ATE270145T1 - Verbessertes verfahren für die herstellung von palladium - gold- trägerkatalysatoren - Google Patents
Verbessertes verfahren für die herstellung von palladium - gold- trägerkatalysatorenInfo
- Publication number
- ATE270145T1 ATE270145T1 AT97945590T AT97945590T ATE270145T1 AT E270145 T1 ATE270145 T1 AT E270145T1 AT 97945590 T AT97945590 T AT 97945590T AT 97945590 T AT97945590 T AT 97945590T AT E270145 T1 ATE270145 T1 AT E270145T1
- Authority
- AT
- Austria
- Prior art keywords
- palladium
- production
- improved process
- supported catalysts
- gold
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- BBKFSSMUWOMYPI-UHFFFAOYSA-N gold palladium Chemical compound [Pd].[Au] BBKFSSMUWOMYPI-UHFFFAOYSA-N 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 150000002940 palladium Chemical class 0.000 abstract 1
- SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/741,543 US6022823A (en) | 1995-11-07 | 1996-10-31 | Process for the production of supported palladium-gold catalysts |
PCT/US1997/019996 WO1998018553A1 (en) | 1996-10-31 | 1997-10-29 | Improved process for the production of supported palladium-gold catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE270145T1 true ATE270145T1 (de) | 2004-07-15 |
Family
ID=24981136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT97945590T ATE270145T1 (de) | 1996-10-31 | 1997-10-29 | Verbessertes verfahren für die herstellung von palladium - gold- trägerkatalysatoren |
Country Status (11)
Country | Link |
---|---|
US (1) | US6022823A (de) |
EP (1) | EP0949965B1 (de) |
JP (1) | JP3978234B2 (de) |
KR (1) | KR100455846B1 (de) |
CN (1) | CN1104951C (de) |
AT (1) | ATE270145T1 (de) |
AU (1) | AU5102998A (de) |
BR (1) | BR9712398A (de) |
CA (1) | CA2268663C (de) |
DE (1) | DE69729744T2 (de) |
WO (1) | WO1998018553A1 (de) |
Families Citing this family (86)
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GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
ID26891A (id) * | 1998-06-02 | 2001-02-15 | Celanese Internasional Corp | Katalis vinil asetat yang terdiri dari palladium logam dan emas yang dibuat dengan potasium aurat |
JP2000070718A (ja) * | 1998-06-17 | 2000-03-07 | Nippon Shokubai Co Ltd | ベンジルエステルの製造方法 |
SG87005A1 (en) * | 1998-07-28 | 2002-03-19 | Dairen Chemical Corp | Preparation process of catalyst for producing alkenyl acetates and catalyst prepared by this process |
DE19914066A1 (de) * | 1999-03-27 | 2000-10-05 | Celanese Chem Europe Gmbh | Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung |
US6383273B1 (en) * | 1999-08-12 | 2002-05-07 | Apyron Technologies, Incorporated | Compositions containing a biocidal compound or an adsorbent and/or catalyst compound and methods of making and using therefor |
US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
US6576588B2 (en) * | 2000-04-07 | 2003-06-10 | Catalytic Distillation Technologies | Process for selective hydrogenation of alkynes and catalyst therefor |
US6420308B1 (en) * | 2000-07-07 | 2002-07-16 | Saudi Basic Industries Corp | Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate |
CN1281322C (zh) * | 2001-03-30 | 2006-10-25 | 国际壳牌研究有限公司 | 制备含viii族金属的催化剂的方法和该催化剂用于制备烯基羧酸酯的用途 |
JP4421201B2 (ja) * | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
US6936568B2 (en) | 2002-06-12 | 2005-08-30 | Sud-Chemie Inc. | Selective hydrogenation catalyst |
CN1314490C (zh) * | 2003-04-23 | 2007-05-09 | 中国石油化工股份有限公司 | 用于合成醋酸乙烯酯的催化剂的制备方法 |
US20050009694A1 (en) * | 2003-06-30 | 2005-01-13 | Watts Daniel J. | Catalysts and methods for making same |
MXPA06005834A (es) * | 2003-11-24 | 2007-01-26 | Michael Lefenfeld | Composiciones de gel de silice que contienen metales alcalinos y aleaciones de metal alcalino. |
TW201236755A (en) * | 2003-12-19 | 2012-09-16 | Celanese Int Corp | Halide free precursors for catalysts |
