JPS5748941A - Preparation of 3-pentenoic acid ester - Google Patents

Preparation of 3-pentenoic acid ester

Info

Publication number
JPS5748941A
JPS5748941A JP55124255A JP12425580A JPS5748941A JP S5748941 A JPS5748941 A JP S5748941A JP 55124255 A JP55124255 A JP 55124255A JP 12425580 A JP12425580 A JP 12425580A JP S5748941 A JPS5748941 A JP S5748941A
Authority
JP
Japan
Prior art keywords
pyridine
butadiene
alkyl
catalyst
acid ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP55124255A
Other languages
Japanese (ja)
Other versions
JPS5912657B2 (en
Inventor
Yoshio Isogai
Motomasa Hosokawa
Takashi Okawa
Natsuko Wakui
Toshiyasu Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Priority to JP55124255A priority Critical patent/JPS5912657B2/en
Priority to US06/199,332 priority patent/US4332966A/en
Priority to DE19803040432 priority patent/DE3040432C2/en
Publication of JPS5748941A publication Critical patent/JPS5748941A/en
Publication of JPS5912657B2 publication Critical patent/JPS5912657B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To prepare the titled compound, economically, in an industrial scale, by the hydroesterification of butadiene in the presence of a cobalt carbonyl catalyst, using a mixed solvent composed of two or more compounds selected from pyridine and its alkyl-substituted derivatives.
CONSTITUTION: In the preparation of a 3-pentenoic acid ester by the reaction of butadiene, carbon monoxide and an alcohol in the presence of a cobalt carbonyl catalyst, a sufficiently high reaction rate can be attained with a small amount of catalyst, various side reactions can be suppressed, and the selectively and the yield can be improved by the use of a mixed solvent composed of two or more compounds selected from pyridine and its alkyl derivatives as a reaction solvent. Accordingly, the process enables the effective utilization of the raw material butadiene at a low catalyst cost, and has high efficiency from the industrial viewpoint. The alkyl-substituted derivative of pyridine is esp. pref. β- or γ-picoline, or 3,4- or 3,5-lutidine.
COPYRIGHT: (C)1982,JPO&Japio
JP55124255A 1979-10-27 1980-09-08 Method for producing 3-pentenoic acid ester Expired JPS5912657B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP55124255A JPS5912657B2 (en) 1980-09-08 1980-09-08 Method for producing 3-pentenoic acid ester
US06/199,332 US4332966A (en) 1979-12-17 1980-10-21 Process for producing 3-pentenoic esters
DE19803040432 DE3040432C2 (en) 1979-10-27 1980-10-27 Process for the preparation of 3-pentenoic acid esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55124255A JPS5912657B2 (en) 1980-09-08 1980-09-08 Method for producing 3-pentenoic acid ester

Publications (2)

Publication Number Publication Date
JPS5748941A true JPS5748941A (en) 1982-03-20
JPS5912657B2 JPS5912657B2 (en) 1984-03-24

Family

ID=14880795

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55124255A Expired JPS5912657B2 (en) 1979-10-27 1980-09-08 Method for producing 3-pentenoic acid ester

Country Status (1)

Country Link
JP (1) JPS5912657B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0267497A2 (en) * 1986-11-08 1988-05-18 BASF Aktiengesellschaft Process for the manufacture of alkyl esters of pentenoic acid and their application
JPS6450842A (en) * 1987-07-30 1989-02-27 Basf Ag Manufacture of alkylpentenoate
JPH0426653A (en) * 1990-05-21 1992-01-29 Agency Of Ind Science & Technol Production 3-pentenoic acid ester

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0267497A2 (en) * 1986-11-08 1988-05-18 BASF Aktiengesellschaft Process for the manufacture of alkyl esters of pentenoic acid and their application
JPS6450842A (en) * 1987-07-30 1989-02-27 Basf Ag Manufacture of alkylpentenoate
JPH0426653A (en) * 1990-05-21 1992-01-29 Agency Of Ind Science & Technol Production 3-pentenoic acid ester

Also Published As

Publication number Publication date
JPS5912657B2 (en) 1984-03-24

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