EP4373989A1 - Tôle à revêtement znaimg à flexibilité améliorée et procédé de réalisation correspondant - Google Patents
Tôle à revêtement znaimg à flexibilité améliorée et procédé de réalisation correspondantInfo
- Publication number
- EP4373989A1 EP4373989A1 EP14795864.9A EP14795864A EP4373989A1 EP 4373989 A1 EP4373989 A1 EP 4373989A1 EP 14795864 A EP14795864 A EP 14795864A EP 4373989 A1 EP4373989 A1 EP 4373989A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal coating
- weight
- bath
- magnesium
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 110
- 239000011248 coating agent Substances 0.000 title claims abstract description 98
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 95
- 239000002184 metal Substances 0.000 title claims abstract description 95
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000758 substrate Substances 0.000 claims abstract description 20
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 19
- 239000011777 magnesium Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000012535 impurity Substances 0.000 claims abstract description 16
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 16
- 239000011701 zinc Substances 0.000 claims abstract description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 12
- 239000010936 titanium Substances 0.000 claims abstract description 11
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 11
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 9
- 239000010959 steel Substances 0.000 claims abstract description 9
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 8
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 8
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
- 238000010422 painting Methods 0.000 claims abstract description 8
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- 238000000151 deposition Methods 0.000 claims abstract description 5
- 238000010791 quenching Methods 0.000 claims abstract description 5
- 230000000171 quenching effect Effects 0.000 claims abstract description 5
- 239000003973 paint Substances 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 229920000728 polyester Polymers 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 11
- 238000007711 solidification Methods 0.000 claims description 11
- 230000008023 solidification Effects 0.000 claims description 11
- 238000005238 degreasing Methods 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- YOYLLRBMGQRFTN-SMCOLXIQSA-N norbuprenorphine Chemical compound C([C@@H](NCC1)[C@]23CC[C@]4([C@H](C3)C(C)(O)C(C)(C)C)OC)C3=CC=C(O)C5=C3[C@@]21[C@H]4O5 YOYLLRBMGQRFTN-SMCOLXIQSA-N 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 11
- 239000000243 solution Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 230000004075 alteration Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000005246 galvanizing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 239000000347 magnesium hydroxide Substances 0.000 description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- DXIGZHYPWYIZLM-UHFFFAOYSA-J tetrafluorozirconium;dihydrofluoride Chemical compound F.F.F[Zr](F)(F)F DXIGZHYPWYIZLM-UHFFFAOYSA-J 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- -1 zinc-aluminum-magnesium Chemical compound 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/265—After-treatment by applying solid particles to the molten coating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/361—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing titanium, zirconium or hafnium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/19—Iron or steel
Definitions
- the present invention relates to a sheet comprising a substrate of which at least one face is coated with a metal coating comprising Al and Mg, the remainder of the metal coating being Zn, unavoidable impurities and optionally one or more additional elements. selected from Si, Ti, Ca, Mn, La, Ce and Bi, the weight content of each additional element in the metal coating being less than 0.3%.
- Galvanized metal coatings consisting essentially of zinc and 0.1 to 0.4% by weight of aluminum are traditionally used for their good protection against corrosion.
- Such metal coatings will generally be referred to herein as zinc-aluminum-magnesium or ZnAIMg coatings.
- magnesium significantly increases the corrosion resistance of steels coated with a metal coating, which can reduce the thickness of the metal coating or increase the guarantee of protection against corrosion over time at constant thickness .
- These sheets coated with a ZnAIMg coating are for example intended for the automotive field, household electrical appliance or construction.
- JP2010255084 it is known from JP2010255084 to improve the resistance to cracking by adding from 0.005 to 0.2% by weight of nickel to a metal coating comprising moreover 1 to 10% by weight of aluminum and 0.2 to 1% by weight. magnesium weight.
- the Nickel thus added has the characteristic of being
- Nickel migration at the steel-metal interface is difficult to perform and introduces additional manufacturing constraints.
