ES2067695T3 - Metodo para la produccion de acido acrilico. - Google Patents

Metodo para la produccion de acido acrilico.

Info

Publication number
ES2067695T3
ES2067695T3 ES90312130T ES90312130T ES2067695T3 ES 2067695 T3 ES2067695 T3 ES 2067695T3 ES 90312130 T ES90312130 T ES 90312130T ES 90312130 T ES90312130 T ES 90312130T ES 2067695 T3 ES2067695 T3 ES 2067695T3
Authority
ES
Spain
Prior art keywords
equal
less
production
acrylic acid
selected element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90312130T
Other languages
English (en)
Inventor
Tatsuya Kawajiri
Shinichi Uchida
Hideyuki Hironaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Application granted granted Critical
Publication of ES2067695T3 publication Critical patent/ES2067695T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

UN METODO PARA LA PRODUCCION DE ACIDO ACRILICO POR OXIDACION DE LA FASE GASEOSA DE LA ACROLEINA CON UN GAS CONTENIENDO OXIGENO MOLECULAR EN PRESENCIA DE UN CATALIZADOR FORMADO POR UN OXIDO O UN COMPUESTO DE OXIDO DE UNA COMPOSICION DE ELEMENTO METALICO REPRESENTADA POR LA SIGUIENTE FORMULA I: DONDE X ES AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO CONSISTENTE DE ZR, TI Y CE, Y ES AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO CONSISTENTE DE MG CA, SR Y BA Y LOS SUBESCRITOS A, B, C, D, E Y F SON TALES QUE B = 2 A 14, 0<C (MENOR O IGUAL) 12, 0<D (MENOR O IGUAL) 6, 0<E (MENOR O IGUAL) 10, Y F = 0 A 3 DONDE A ESTA FIJA EN 12, 2.0<CU+X (MENOR O IGUAL) 10.0 Y 0.25 (MENOR O IGUAL) CU/X (MENOR O IGUAL) 6.0.
ES90312130T 1989-11-06 1990-11-06 Metodo para la produccion de acido acrilico. Expired - Lifetime ES2067695T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28751889 1989-11-06

Publications (1)

Publication Number Publication Date
ES2067695T3 true ES2067695T3 (es) 1995-04-01

Family

ID=17718382

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90312130T Expired - Lifetime ES2067695T3 (es) 1989-11-06 1990-11-06 Metodo para la produccion de acido acrilico.

Country Status (11)

Country Link
US (1) US5177260A (es)
EP (1) EP0427508B1 (es)
KR (1) KR950003119B1 (es)
CN (2) CN1031050C (es)
AU (1) AU639500B2 (es)
BR (1) BR9005603A (es)
CA (1) CA2029277A1 (es)
DE (1) DE69016590T2 (es)
ES (1) ES2067695T3 (es)
MX (1) MX171566B (es)
RU (1) RU2024296C1 (es)

