JPS5686133A - Production of 3-pentenoic ester - Google Patents

Production of 3-pentenoic ester

Info

Publication number
JPS5686133A
JPS5686133A JP16384079A JP16384079A JPS5686133A JP S5686133 A JPS5686133 A JP S5686133A JP 16384079 A JP16384079 A JP 16384079A JP 16384079 A JP16384079 A JP 16384079A JP S5686133 A JPS5686133 A JP S5686133A
Authority
JP
Japan
Prior art keywords
butadiene
isoquinoline
pyridine
catalyst
hydroesterification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16384079A
Other languages
Japanese (ja)
Other versions
JPS5826901B2 (en
Inventor
Yoshio Isogai
Motomasa Hosokawa
Takashi Okawa
Natsuko Wakui
Toshiyasu Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Priority to JP54163840A priority Critical patent/JPS5826901B2/en
Priority to US06/199,332 priority patent/US4332966A/en
Priority to DE19803040432 priority patent/DE3040432C2/en
Publication of JPS5686133A publication Critical patent/JPS5686133A/en
Publication of JPS5826901B2 publication Critical patent/JPS5826901B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

PURPOSE: The hydroesterification of butadiene is effected in the presence of a small amount of cobalt carbonyl catalyst using a solvent mixture composed of pyridine and isoquinoline to produce the titled compound in high selectivity and yield with high industrial efficiency.
CONSTITUTION: The reaction between butadiene, carbon monoxide and a lower alcohol such as methanol is conducted in a solvent mixture composed of pyridine and isoquinoline in the presence of a cobalt carbonyl catalyst such as dicobalt octacarbonyl at 100W140°C under 100W300kg/cm2 carbon monoxide partial pressure to produce 3-pentenoic ester. The molar ratio of pyridine to isoquinoline is 1/(0.05W 10), preferably (0.1W5). The amount of the catalyst is 0.05W0.02mol/mol of butadiene.
EFFECT: A raw material, butadiene, is effectively utilized in low catalyst costs and the process is greatly significant as an industrial hydroesterification one.
COPYRIGHT: (C)1981,JPO&Japio
JP54163840A 1979-10-27 1979-12-17 Method for producing 3-pentenoic acid ester Expired JPS5826901B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP54163840A JPS5826901B2 (en) 1979-12-17 1979-12-17 Method for producing 3-pentenoic acid ester
US06/199,332 US4332966A (en) 1979-12-17 1980-10-21 Process for producing 3-pentenoic esters
DE19803040432 DE3040432C2 (en) 1979-10-27 1980-10-27 Process for the preparation of 3-pentenoic acid esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54163840A JPS5826901B2 (en) 1979-12-17 1979-12-17 Method for producing 3-pentenoic acid ester

Publications (2)

Publication Number Publication Date
JPS5686133A true JPS5686133A (en) 1981-07-13
JPS5826901B2 JPS5826901B2 (en) 1983-06-06

Family

ID=15781742

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54163840A Expired JPS5826901B2 (en) 1979-10-27 1979-12-17 Method for producing 3-pentenoic acid ester

Country Status (1)

Country Link
JP (1) JPS5826901B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS615051A (en) * 1984-04-10 1986-01-10 バスフ　アクチエン　ゲゼルシヤフト Method of obtaining pentenoic acid c1-c4-alkyl ester

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS615051A (en) * 1984-04-10 1986-01-10 バスフ　アクチエン　ゲゼルシヤフト Method of obtaining pentenoic acid c1-c4-alkyl ester
JPH0579658B2 (en) * 1984-04-10 1993-11-04 Basf Ag

Also Published As

Publication number Publication date
JPS5826901B2 (en) 1983-06-06

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