- the present invention aims to overcome the aforementioned problems by proposing a ZnAIMg sheet whose metal coating crack less on severe folds, while retaining the advantages of ZnAIMg coating in terms of corrosion resistance.
- the invention firstly relates to a method for producing a prepainted sheet comprising at least the steps of:
- a metal coating on at least one face by quenching the substrate in a bath consisting of 4.4% to 5.6% by weight of aluminum and 0.3% to 0.56% by weight of magnesium, the remainder of the bath being exclusively zinc, unavoidable impurities related to the process and optionally one or more additional elements selected from the group consisting of Si, Ti, Ca, Mn, La, Ce and Bi, the content by weight of each additional element in the metal coating being less than 0.3%, the presence of nickel being excluded,
- the method according to the invention may also comprise the following optional characteristics, taken alone or in combination:
- the bath comprises from 4.75 to 5.25% by weight of aluminum, the bath comprises from 0.44 to 0.56% by weight of magnesium,
- the bath is at a temperature of between 370 ° C. and 470 ° C.
- the solidification of the metal coating is carried out at a cooling rate of the metal coating between the beginning of the solidification and the end of the solidification greater than or equal to 15 ° C / s,
- the cooling rate is between 15 and 35 ° C / s
- the surface preparation comprises a step chosen from a rinsing, a degreasing and a conversion treatment,
- the degreasing is carried out at a pH of between 12 and 13,
- the conversion treatment is based on hexafluorotitanic acid
- the painting of the metallic coating is carried out by means of a paint comprising at least one polymer chosen from the group consisting of melamine-crosslinked polyesters, isocyanate-crosslinked polyesters, polyurethanes and halogenated derivatives of vinyl polymers, exclusion of cataphoretic paints.
- the solution to the technical problem consists in combining a paint film and a metal coating having a particular composition. Surprisingly, it has been found by the inventors that this combination has an action synergy so that the ZnAIMg coating according to the invention has fewer cracks on the severe folds when it is covered with a film of paint than when he is naked.
- a second subject of the invention consists of a pre-painted sheet comprising a steel substrate of which at least one face is coated with a metal coating consisting of 4.4% to 5.6% by weight of aluminum and 0.3% 0.56% by weight of magnesium, the remainder of the metal coating being exclusively zinc, unavoidable impurities related to the process and optionally one or more additional elements selected from the group consisting of Si, Ti, Ca, Mn, La, Ce and Bi, the weight content of each additional element in the metal coating being less than 0.3%, the presence of nickel in the metal coating being excluded, the metal coating being covered with at least one paint film.
- the sheet according to the invention may also comprise the following optional characteristics, taken alone or in combination:
- the metal coating comprises from 4.75 to 5.25% by weight of aluminum
- the metal coating comprises from 0.44 to 0.56% by weight of magnesium
- the metal coating does not include any additional element
- the paint film comprises at least one polymer chosen from the group consisting of melamine-crosslinked polyesters, isocyanate-crosslinked polyesters, polyurethanes and halogenated derivatives of vinyl polymers, with the exception of cataphoretic paints,
- a conversion layer comprising titanium is located at the interface between the metal coating and the paint film.
- the sheet comprises a steel substrate coated on at least one of its faces with a metal coating, itself covered with at least one paint film.
- the metal coating generally has a thickness of less than or equal to 25 ⁇ m and is intended to protect the substrate against corrosion.
- the metal coating consists of aluminum and magnesium, the remainder of the metal coating being exclusively zinc, unavoidable impurities related to the deposition process of the metal coating and optionally one or more additional elements selected from Si, Ti, Ca, Mn, La, Ce and Bi, the weight content of each additional element in the metal coating being less than 0.3%, the presence of nickel being excluded.
- the weight content of aluminum of the metal coating is between 4.4 and 5.6%. This range of aluminum weight content promotes the formation of Zn / Al binary eutectic in the microstructure of the metal coating. This eutectic is particularly ductile and promotes the obtaining of a flexible metal coating.