US7208646B2 (en) * | 2004-05-14 | 2007-04-24 | Catalytic Distillation Technologies | Selective hydrogenation of butadiene |
US7811541B2 (en) * | 2004-06-14 | 2010-10-12 | Signa Chemistry, Inc. | Silicide compositions containing alkali metals and methods of making the same |
CA2580930C (en) | 2004-09-22 | 2013-07-09 | Signa Chemistry Llc | Titanium oxide and alumina alkali metal compositions |
US7468455B2 (en) | 2004-11-03 | 2008-12-23 | Velocys, Inc. | Process and apparatus for improved methods for making vinyl acetate monomer (VAM) |
EP2380661A3 (de) | 2004-12-20 | 2012-02-01 | Celanese International Corporation | Modifizierte Trägermaterialien für Katalysatoren |
US20060173224A1 (en) * | 2005-02-01 | 2006-08-03 | Catalytic Distillation Technologies | Process and catalyst for selective hydrogenation of dienes and acetylenes |
US8227369B2 (en) * | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
DE102005040286A1 (de) * | 2005-08-25 | 2007-03-01 | Basf Ag | Mechanisch stabiler Katalysator auf Basis von alpha-Aluminiumoxid |
US8168562B2 (en) * | 2006-02-02 | 2012-05-01 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
US7348463B2 (en) * | 2006-03-27 | 2008-03-25 | Catalytic Distillation Technologies | Hydrogenation of aromatic compounds |
US8258070B2 (en) * | 2006-11-27 | 2012-09-04 | WGCH Technology Limited | Engine exhaust catalysts containing palladium-gold |
KR100917495B1 (ko) * | 2006-11-27 | 2009-09-16 | 나노스텔라 인코포레이티드 | 팔라듐-금을 포함하는 엔진 배기가스 촉매 |
US7534738B2 (en) | 2006-11-27 | 2009-05-19 | Nanostellar, Inc. | Engine exhaust catalysts containing palladium-gold |
US7709414B2 (en) * | 2006-11-27 | 2010-05-04 | Nanostellar, Inc. | Engine exhaust catalysts containing palladium-gold |
US7825204B2 (en) * | 2006-12-19 | 2010-11-02 | Lyondell Chemical Technology, L.P. | Inorganic oxide extrudates |
JP5196674B2 (ja) * | 2007-01-17 | 2013-05-15 | ナノステラー インコーポレイテッド | パラジウム−金を含有するエンジン排ガス触媒 |
US7811968B2 (en) * | 2007-05-11 | 2010-10-12 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
DE102007025443A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025223A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025442B4 (de) | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
DE102007025444A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025362A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007043446B4 (de) | 2007-09-12 | 2013-08-22 | Süd-Chemie Ip Gmbh & Co. Kg | Katalysatorträger mit erhöhter Wärmeleitfähigkeit |
DE102007043447B4 (de) | 2007-09-12 | 2014-02-13 | Süd-Chemie Ip Gmbh & Co. Kg | Katalysatorträger mit erhöhter thermischer Leitfähigkeit |
JP2009220099A (ja) * | 2008-02-20 | 2009-10-01 | Showa Denko Kk | 低級脂肪族カルボン酸製造用触媒の製造方法 |
US20100121100A1 (en) * | 2008-11-12 | 2010-05-13 | Daniel Travis Shay | Supported palladium-gold catalysts and preparation of vinyl acetate therewith |
DE102008059340A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie dessen Verwendung |
DE102008059341A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung |
DE102008059342A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung |
US8415269B2 (en) | 2009-01-21 | 2013-04-09 | WGCH Technology Limited | Palladium-gold catalyst synthesis |
JP5778131B2 (ja) * | 2009-03-30 | 2015-09-16 | インテリジェント エナジー リミテッドIntelligent Energy Limited | ナトリウムシリサイドおよびナトリウムシリカゲル物質を使用する水素生成システムおよび方法 |
US9102528B2 (en) | 2009-03-30 | 2015-08-11 | Intelligent Energy Limited | Hydrogen generation systems and methods utilizing sodium silicide and sodium silica gel materials |
US20110028770A1 (en) | 2009-08-03 | 2011-02-03 | Honeywell International Inc. | Hydrogenation catalyst |
US8263801B2 (en) | 2009-09-30 | 2012-09-11 | Lyondell Chemical Technology, L.P. | Process for producing allyl acetate |
