JPS6466142A - Production of unsaturated carboxylic acid and ester thereof - Google Patents

Production of unsaturated carboxylic acid and ester thereof

Info

Publication number
JPS6466142A
JPS6466142A JP62223778A JP22377887A JPS6466142A JP S6466142 A JPS6466142 A JP S6466142A JP 62223778 A JP62223778 A JP 62223778A JP 22377887 A JP22377887 A JP 22377887A JP S6466142 A JPS6466142 A JP S6466142A
Authority
JP
Japan
Prior art keywords
catalyst
raw material
methyl
ester
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62223778A
Other languages
Japanese (ja)
Inventor
Mamoru So
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP62223778A priority Critical patent/JPS6466142A/en
Publication of JPS6466142A publication Critical patent/JPS6466142A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

PURPOSE:To obtain the titled compound from a raw material gas containing methyl acetate or methyl propionate and O2 in one stage reaction and good yield and further re-utilize the by-product, by using a P-V-Ti-O based catalyst reduced in V content and having a specific composition as a catalyst. CONSTITUTION:When a raw material gas containing methyl acetate or methyl propionate and O2 is brought into contact with a catalyst to provide acrylic acid, methyl acrylate or methacrylic acid or methyl methacrylate, a catalyst containing an ingredient expressed by the formula PaVbTicOd (a-d are each atomic numbers and when a+b+c are 100mol.%, b is 2-20mol%, c is 10-50mol.% and d is valence required for satisfying valence of ingredients excluding O) is used. Methanol can be preferably and further added to the raw material.
JP62223778A 1987-09-07 1987-09-07 Production of unsaturated carboxylic acid and ester thereof Pending JPS6466142A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62223778A JPS6466142A (en) 1987-09-07 1987-09-07 Production of unsaturated carboxylic acid and ester thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62223778A JPS6466142A (en) 1987-09-07 1987-09-07 Production of unsaturated carboxylic acid and ester thereof

Publications (1)

Publication Number Publication Date
JPS6466142A true JPS6466142A (en) 1989-03-13

Family

ID=16803564

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62223778A Pending JPS6466142A (en) 1987-09-07 1987-09-07 Production of unsaturated carboxylic acid and ester thereof

Country Status (1)

Country Link
JP (1) JPS6466142A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111763145A (en) * 2019-11-22 2020-10-13 中国科学院大连化学物理研究所 Method for synthesizing acrylic acid from methyl acetate aqueous solution
CN114394893A (en) * 2022-01-06 2022-04-26 北京大学 Method for directly preparing acrylic acid from methyl acetate and catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111763145A (en) * 2019-11-22 2020-10-13 中国科学院大连化学物理研究所 Method for synthesizing acrylic acid from methyl acetate aqueous solution
CN114394893A (en) * 2022-01-06 2022-04-26 北京大学 Method for directly preparing acrylic acid from methyl acetate and catalyst

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