- the content by weight of aluminum is between 4.75 and
- the content by weight of aluminum is measured without taking into account the aluminum-rich intermetallic located at the interface substrate-metal coating. Such a measurement can for example be carried out by glow discharge spectrometry. A measurement by chemical dissolution would lead to the simultaneous dissolution of the metal coating and intermetallic and give an over-estimated aluminum content by weight of the order of 0.05 to 0.5% depending on the thickness of the metal coating.
- the weight content of magnesium metal coating is between 0.3 and 0.56%. Below 0.3%, the improvement in the resistance to corrosion provided by magnesium is no longer sufficient. Above 0.56%, the synergistic action of the paint film and the metal coating according to the invention is no longer observed.
- the weight content of magnesium is between 0.44 and 0.56%, which constitutes the best compromise in terms of corrosion resistance and flexibility.
- the unavoidable impurities come from the feed ingots of the molten zinc bath or result from the passage of the substrate in the bath.
- the most common unavoidable impurity resulting from the passage of the substrate in the bath is iron which may be present at a content of up to 0.8% by weight of the metal coating, generally less than or equal to 0.4% and generally between 0.1 and 0.4% by weight.
- the unavoidable impurities from the ingots are generally lead (Pb), present at a content of less than 0.01% by weight, Cadmium (Cd), present at a content of less than 0.005% by weight and tin (Sn), present at a content of less than 0.001% by weight. It should be noted here that nickel is not an unavoidable impurity related to the galvanizing process.
- the various additional elements may make it possible, inter alia, to improve the ductility or adhesion of the metal coating to the substrate.
- the metal coating does not include nickel as an additional element, nickel having the drawbacks mentioned above.
- the metal coating does not include any additional elements. This simplifies the management of the galvanizing bath and minimizes the number of phases formed in the metal coating.
- the sheet finally includes a paint film.
- the paint films are generally based on polymers and comprise at least one layer of paint.
- they comprise at least one polymer selected from the group consisting of melamine-crosslinked polyesters, isocyanate-crosslinked polyesters, polyurethanes and halogenated derivatives of vinyl polymers, with the exception of cataphoretic paints.
- These polymers have the characteristic of being particularly flexible, which promotes the synergistic action of the paint film and the metal coating.
- the paint film may be formed for example of two layers of successive paints, namely a primer layer and a topcoat which is generally the case for producing the film applied to the upper face of the sheet, or a layer of single paint, which is generally the case for making the film applied to the lower face of the sheet. Other numbers of layers may be used in certain variants.
- the paint films typically have thicknesses of between 1 and 200 ⁇ m.
- the interface between the metal coating and the paint film includes one or more characteristics to be selected from an alteration of the naturally occurring aluminum oxide / hydroxide layer on the surface metal coating, an alteration of the magnesium oxide / hydroxide layer naturally occurring on the surface of the metal coating and a conversion layer characterized by its chromium layer weight (in case of chromate conversion treatment) or by its weight of titanium layer (in case of conversion treatment without chromium).
- the installation used may comprise a single line or, for example, two different lines for producing respectively the metal coatings and the painting.
- two different lines may be located on the same site or on separate sites. In the remainder of the description, for example, a variant in which two distinct lines are used is considered.
- a steel substrate obtained for example by hot rolling then cold.
- the substrate is in the form of a strip which is passed through a bath to deposit the metal coating by hot quenching.
- the bath is a molten zinc bath containing 4.4 to 5.6% by weight of aluminum and 0.3 to 0.56% by weight of magnesium.
- the bath may also contain unavoidable process-related impurities, such as impurities from the bath feed ingots, and / or one or more additional members selected from the group consisting of Si, Ti, Ca, Mn, La, Ce and Bi, the weight content of each additional element in the metal coating being less than 0.3%, the presence of nickel being excluded.