US20110087047A1 (en) * | 2009-10-09 | 2011-04-14 | Noel Hallinan | Vinyl acetate production process |
BRPI1004975A2 (pt) * | 2009-12-08 | 2013-04-02 | Haldor Topsoe A/S | processo integrado para a produÇço de Ácido acÉtico, etileno e monâmero de acetato de vinila |
US20110137075A1 (en) * | 2009-12-09 | 2011-06-09 | Brtko Wayne J | Vinyl acetate production process |
US8329611B2 (en) * | 2009-12-16 | 2012-12-11 | Lyondell Chemical Technology, L,P. | Titania-containing extrudate |
US8507720B2 (en) * | 2010-01-29 | 2013-08-13 | Lyondell Chemical Technology, L.P. | Titania-alumina supported palladium catalyst |
WO2011075277A1 (en) | 2009-12-16 | 2011-06-23 | Lyondell Chemical Technology, L.P. | Titania-containing extrudate |
EP2544815B1 (de) | 2009-12-16 | 2016-01-06 | LyondellBasell Acetyls, LLC | Herstellung von Vinylacetat in Gegenwart eines Palladium-Katalysators dessen Träger aus Titanoxid und Aluminiumoxid besteht |
US8273682B2 (en) * | 2009-12-16 | 2012-09-25 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalyst |
US20120302439A1 (en) | 2009-12-31 | 2012-11-29 | Nanostellar, Inc. | Engine exhaust catalysts doped with bismuth or manganese |
GB201000638D0 (en) | 2010-01-15 | 2010-03-03 | Univ Birmingham | Improved catalyst |
US8895204B2 (en) | 2010-11-08 | 2014-11-25 | Intelligent Energy Limited | Water reactive hydrogen fuel cell power system |
US20110306748A1 (en) | 2010-06-11 | 2011-12-15 | Daniel Travis Shay | Titania-alumina-tungsta extrudate and its use |
US8519182B2 (en) | 2010-10-18 | 2013-08-27 | Lyondell Chemical Technology, L.P. | Acetic acid production process |
MX2013005185A (es) | 2010-11-08 | 2014-02-17 | Signa Chemistry Inc | Sistema de energia de celda de combustible de hidrogeno reactivo al agua. |
US8822717B2 (en) | 2010-11-24 | 2014-09-02 | LyondellBassell Acetyls, LLC | Vinyl acetate production process |
US20120149939A1 (en) | 2010-12-10 | 2012-06-14 | Celanese International Corporation | Recovery of Acetic Acid from Heavy Ends in Vinyl Acetate Synthesis Process |
WO2012124616A1 (ja) * | 2011-03-11 | 2012-09-20 | 宇部興産株式会社 | シュウ酸ジエステル製造用触媒及び当該触媒を用いたシュウ酸ジエステルの製造方法 |
US8399700B2 (en) | 2011-04-15 | 2013-03-19 | Lyondell Chemical Technology, L.P. | Vinyl acetate production process |
EP2703078A1 (de) * | 2012-09-03 | 2014-03-05 | Saudi Basic Industries Corporation | Photokatalysator enthaltend Gold-Palladium-Legierung, Verfahren zu dessen Herstellung und Photolysesystem |
TWI510293B (zh) | 2012-09-19 | 2015-12-01 | Clariant Int Ltd | 用於製造烯基羧酸酯之銅促進殼催化劑,及用於製造該銅促進殼催化劑之方法。 |
US20140081040A1 (en) * | 2012-09-20 | 2014-03-20 | Lyondell Chemical Technology, L.P. | Process for pre-treatment of a catalyst support and catalyst prepared therefrom |
DE112015004756T5 (de) | 2014-10-20 | 2017-09-28 | Velocys Technologies Limited | Verfahren der Entfernung von Wärme |
US9822053B2 (en) | 2016-01-28 | 2017-11-21 | Eastman Chemical Company | Single step conversion of N-butyraldehyde to 2-ethylhexanal |
US10780424B2 (en) | 2016-11-17 | 2020-09-22 | Lyondellbasell Acetyls, Llc | Crush strength and porosity of an alumina carrier for enhanced VAM catalysts |
WO2018093915A1 (en) | 2016-11-17 | 2018-05-24 | Lyondellbasell Acetyls, Llc | High pore volume alumina supported catalyst for vinyl acetate monomer (vam) process |
CN110523410B (zh) * | 2018-05-25 | 2020-12-01 | 中国科学院大连化学物理研究所 | 一种担载型催化剂的制备方法及其在橡胶促进剂dm合成中的应用 |
CN111774065B (zh) * | 2019-04-03 | 2023-01-10 | 中国石油化工股份有限公司 | 加氢脱金属催化剂的制备方法 |
JP7314712B2 (ja) * | 2019-08-21 | 2023-07-26 | 株式会社レゾナック | 酢酸アリル製造用触媒の製造方法 |
TW202128605A (zh) | 2019-12-19 | 2021-08-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造期間監測各式流之可燃性之方法及系統 |
CN111054333B (zh) * | 2020-02-14 | 2022-11-01 | 郑州轻工业大学 | 用于苯乙炔选择加氢制苯乙烯的水滑石负载钯催化剂及其制备方法和应用 |