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DE4302991A1 (de) * 1993-02-03 1994-08-04 Basf Ag Multimetalloxidmassen
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TW349033B (en) * 1994-05-31 1999-01-01 Nippon Catalytic Chem Ind Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalysta catalyst for the production of methacrylic acid by the vapor-phase catalytic oxidation and/or oxidative dehydrogenation of at least one compound
DE4431949A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure
EP0811597B1 (en) * 1994-11-14 2000-08-23 Nippon Shokubai Co., Ltd. Process for production of acrylic acid
JP3786297B2 (ja) * 1995-03-03 2006-06-14 日本化薬株式会社 触媒の製造方法
JP3537253B2 (ja) * 1996-03-06 2004-06-14 株式会社日本触媒 アクリル酸の製造方法
DE19622331A1 (de) 1996-06-04 1997-12-11 Basf Ag Verfahren der heterogen katalysierten Gasphasenoxidation von Propan zu Acrolein
MY121878A (en) * 1999-03-10 2006-02-28 Basf Ag Method for the catalytic gas-phase oxidation of propene into acrylic acid
US6500982B1 (en) 1999-06-28 2002-12-31 Rohm And Haas Company Process for preparing (meth) acrylic acid
US6639106B1 (en) 1999-07-23 2003-10-28 Rohm And Haas Company Process for preparing and purifying acrylic acid from propylene having improved capacity
US6620968B1 (en) 1999-11-23 2003-09-16 Rohm And Haas Company High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
JP3744750B2 (ja) * 1999-12-08 2006-02-15 株式会社日本触媒 複合酸化物触媒およびアクリル酸の製造方法
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
US6444845B1 (en) 2000-04-28 2002-09-03 Saudia Basic Industries Corporation Process for the oxidation of unsaturated aldehydes to produce carboxylic acids using Mo-V based catalysts
FR2811243A1 (fr) * 2000-07-04 2002-01-11 Atofina Compositions solides utiles dans la fabrication de l'acide acrylique par oxydation de l'acroleine
JP5134745B2 (ja) 2001-09-19 2013-01-30 株式会社日本触媒 アクリル酸の製造方法
DE60133473T2 (de) 2001-12-14 2009-05-20 Evonik Stockhausen Gmbh Verfahren zur Herstellung von Acrylsäure
WO2003057653A1 (fr) * 2001-12-28 2003-07-17 Mitsubishi Chemical Corporation Procede d'oxydation catalytique en phase vapeur
KR100497173B1 (ko) * 2002-11-29 2005-06-28 주식회사 엘지화학 아크롤레인의 부분 산화 반응용 촉매의 제조방법
BRPI0413440A (pt) 2003-08-14 2006-10-17 Basf Ag processo para a preparação de (met) acroleìna e/ou de ácido (met) acrìlico por oxidação parcial em fase gasosa catalisada heterogeneamente
JP2005336142A (ja) * 2004-05-31 2005-12-08 Mitsubishi Chemicals Corp （メタ）アクリル酸の製造装置及び（メタ）アクリル酸の製造方法
MX2008015540A (es) 2007-12-26 2009-06-26 Rohm Ahd Haas Company Un proceso integrado para preparar un acido carboxilico a partir de un alcano.
EP2143704A1 (en) 2008-07-10 2010-01-13 Rohm and Haas Company An integrated process for preparing a carboxylic acid from an alkane
CN102076411B (zh) * 2008-09-30 2013-02-13 株式会社日本触媒 用于制备丙烯醛和/或丙烯酸的催化剂以及使用了该催化剂的丙烯醛和/或丙烯酸的制备方法
SG172273A1 (en) 2008-12-26 2011-07-28 Nippon Catalytic Chem Ind Process for producing acrylic acid
CN101507927B (zh) * 2009-02-10 2011-12-21 上海华谊丙烯酸有限公司 一种复合氧化物催化剂的制备方法及其在合成丙烯酸工艺中的应用
CN102039141B (zh) * 2009-10-13 2012-11-14 中国石油化工股份有限公司 由不饱和醛氧化制不饱和酸的催化剂及其制备方法
CN102040505B (zh) * 2009-10-13 2014-04-23 中国石油化工股份有限公司 由不饱和醛氧化制不饱和酸的方法
CN102770403A (zh) 2009-12-04 2012-11-07 巴斯夫欧洲公司 由生物乙醇制备乙醛和/或乙酸
CN102371158A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 氧化法制丙烯酸催化剂及其制备方法
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
CA2781246A1 (en) 2011-07-14 2013-01-14 Rohm And Haas Company Method for removal of organic compounds from waste water streams in a process for production of (meth)acrylic acid
KR102586150B1 (ko) 2016-12-21 2023-10-06 코닝 인코포레이티드 소결 시스템 및 소결된 물품
CN109304157A (zh) * 2017-07-28 2019-02-05 中国石油化工股份有限公司 丙烯醛氧化制丙烯酸的催化剂
CN110694635A (zh) * 2019-11-25 2020-01-17 上海华谊新材料有限公司 钼钒系复合氧化物催化剂、其制备方法和用途

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Also Published As

Publication number Publication date
DE69016590D1 (de) 1995-03-16
BR9005603A (pt) 1991-09-17
CN1070468C (zh) 2001-09-05
CN1031050C (zh) 1996-02-21
AU6587690A (en) 1991-05-09
CA2029277A1 (en) 1991-05-07
AU639500B2 (en) 1993-07-29
KR910009625A (ko) 1991-06-28
EP0427508B1 (en) 1995-02-01
EP0427508A1 (en) 1991-05-15
RU2024296C1 (ru) 1994-12-15
CN1121504A (zh) 1996-05-01
MX171566B (es) 1993-11-05
US5177260A (en) 1993-01-05
CN1054972A (zh) 1991-10-02
DE69016590T2 (de) 1995-06-01
KR950003119B1 (ko) 1995-04-01

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