- the most common unavoidable impurity resulting from the passage of the substrate in the bath is iron which may be present at a content of up to 0.8% by weight, generally less than or equal to 0.4% and generally between 0.1 and 0.4% by weight.
- the unavoidable impurities from the ingots are generally lead (Pb), present at a content of less than 0.01% by weight, Cadmium (Cd), present at a content of less than 0.005% by weight and tin (Sn), present at a content of less than 0.001% by weight.
- Pb lead
- Sn tin
- nickel is not an unavoidable impurity related to the galvanizing process.
- the bath has a temperature between 350 ° C and 510 ° C, preferably between 370 ° C and 470 ° C.
- the substrate is for example spun by means of nozzles throwing a gas on either side of the substrate, so as to adjust the thickness of the coatings.
- the wringing gas does not comprise particles or solutions such as, for example, those comprising a magnesium phosphate and / or a magnesium silicate.
- a brushing may be performed to remove the coating deposited on one side so that only one side of the sheet will ultimately be coated.
- the coatings are then allowed to cool in a controlled manner to solidify.
- the controlled cooling of the or each coating is carried out by means of a cooling box or any other suitable means and is provided at a speed preferably between 2 ° C / sec, corresponding approximately to a natural convection, and 35 ° C / sec between the onset of solidification (ie, when the coating reaches a temperature just below that of the liquidus) and the end of solidification (that is, when the coating reaches the temperature solidus). It was found that cooling rates above 35 ° C / sec did not improve the results further.
- the cooling is provided at a speed greater than or equal to 15 ° C / sec which contributes to refining the microstructure of the metal coating and thus to avoid the formation on the metal coating of a visible flowering to the naked eye and which remains apparent after painting. More preferably, the cooling rate is between 15 and 35 ° C / sec.
- the strip thus treated can then be subjected to a so-called skin-pass step which allows it to be hardened so as to erase the level of elasticity, to fix the mechanical characteristics and to give it a roughness adapted to the stamping operations and the quality of the painted surface that one wishes to obtain.
- the band may optionally be wound before being sent to a prelacing line.
- the outer surfaces of the coatings are subjected to a surface preparation step.
- a preparation comprises at least one step chosen from a rinsing, a degreasing and a conversion treatment.
- Rinsing is intended to remove loose dirt, possible residues of conversion solutions, soaps eventually formed and present a clean and reactive surface.
- degreasing is to clean the surface by removing all traces of organic dirt, metal particles and dust from the surface. This step also makes it possible to alter the oxide / aluminum hydroxide and magnesium oxide / hydroxide layers that may be present on the surface of the metal coating, without however unduly modifying the chemical nature of the surface. Such tampering improves the quality of the metal coating / paint film interface which improves the corrosion resistance and adhesion of the paint film.
- the degreasing is carried out in an alkaline medium. More preferably, the pH of the degreasing solution is between 12 and 13.
- the conversion treatment step comprises applying to the metal coating a conversion solution that chemically reacts with the surface and thereby forming conversion layers on the metal coating. These conversion coats increase the adhesion of the paint and the corrosion resistance.
- the conversion treatment is an acid solution not containing chromium. More preferably, the conversion treatment is based on hexafluorotitanic acid or hexafluorozirconic acid.
- the possible stages of degreasing and conversion treatment may include other sub-stages of rinsing, drying ...
- the surface preparation may also include a step of altering the magnesium oxide and magnesium hydroxide layers formed on the surface of the metal coating.
- This alteration can in particular, the application of an acidic solution before application of the conversion solution, or the application of an acidified conversion solution at a pH of between 1 and 5 or else the application of mechanical stresses on the area.
- the painting is carried out by deposition of paint layers by means of, for example, roller coaters.
- Each deposit of a paint layer is generally followed by baking in an oven so as to crosslink the paint and / or evaporate the possible solvents and thus obtain a dry film.
- prepainted sheet The sheet thus obtained, called prepainted sheet, can be rewound before being cut, possibly shaped and assembled with other sheets or other elements by users.
