA SOLUCION DE SALES METALICAS DEL MATERIAL CATALIZADOR, APLICACION DE LA SOLUCION PULVERIZADA SOBRE LA PARTICULA PORTADORA EN UN TIEMPO LIMITE Y SECADO DE LA SOLUCION APLICADA YA QUE LA SAL METALICA ACTIVA CATALITICAMENTE NO PUEDE PENETRAR HASTA EL NUCLEO DE LA PARTICULA PORTADORA, SINO SOLAMENTE UNA PARTE EXTERIOR MAS O MENOS PEQUEÑA.
ES93105335T 1992-04-08 1993-03-31 Catalizador con soporte, procedimiento para su produccion asi como su utilizacion para la preparacion de acetato de vinilo. Expired - Lifetime ES2093874T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4211780 1992-04-08

Publications (1)

Publication Number Publication Date
ES2093874T3 true ES2093874T3 (es) 1997-01-01

Family

ID=6456375

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93105335T Expired - Lifetime ES2093874T3 (es) 1992-04-08 1993-03-31 Catalizador con soporte, procedimiento para su produccion asi como su utilizacion para la preparacion de acetato de vinilo.

Country Status (17)

Country Link
US (2) US5422329A (es)
EP (1) EP0565952B1 (es)
JP (1) JPH067676A (es)
KR (1) KR930021261A (es)
AT (1) ATE142535T1 (es)
AU (1) AU657213B2 (es)
BR (1) BR9301467A (es)
CA (1) CA2093610A1 (es)
DE (1) DE59303704D1 (es)
DK (1) DK0565952T3 (es)
ES (1) ES2093874T3 (es)
FI (1) FI931556A (es)
MX (1) MX9301994A (es)
MY (1) MY110347A (es)
NO (1) NO931319L (es)
NZ (1) NZ247368A (es)
TW (1) TW330160B (es)

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GB9313901D0 (en) * 1993-07-06 1993-08-18 Chandler Brian Linings for pipelines and passageways
DE4323980C1 (de) * 1993-07-16 1995-03-30 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE4323981C1 (de) * 1993-07-16 1995-03-09 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE4323978C1 (de) * 1993-07-16 1995-02-16 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
CA2135021A1 (en) * 1993-11-19 1995-05-20 David J. Gulliver Process for the preparation of catalysts for use in the production of vinyl acetate
US5600031A (en) * 1995-08-18 1997-02-04 Exxon Chemical Patents, Inc. Process for preforming cobaltous salts using shell-type preformer catalysts
US5691267A (en) * 1996-04-16 1997-11-25 Hoechst Celanese Corporation Two step gold addition method for preparing a vinyl acetate catalyst
US5693586A (en) * 1996-06-28 1997-12-02 Hoechst Celanese Corporation Palladium-gold catalyst for vinyl acetate production
US5731457A (en) * 1997-06-03 1998-03-24 Hoechst Celanese Corporation Vinyl acetate process utilizing a palladium-gold-copper catalyst
US5968869A (en) * 1997-06-03 1999-10-19 Celanese International Corporation Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
DE19723591A1 (de) * 1997-06-05 1998-12-10 Hoechst Ag Katalysator, Verfahren zu seiner Herstellung und seine Verwendung zur Herstellung von Vinylacetat
CN1049680C (zh) * 1997-09-23 2000-02-23 中国石油化工集团公司 乙烷-乙烯馏份中的炔烃选择加氢催化剂
JP2000070718A (ja) * 1998-06-17 2000-03-07 Nippon Shokubai Co Ltd ベンジルエステルの製造方法
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
DE19914066A1 (de) 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
WO2002078843A1 (en) * 2001-03-30 2002-10-10 Shell Internationale Research Maatschappij B.V. Process for preparing a group viii-metal containing catalyst, use thereof for preparing an alkenyl carboxylate
DE10152146A1 (de) * 2001-10-25 2003-05-22 Ticona Gmbh Verfahren zur Reduzierung der Zähigkeit mechanisch zu bearbeitender Formteile aus Kunststoff sowie deren Verwendung
DE10163180A1 (de) * 2001-12-21 2003-07-10 Degussa Trägerkatalysator
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
US7381683B1 (en) 2004-10-28 2008-06-03 Nanostellar, Inc. Method of producing multi-component catalysts
US7381682B1 (en) 2004-10-28 2008-06-03 Nanostellar, Inc. Method for producing heterogeneous catalysts containing metal nanoparticles
US7585312B2 (en) * 2005-04-29 2009-09-08 Warsaw Orthopedic, Inc. Spinal stabilization apparatus and method
KR101120699B1 (ko) * 2006-11-20 2012-03-22 나노스텔라 인코포레이티드 금속 나노입자를 함유하는 불균질 촉매의 제조방법
DE102006058800A1 (de) 2006-12-13 2008-06-19 Wacker Chemie Ag Verfahren zur Herstellung von Katalysatoren und deren Verwendung für die Gasphasenoxidation von Olefinen
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025358A1 (de) 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators
DE202007019009U1 (de) 2007-05-31 2010-03-04 Süd-Chemie AG Vorrichtung zur Herstellung eines als Schalenkatalysator ausgebildeten geträgerten Edelmetallkatalysators
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025224A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025356A1 (de) 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
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DE102007043447B4 (de) 2007-09-12 2014-02-13 Süd-Chemie Ip Gmbh & Co. Kg Katalysatorträger mit erhöhter thermischer Leitfähigkeit
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EP2103216A1 (de) 2008-03-19 2009-09-23 Bayer CropScience AG Ausgewählte Salze des 3-(5,6-dihydro-1,4,2-dioxazin-3-yl)-N-[(4,6-dimethoxypyrimidin-2-yl)carbamoyl] pyridin-2-sulfonamids, Verfahren zur deren Herstellung, sowie deren Verwendung als Herbizide und Pflanzenwachstumsregulatoren
DE102008032080A1 (de) 2008-07-08 2010-01-14 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators
DE102008059340A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie dessen Verwendung
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
DE102008059342A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung
DE102010026462A1 (de) 2010-07-08 2012-01-12 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102011018532A1 (de) * 2011-04-26 2012-10-31 Süd-Chemie AG Basische Katalysatorträgerkörper mit niedriger Oberfläche
WO2015057311A1 (en) 2013-10-18 2015-04-23 Exxonmobile Chemical Patents Inc. A hydrogenation catalyst, its method of preparation and use
DE102014223759A1 (de) 2014-11-20 2016-05-25 Wacker Chemie Ag Entfernung von Sauerstoff aus Kohlenwasserstoff-haltigen Gasgemischen
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Also Published As

Publication number Publication date
MX9301994A (es) 1994-06-30
FI931556A (fi) 1993-10-09
US5476963A (en) 1995-12-19
DE59303704D1 (de) 1996-10-17
ATE142535T1 (de) 1996-09-15
NZ247368A (en) 1995-07-26
EP0565952A1 (de) 1993-10-20
AU3677993A (en) 1993-10-14
NO931319D0 (no) 1993-04-06
BR9301467A (pt) 1993-10-13
AU657213B2 (en) 1995-03-02
NO931319L (no) 1993-10-11
US5422329A (en) 1995-06-06
DK0565952T3 (es) 1997-02-24
JPH067676A (ja) 1994-01-18
FI931556A0 (fi) 1993-04-06
MY110347A (en) 1998-04-30
CA2093610A1 (en) 1993-10-09
KR930021261A (ko) 1993-11-22
EP0565952B1 (de) 1996-09-11
TW330160B (en) 1998-04-21

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