JPS6468335A - Production of unsaturated carboxylic acid and ester thereof - Google Patents
Production of unsaturated carboxylic acid and ester thereofInfo
- Publication number
- JPS6468335A JPS6468335A JP62224798A JP22479887A JPS6468335A JP S6468335 A JPS6468335 A JP S6468335A JP 62224798 A JP62224798 A JP 62224798A JP 22479887 A JP22479887 A JP 22479887A JP S6468335 A JPS6468335 A JP S6468335A
- Authority
- JP
- Japan
- Prior art keywords
- ester
- catalyst
- raw material
- material gas
- acetic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE:To readily obtain the titled compound having one more carbon atom in good yield, by bringing a raw material gas containing saturated monocarboxylic acids, such as acetic acid and ester thereof, and formaldehydes into contact with a catalyst having a P-V-Ti-O based composition. CONSTITUTION:A raw material gas containing acetic acid and/or an ester thereof or propionic acid and/or an ester thereof and formaldehyde and/or a derivative thereof is brought into contact with a catalyst containing a component expressed by the formula (P, V, Ti and O are phosphorus, vanadium, titanium and oxygen; a, b, c and d each are the numbers of P, V, Ti and O atoms; b is 2-20mol.%; c is 10-50mol.%; d is the number required to satisfy the valences of the components except O when a+b+c is 100mol.%) to afford the aimed compound. The catalyst used is obtained by heat-treating a mixture or reaction product of ammonium salts, halides, oxides, etc., of the component elements.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62224798A JPS6468335A (en) | 1987-09-08 | 1987-09-08 | Production of unsaturated carboxylic acid and ester thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62224798A JPS6468335A (en) | 1987-09-08 | 1987-09-08 | Production of unsaturated carboxylic acid and ester thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6468335A true JPS6468335A (en) | 1989-03-14 |
Family
ID=16819367
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62224798A Pending JPS6468335A (en) | 1987-09-08 | 1987-09-08 | Production of unsaturated carboxylic acid and ester thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6468335A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5195736A (en) * | 1990-09-19 | 1993-03-23 | Oki Electric Industry Co., Ltd. | Method and apparatus for feeding sheets |
WO2013039715A1 (en) | 2011-09-16 | 2013-03-21 | Eastman Chemical Company | PROCESS FOR PREPARING V-Ti-P CATALYSTS FOR SYNTHESIS OF 2,3-UNSATURATED CARBOXYLIC ACIDS |
WO2013039716A1 (en) | 2011-09-16 | 2013-03-21 | Eastman Chemical Company | Process for preparing modified v-ti-p catalysts for synthesis of 2,3-unsaturated carboxylic acids |
WO2014158794A1 (en) | 2013-03-14 | 2014-10-02 | Eastman Chemical Company | Process for preparing v- ti-p catalysts for synthesis of 2,3-unsaturated carboxylic acids |
JP2014534167A (en) * | 2011-09-16 | 2014-12-18 | イーストマン ケミカル カンパニー | Catalytic dehydration of alcohols and ethers over ternary mixed oxides |
US8993801B2 (en) | 2011-09-16 | 2015-03-31 | Eastman Chemical Company | Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US9573119B2 (en) | 2011-09-16 | 2017-02-21 | Eastman Chemical Company | Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
-
1987
- 1987-09-08 JP JP62224798A patent/JPS6468335A/en active Pending
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5195736A (en) * | 1990-09-19 | 1993-03-23 | Oki Electric Industry Co., Ltd. | Method and apparatus for feeding sheets |
JP2014531973A (en) * | 2011-09-16 | 2014-12-04 | イーストマン ケミカル カンパニー | Process for the preparation of V-Ti-P catalysts for the synthesis of 2,3-unsaturated carboxylic acids |
WO2013039716A1 (en) | 2011-09-16 | 2013-03-21 | Eastman Chemical Company | Process for preparing modified v-ti-p catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US8765629B2 (en) | 2011-09-16 | 2014-07-01 | Eastman Chemical Company | Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US8883672B2 (en) | 2011-09-16 | 2014-11-11 | Eastman Chemical Company | Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
WO2013039715A1 (en) | 2011-09-16 | 2013-03-21 | Eastman Chemical Company | PROCESS FOR PREPARING V-Ti-P CATALYSTS FOR SYNTHESIS OF 2,3-UNSATURATED CARBOXYLIC ACIDS |
JP2014534167A (en) * | 2011-09-16 | 2014-12-18 | イーストマン ケミカル カンパニー | Catalytic dehydration of alcohols and ethers over ternary mixed oxides |
US8993801B2 (en) | 2011-09-16 | 2015-03-31 | Eastman Chemical Company | Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US9493390B2 (en) | 2011-09-16 | 2016-11-15 | Eastman Chemical Company | Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US9573119B2 (en) | 2011-09-16 | 2017-02-21 | Eastman Chemical Company | Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US9861965B2 (en) | 2011-09-16 | 2018-01-09 | Eastman Chemical Company | Process for preparing modified V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
US10065180B2 (en) | 2011-09-16 | 2018-09-04 | Eastman Chemical Company | Process for preparing modified V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids |
WO2014158794A1 (en) | 2013-03-14 | 2014-10-02 | Eastman Chemical Company | Process for preparing v- ti-p catalysts for synthesis of 2,3-unsaturated carboxylic acids |
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