- the propensity to crack of a ZnAIMg sheet, prepainted or not, is evaluated as follows:
- a T-bend fold is made on a specimen of a sheet according to the EN 13523-7 standard of April 2001,
- T-bend 2T and 3T folds were then made on both the bare sheets and those coated and analyzed.
- T-bend 2T and 3T plies were also on bare or coated sheet including other types of ZnAIMg coating.
- Tables 1 and 2 summarize the results obtained, respectively ZnAIMg bare sheets and zinc coated ZnAIMg sheets. The comparison of the 1 and 2 show that, very surprisingly, the cracks in the ZnAIMa coating thickness according to the invention are significantly less numerous.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Coating With Molten Metal (AREA)
- Chemically Coating (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Chemical Treatment Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IB2013/002239 WO2015052546A1 (fr) | 2013-10-09 | 2013-10-09 | Tôle à revêtement znaimg à flexibilité améliorée et procédé de réalisation correspondant |
| PCT/IB2014/002059 WO2015052572A1 (fr) | 2013-10-09 | 2014-10-09 | Tôle à revêtement znaimg à flexibilité améliorée et procédé de réalisation correspondant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4373989A1 true EP4373989A1 (fr) | 2024-05-29 |
Family
ID=49780095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP14795864.9A Pending EP4373989A1 (fr) | 2013-10-09 | 2014-10-09 | Tôle à revêtement znaimg à flexibilité améliorée et procédé de réalisation correspondant |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20160251761A1 (pt) |
| EP (1) | EP4373989A1 (pt) |
| JP (1) | JP6279723B2 (pt) |
| KR (2) | KR102089879B1 (pt) |
| CN (1) | CN105829568B (pt) |
| AU (1) | AU2014333502B2 (pt) |
| BR (1) | BR112016006159B1 (pt) |
| CA (1) | CA2926564C (pt) |
| EA (1) | EA030933B1 (pt) |
| MX (1) | MX2016004415A (pt) |
| UA (1) | UA119543C2 (pt) |
| WO (2) | WO2015052546A1 (pt) |
| ZA (1) | ZA201601734B (pt) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106929708A (zh) * | 2017-04-27 | 2017-07-07 | 甘肃酒钢集团宏兴钢铁股份有限公司 | 一种含Zn‑Al‑Mg‑Si‑Ni‑Ce的热浸镀用高耐蚀锌基铸造合金的制备方法 |
| DE202018006293U1 (de) * | 2017-05-25 | 2020-01-07 | Tata Steel Ijmuiden B.V. | Schmelztauchbeschichtetes Stahlblech |
| ES2767852T3 (es) * | 2017-09-18 | 2020-06-18 | Henkel Ag & Co Kgaa | Tratamiento previo de aluminio en dos etapas, en particular de aleaciones de aluminio, que comprende el decapado y tratamiento de conversión |
| KR102031466B1 (ko) | 2017-12-26 | 2019-10-11 | 주식회사 포스코 | 표면품질 및 내식성이 우수한 아연합금도금강재 및 그 제조방법 |
| EP3858495A1 (en) * | 2020-02-03 | 2021-08-04 | Public Joint-Stock Company NOVOLIPETSK STEEL | Method for production of corrosion-resistant steel strip |