CN111569874B (zh) * | 2020-05-28 | 2023-02-17 | 台州学院 | 一种活性炭-钯金镓液态合金复合催化剂及其制备方法和应用 |
TW202204039A (zh) * | 2020-06-11 | 2022-02-01 | 美商瑟蘭斯國際股份有限公司 | 用於乙酸乙烯酯製造之催化劑的製備方法 |
TW202204892A (zh) | 2020-06-29 | 2022-02-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造之金屬離子原位分析 |
CN114425328B (zh) * | 2020-09-27 | 2024-01-26 | 中国石油化工股份有限公司 | 一种α,α-二甲基苄醇氢解催化剂及其制备方法与应用 |
CN116099530A (zh) * | 2021-11-09 | 2023-05-12 | 中国科学院理化技术研究所 | 一种热辅助光催化氮气氧化制备硝酸用催化剂及其制备方法和应用 |
CN113976153B (zh) * | 2021-11-17 | 2022-09-16 | 中国科学院大连化学物理研究所 | 一种三元新相Pd3ZnCx催化剂的制备及其在乙炔选择加氢反应中的应用 |
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CA820352A (en) * | 1969-08-12 | Kronig Walter | Process for the production of organic esters | |
FR1383076A (fr) * | 1963-11-12 | 1964-12-24 | Pechiney Saint Gobain | Alumine active de grande porosité |
JPS514118A (en) * | 1974-06-27 | 1976-01-14 | Kuraray Co | Sakusanbiniruno seizohoho |
US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
FR2523149A1 (fr) * | 1982-03-15 | 1983-09-16 | Catalyse Soc Prod Francais | Nouveau catalyseur supporte palladium-or, sa preparation et son utilisation dans les reactions d'hydrogenation selective d'hydrocarbures diolefiniques et/ou acetyleniques |
JPS60171271A (ja) * | 1984-02-14 | 1985-09-04 | 三菱マテリアル株式会社 | 焼結体の原料粉末用2チタンアルミニウム窒化物粉末の製造法 |
DE4127918A1 (de) * | 1991-03-05 | 1992-09-10 | Interox Int Sa | Verfahren zur herstellung von wasserstoffperoxid |
US5194417A (en) * | 1991-12-05 | 1993-03-16 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
US5332710A (en) * | 1992-10-14 | 1994-07-26 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5314858A (en) * | 1992-10-14 | 1994-05-24 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
DE4323981C1 (de) * | 1993-07-16 | 1995-03-09 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
US5637548A (en) * | 1995-07-07 | 1997-06-10 | The Dow Chemical Company | Preparation of bimetallic catalysts for hydrodechlorination of chlorinated hydrocarbons |
US5691267A (en) * | 1996-04-16 | 1997-11-25 | Hoechst Celanese Corporation | Two step gold addition method for preparing a vinyl acetate catalyst |
US5693586A (en) * | 1996-06-28 | 1997-12-02 | Hoechst Celanese Corporation | Palladium-gold catalyst for vinyl acetate production |
-
1996
- 1996-10-31 US US08/741,543 patent/US6022823A/en not_active Expired - Lifetime
-
1997
- 1997-10-29 DE DE69729744T patent/DE69729744T2/de not_active Expired - Lifetime
- 1997-10-29 JP JP52081698A patent/JP3978234B2/ja not_active Expired - Lifetime
- 1997-10-29 KR KR10-1999-7003800A patent/KR100455846B1/ko not_active IP Right Cessation
- 1997-10-29 CA CA002268663A patent/CA2268663C/en not_active Expired - Lifetime
- 1997-10-29 AT AT97945590T patent/ATE270145T1/de not_active IP Right Cessation
- 1997-10-29 AU AU51029/98A patent/AU5102998A/en not_active Abandoned
- 1997-10-29 CN CN97199336A patent/CN1104951C/zh not_active Expired - Lifetime
- 1997-10-29 WO PCT/US1997/019996 patent/WO1998018553A1/en active IP Right Grant
- 1997-10-29 EP EP97945590A patent/EP0949965B1/de not_active Expired - Lifetime
- 1997-10-29 BR BR9712398-6A patent/BR9712398A/pt not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CA2268663C (en) | 2007-02-06 |
US6022823A (en) | 2000-02-08 |
WO1998018553A1 (en) | 1998-05-07 |
EP0949965A1 (de) | 1999-10-20 |
CN1104951C (zh) | 2003-04-09 |
CN1235561A (zh) | 1999-11-17 |
DE69729744D1 (de) | 2004-08-05 |
KR100455846B1 (ko) | 2004-11-08 |
BR9712398A (pt) | 1999-08-31 |
KR20000052930A (ko) | 2000-08-25 |
JP3978234B2 (ja) | 2007-09-19 |
AU5102998A (en) | 1998-05-22 |
DE69729744T2 (de) | 2005-07-14 |
EP0949965B1 (de) | 2004-06-30 |
CA2268663A1 (en) | 1998-05-07 |
JP2001503321A (ja) | 2001-03-13 |
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