| RU2727391C1 (ru) * | 2020-02-03 | 2020-07-21 | Публичное Акционерное Общество "Новолипецкий металлургический комбинат" | Способ производства коррозионностойкого окрашенного стального проката с цинк-алюминий-магниевым покрытием |
| WO2023166858A1 (ja) * | 2022-03-04 | 2023-09-07 | Ｊｆｅスチール株式会社 | 溶融Ａｌ－Ｚｎ系めっき鋼板、その製造方法、表面処理鋼板及び塗装鋼板 |
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| CA1132011A (en) * | 1978-11-09 | 1982-09-21 | Bernard Schoeps | Process and apparatus for producing a sheet or strip which is lightly galvanized on one or both sides and products obtained by said process |
| JPS58177447A (ja) * | 1982-04-08 | 1983-10-18 | Nisshin Steel Co Ltd | 耐食性、塗装性に優れた溶融亜鉛めつき鋼板の製造法 |
| US5059455A (en) * | 1988-03-08 | 1991-10-22 | Cyclops Corporation | Method for galvanizing perforated steel sheet |
| US5578669A (en) * | 1993-12-24 | 1996-11-26 | Nippon Paint Co., Ltd. | Water-based polyurethane coating composition |
| JPH11158657A (ja) * | 1997-11-26 | 1999-06-15 | Nippon Steel Corp | 耐食性に優れた表面処理鋼材 |
| US6465114B1 (en) * | 1999-05-24 | 2002-10-15 | Nippon Steel Corporation | -Zn coated steel material, ZN coated steel sheet and painted steel sheet excellent in corrosion resistance, and method of producing the same |
| JP2001020049A (ja) * | 1999-07-06 | 2001-01-23 | Nippon Steel Corp | 未塗装ならびに塗装後の耐食性に優れた溶融Ｚｎ−Ａｌ−Ｍｇめっき鋼材およびその製造方法 |
| JP3465688B2 (ja) * | 2001-01-17 | 2003-11-10 | 住友金属工業株式会社 | 加工性に優れた溶融Ｚｎ−Ａｌ系合金めっき鋼板とその製造方法 |
| JP2002285312A (ja) * | 2001-03-27 | 2002-10-03 | Nippon Steel Corp | 成形性に優れた溶融亜鉛めっき鋼板及びその製造方法 |
| US6555231B2 (en) * | 2001-07-03 | 2003-04-29 | Basf Corporation | Waterborne coating composition and a paint system thereof having improved chip resistance |
| JP2006328445A (ja) * | 2005-05-23 | 2006-12-07 | Nippon Parkerizing Co Ltd | プレコート金属材料用水系表面処理剤、表面処理方法及びプレコート金属材料の製造方法 |
| JP5194465B2 (ja) * | 2006-03-08 | 2013-05-08 | Ｊｆｅスチール株式会社 | 塗装鋼板、加工品および薄型テレビ用パネルならびに塗装鋼板の製造方法 |
| JP2007292288A (ja) * | 2006-03-31 | 2007-11-08 | Akebono Brake Ind Co Ltd | ブレーキ部材及びその接着方法 |
| EP1857567B1 (de) * | 2006-05-15 | 2017-04-05 | ThyssenKrupp Steel Europe AG | Verfahren zum Herstellen eines mit einem Korrosionsschutzsystem überzogenen Stahlflachprodukts |
| CN101466871B (zh) * | 2006-06-15 | 2010-09-29 | 新日本制铁株式会社 | 被覆钢板 |
| JP2008000910A (ja) * | 2006-06-20 | 2008-01-10 | Jfe Steel Kk | 高耐食性表面処理鋼板及びその製造方法 |
| JP5101249B2 (ja) * | 2006-11-10 | 2012-12-19 | Ｊｆｅ鋼板株式会社 | 溶融Ｚｎ−Ａｌ系合金めっき鋼板およびその製造方法 |
| CA2677753C (en) * | 2007-02-12 | 2016-03-29 | Henkel Ag & Co. Kgaa | Process for treating metal surfaces |
| JP2009113389A (ja) * | 2007-11-07 | 2009-05-28 | Jfe Galvanizing & Coating Co Ltd | プレコート鋼板 |
| JP2009191317A (ja) * | 2008-02-14 | 2009-08-27 | Sumitomo Metal Ind Ltd | 脱脂性に優れる溶融亜鉛系めっき鋼板の製造方法 |
| US20100035080A1 (en) * | 2008-02-29 | 2010-02-11 | Gm Global Technology Operations, Inc. | Corrosion resistant laminated steel |
| EP2119804A1 (fr) * | 2008-05-14 | 2009-11-18 | ArcelorMittal France | Procédé de fabrication d'une bande métallique revêtue présentant un aspect amélioré |
| JP5600398B2 (ja) | 2009-04-28 | 2014-10-01 | Ｊｆｅ鋼板株式会社 | 溶融Ｚｎ系めっき鋼板 |
| WO2010130884A1 (fr) * | 2009-05-14 | 2010-11-18 | Arcelormittal Investigacion Y Desarrollo Sl | Procédé de fabrication d'une bande métallique revêtue présentant un aspect amélioré |
| CA2809940C (en) * | 2010-09-02 | 2014-07-08 | Nippon Steel & Sumitomo Metal Corporation | Precoated metal sheet excellent in conductivity and corrosion resistance |
| JP5649179B2 (ja) * | 2011-05-30 | 2015-01-07 | Ｊｆｅ鋼板株式会社 | 耐食性と加工性に優れた溶融Ｚｎ−Ａｌ系合金めっき鋼板およびその製造方法 |
-
2013
- 2013-10-09 WO PCT/IB2013/002239 patent/WO2015052546A1/fr active Application Filing
-
2014
- 2014-10-09 EA EA201690733A patent/EA030933B1/ru not_active IP Right Cessation
- 2014-10-09 CA CA2926564A patent/CA2926564C/fr active Active
- 2014-10-09 US US15/028,249 patent/US20160251761A1/en not_active Abandoned
- 2014-10-09 UA UAA201604963A patent/UA119543C2/uk unknown
- 2014-10-09 JP JP2016521699A patent/JP6279723B2/ja active Active
- 2014-10-09 WO PCT/IB2014/002059 patent/WO2015052572A1/fr active Application Filing
- 2014-10-09 BR BR112016006159-4A patent/BR112016006159B1/pt active IP Right Grant
- 2014-10-09 CN CN201480055353.XA patent/CN105829568B/zh active Active
- 2014-10-09 KR KR1020187003953A patent/KR102089879B1/ko active IP Right Grant
- 2014-10-09 EP EP14795864.9A patent/EP4373989A1/fr active Pending
- 2014-10-09 AU AU2014333502A patent/AU2014333502B2/en active Active
- 2014-10-09 KR KR1020167011963A patent/KR20160067943A/ko active Application Filing
- 2014-10-09 MX MX2016004415A patent/MX2016004415A/es unknown
-
2016
- 2016-03-14 ZA ZA2016/01734A patent/ZA201601734B/en unknown
-
2021
- 2021-06-15 US US17/347,868 patent/US20210310129A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EA201690733A1 (ru) | 2016-08-31 |
| CA2926564C (fr) | 2018-11-27 |
| US20160251761A1 (en) | 2016-09-01 |
| CN105829568A (zh) | 2016-08-03 |
| JP2016540885A (ja) | 2016-12-28 |
| ZA201601734B (en) | 2020-07-29 |
| KR20180017240A (ko) | 2018-02-20 |
| AU2014333502B2 (en) | 2018-02-15 |
| BR112016006159B1 (pt) | 2021-07-06 |
| KR102089879B1 (ko) | 2020-03-17 |
| MX2016004415A (es) | 2016-07-05 |
| UA119543C2 (uk) | 2019-07-10 |
| US20210310129A1 (en) | 2021-10-07 |
| BR112016006159A2 (pt) | 2017-08-01 |
| BR112016006159A8 (pt) | 2020-02-18 |
| JP6279723B2 (ja) | 2018-02-14 |
| KR20160067943A (ko) | 2016-06-14 |
| WO2015052546A1 (fr) | 2015-04-16 |
| EA030933B1 (ru) | 2018-10-31 |
| WO2015052572A9 (fr) | 2015-08-20 |
| CA2926564A1 (fr) | 2015-04-16 |
| CN105829568B (zh) | 2018-11-23 |
| AU2014333502A1 (en) | 2016-04-28 |
| WO2015052572A1 (fr) | 2015-04-16 |
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